An improved method of fracturing an underground fluid bearing formation penetrated by a well bore for the production of fluids therefrom by injecting a composition capable of forming a fluid permeable barrier in said formation at a pressure sufficient to form fissures therein extending from said well bore, and thereafter maintaining pressure on the composition for a predetermined period to permit the composition to set and form a fluid permeable barrier in the formed fissures.
A method of propping fractures in a subterranean formation whereby a high viscosity fluid is introduced into the formation to open and extend the fractures, the high viscosity fluid containing slugs of a hardenable liquid which are carried into and held in spaced relationship in the fractures and permitted to harden therein whereby the fractures are propped in the open position.
Compositions comprising a base fluid and a monoester copolymer of styrene and maleic anhydride are disclosed. The compositions can further comprise an alkyl orthophosphate ester. The base fluid can be an aqueous or organic base fluid. The monoester copolymer is at least partially soluble or dispersible in the base fluid. Preferably, the composition may further include a cross-linking agent capable of increasing the viscosity of the composition, such as aluminum isopropoxide or other metal source compounds. The composition can form a gel which is stable at a temperature of about 250.degree. F. (121.degree. C.) or higher. Some gels of the present invention exhibit stability up to about 300.degree. F. (149.degree. C.) to 350.degree. F. (177.degree. C.) or higher. The compositions have many applications, such as pipeline treatment, conformance, hydraulic fracturing, well completion, gravel packing, drilling fluids, process facility treatment fluids, and other well treatment applications.
Gelled organic compositions and methods for using same. The gelled compositions may be liquid organic fluids, such as gelled liquid hydrocarbons, formed from a mixture of an organic-base fluid, a carboxylic acid, and one or more metal source compounds, such as a metal salt of carboxylic acid. The gelled compositions may be used in variety of applications including, but not limited to, oil field, pipeline and processing facility applications.
Solid surfactant suspension compositions are formed by combining solid surfactants, such as alpha-olefin sulfonates, with an organic base fluid, such as diesel. Solid surfactant suspensions may be combined with an aqueous carrier fluid to form surfactant-containing fluids suitable for, among other things, forming foams or for water wetting surfaces. Solid surfactant suspensions may also be combined with additive materials, such as polymer particles, to form a dispersion or emulsion. Polymer-containing solid surfactant suspensions may also be combined with aqueous carrier fluids to form, for example, viscosified, gelled, or foamed fluids. Concentration of solid surfactant materials contained in a solid surfactant suspension may be varied to affect the function the solid surfactant suspension. For example, the solid surfactant material may function as a polymer surface wetting agent, an emulsifier, a dispersant, a viscosifier, and/or a foamer in well completion and remedial and/or workover fluids.
