A semiconductive junction device comprises a thin layer og a glassy amorphous material exhibiting one type of conductivity (either N or P) disposed upon a semiconductive substrate possessing the other kind of conductivity. The glassy layer is sufficiently thin that it exhibits a useful level of conductivity. Preferably, the glassy layer is ion impermeable so that the device remains stable under a wide range of operating conditions. These junctions behave as diodes and can be incorporated in a wide variety of complex semiconductive devices.
CROSS REFERENCE TO RELATED APPLICATIONS
This is a continuation, division of application Ser. No. 227,933, filed Feb. 22, 1972, now U.S. Pat. No. 3,801,879, which application is a continuation-in-part of United States application Ser. No. 122,420 filed by the same inventor on Mar. 9, 1971.
The invention is a ultra-fast, high frequency, high temperature rectifying diode formed in silicon carbide that comprises a monocrystalline silicon carbide substrate having a sufficient carrier concentration to give the substrate a first conductivity type, a first monocrystalline epitaxial layer of silicon carbide upon the substrate and having the same conductivity type as the substrate, and a second monocrystalline epitaxial layer of silicon carbide upon the first epitaxial layer and having the opposite conductivity type from the first epitaxial layer. One of the epitaxial layers has a carrier concentration greater than the carrier concentration of the other epitaxial layer, so that the layer with the lesser concentration is predominantly depleted at reverse bias. The first and second epitaxial layers form an abrupt p-n junction.