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Claims  |
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What is claimed is:
1. A process for the formation of a structure for the transfer of energy
between a locus in a borehole and a subterranean formation comprising:
a. drilling a borehole from the surface into the formation,
b. fracturing and propping the formation adjacent to the locus by injecting
a reactive slurry into the formation at a pressure above the fracturing
pressure of the formation, the slurry comprising finely divided aluminum
and a reactive metal oxide in a fluid carrier,
c. igniting the reactive slurry within the formation so that the aluminum
and the metal oxide therein react to form a liquid metal within the
fracture system formed in the formation, and
d. allowing the liquid metal in the formation to cool and solidify within
the fracture system.
2. The process of claim 1 wherein:
e. the reactive slurry of (b) comprises finely divided aluminum and iron
oxide in an aqueous carrier thickened with a polymer,
f. the reactive slurry is substantially displaced into the formation by
injecting sufficient of a non-reactive slurry to substantially displace
the reactive slurry from the wellbore above the locus subsequent to step
(b) of claim 1 and prior to the ignition of step (c) of claim 1, and
g. sufficient pressure is maintained on the column of non-reactive slurry
in the wellbore to prevent backflow of the reacting slurry following
ignition and prior to solidification.
3. The process of claim 1 wherein the structure is made corrosion resistant
by incorporating a corrosion resistance imparting metal or metal compound
into the reactive slurry.
4. A process for the recovery of heat from a geothermically heated
subterranean formation comprising:
h. drilling a borehole from the surface into the formation,
i. fracturing and propping the formation by injecting a reactive slurry
into the formation at a pressure above the fracturing pressure of the
formation, the reactive slurry comprising finely divided aluminum and a
reactive metal oxide in a fluid carrier,
j. igniting the reactive slurry within the formation so that the aluminum
and metal oxide therein react to form a liquid metal within the fracture
system formed in the formation,
k. allowing the liquid metal in the formation to cool and solidify within
the fracture system, and
l. withdrawing heat from a locus in the wellbore adjacent to the solidified
metal which is conducted thereto from within the formation by the
solidified metal within the fracture system.
5. The process of claim 4 wherein:
m. the reactive slurry of (i) comprises finely divided aluminum and iron
oxide in an aqueous carrier thickened with a polymer,
n. the reactive slurry is substantially displaced into the formation by
injecting sufficient of a less dense non-reactive slurry to substantially
displace the reactive slurry from the wellbore above the geothermically
heated subterranean formation subsequent to step (i) and prior to the
ignition of step (j) and
o. sufficient pressure is maintained on the column of non-reactive slurry
in the well bore to prevent backflow of the reacting slurry following
ignition and prior to solidification.
6. The process of claim 5 wherein heat is withdrawn from the geothermically
heated formation by circulating a fluid to the locus in the well bore and
returning the heated fluid to the surface.
7. The process of claim 6 wherein water is circulated to the locus and
steam is returned to the surface.
8. A process for imparting energy to a hydrocarbon containing subterranean
formation comprising:
p. drilling a bore hole from the surface into the formation,
g. fracturing and propping the formation by injecting a reactive slurry
into the formation at a pressure above the fracturing pressure of the
formation, the reactive slurry comprising finely divided aluminum and a
reactive metal oxide in a fluid carrier,
r. igniting the reactive slurry within the formation so that the aluminum
and metal oxide therein react to form a liquid metal within the fracture
system formed in the formation,
s. allowing the liquid metal in the formation to cool and solidify within
the fracture system, and
t. imparting energy into the formation from a locus in the well bore
adjacent to the solidified metal by conduction through the solidified
metal within the fracture network.
9. The process of claim 8 wherein:
u. the reactive slurry of (q) comprises finely divided aluminum and iron
oxide in an aqueous carrier thickened with a polymer,
v. the reactive slurry is substantially displaced into the formation by
injecting sufficient of a less dense non-reactive slurry to substantially
displace the reactive slurry from the well bore above the hydrocarbon
containing subterranean formation subsequent to step (q) and prior to the
ignition of steps (r) and (v), sufficient pressure is maintained on the
column of non-reactive slurry in the well bore to prevent backflow of the
reacting slurry following ignition and prior to solidification.
10. The process of claim 9 wherein the energy is imparted into the
formation by conducting electrical energy from a surface generating source
through a conductor and through the solidified metal into the formation.
11. The process of claim 9 wherein the energy is supplied to the locus of
(t) by circulating a heated fluid to the locus and returning cooled fluid
to the surface.
12. The process of claim 11 wherein steam is circulated to the locus. |
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Claims  |
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Description  |
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BACKGROUND OF THE INVENTION
1. Field of the Invention
The invention relates to the transfer of energy between a locus in a
borehole and a subterranean formation penetrated by the borehole. In one
aspect, the invention relates to formation of a structure for the recovery
of heat from the geothermally heated formation by drilling a well,
fracturing and propping with a slurry capable of maintaining a thermit
reaction, igniting the slurry, and allowing to cool to form a conductor
fin network within the formation for the conduction of heat to the locus
in the wellbore. In another aspect, the invention relates to a heat
recovery process for the recovery of heat from a geothermally heated
subterranean formation comprising drilling a borehole into the formation,
fracturing the formation with a slurry capable of maintaining a thermit
reaction, igniting the slurry, allowing the molten metal formed by the
thermit reaction to cool forming a metal conductor fin network from the
bore into the fracture formation, and recovering heat conducted to a locus
in the bore by a fluid heat recovery system.
2. Brief Description of the Prior Art
Many regions are known in which volcanic or intrusive activity has occurred
recently enough so that the geothermal gradient is still as high as
150.degree. to 190.degree. C per km (435.degree. to 550.degree. F per
mile). In such regions, temperatures high enough to produce commercially
useful steam exist within two to three kilometers (6600 to 9800 feet of
the earth's surface. In some places, natural steam can be produced from
the geothermal heat.
Where natural steam is not produced, exploitation of such geothermal
reservoirs has not been commerically undertaken, in spite of the fact that
many of such reservoirs are closer to the earth's surface than are the
lower levels of a deep mine. A principal reason for such lack of
commercialization is because the thermal conductivities of the heat
bearing rocks are typically very low. Though specific heats are high, so
that a relatively large amount of heat is available from a unit volume of
hot rock. Such heat, however, can be extracted from the rock only though
some free surface such as a wall of a borehole. Since heat is conducted to
that surface quite slowly, because of the low thermal conductivity of the
rock, it is very difficult to remove thermal energy from the rock at a
usefully high rate.
One approach to the problem of removing heat energy from such geothermal
formations at useful rates is disclosed in U.S. Pat. No. 3,786,858 wherein
a relatively large surface area is created by hydraulically fracturing
between two well bores penetrating the geothermal formation and passing a
fluid through the hydraulically created fracture system.
U.S. Pat. No. 3,857,244 discloses an advanced system for heat energy
recovery from geothermally heated rock formations once the heat is
transferred to a locus in the well bore adjacent to the geothermally
heated rock.
U.S. Pat. No. 3,105,545 discloses injecting a slurry of metal particles
into fractures formed in a hydrocarbon bearing formation to emplace
closely packed metal particles in the fracture zone with subsequent
circulation of heated fluid into the well to impart heat to the formation
and provide for improved recovery of hydrocarbons.
My invention constitutes a substantial advance in the art by providing for
efficient transfer of energy between a locus in a borehole and a
subterranean formation. In a particular aspect, my invention provides for
more efficient recovery of heat from a geothermal formation by overcoming
the lack of sufficient thermal conductivity of the reservoir rock for
feasible heat extraction.
OBJECTS OF THE INVENTION
An object of the invention is to provide a process for the formation of a
structure for the transfer of energy between a locus in a borehole and a
subterranean formation penetrated by the borehole.
Another object is to provide a process for the recovery of heat from a
geothermically heated subterranean formation.
SUMMARY OF THE INVENTION
A structure and system for the transfer of energy between a locus in a
borehole and a subterranean formation is formed by (a) drilling a borehole
from the surface into the formation, (b) fracturing and propping the
formation by injecting a fracturing and reactive slurry into the
formation, the slurry comprising finely divided aluminum and a reactive
metal oxide in a fluid carrier, (c) igniting the reactive slurry within
the formation so that the aluminum and metal oxide components thereof
react with a thermit reaction to form a liquid metal within the fracture
system formed in the formation by the fracturing and propping, and (d)
allowing the liquid metal in the formation to cool and solidify within the
fractured system.
Thus, in one aspect, a geothermally heated formation is penetrated by a
bore. The formation is fractured and propped with a slurry capable of
maintaining a thermit reaction. The slurry is ignited. Upon cooling, a
solid iron conductor fin network from the bore into the formation in the
fracture system is formed. Thermal energy is conducted by the network from
the formation to a locus in the bore where it is recovered to the surface
by a liquid or liquid-vapor recovery system.
According to another aspect of the invention, a hydrocarbon-bearing
formation is penetrated by a bore. The formation is fractured and propped
with a slurry containing particles of iron oxide and particles of aluminum
oxide. The metallic components are ignited in the fracture system. After a
thermit reaction has occurred and cooling has occurred, a solid iron
conductor fin network from the bore into the fracture system in the
formation is formed. Thermal energy is conducted by the network into the
formation from a surface source by a liquid or liquid-vapor heat transfer
system.
BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 illustrates a cross section of a borehole penetrating a subterranean
formation having the energy transfer system and structure of the invention
emplaced therein.
FIG. 2 illustrates a cross section of two bore holes penetrating a
subterranean formation having an electrical energy transfer system and
structure of the invention emplaced therein.
DESCRIPTION OF THE DRAWINGS
FIG. 1 illustrates a cross section of a subterranean formation having the
structure of this invention emplaced therein. The subterranean formation 2
is overlain by overburden 1 and penetrated by well bore 3.
According to a presently preferred mode, the subterranean formation 2 is a
geothermically heated formation. Well casing 5 extends to the upper region
of the formation 2 and is insulated from the overburden 1 by insulation 6.
A solid metal conductor fin network 12 is emplaced in the formation 2 by
fracturing and propping the formation 2 by injecting a reactive slurry
down the well bore into the formation 2 at a pressure above the fracturing
pressure of the formation, the fracturing and propping slurry containing
finely divided alluminum and a reactive metal oxide such as iron oxide in
a fluid carrier; preferably following injection of the reactive slurry by
a non-reactive slurry so that reactive slurry does not extend above the
upper level of the formation 2; igniting the reactive slurry within the
well bore as with a pyrotechnic device such that the aluminum and the
metal oxide in the reactive slurry react to form a liquid metal within the
fracture system formed in the formation; allowing the liquid metal in the
formation to cool and solidify thus formimg the solid metal conductor fin
network 12 extending from the bore 3 into the formation 2; and preferably
re-boring well bore 3 within the formation 2.
Thereupon, tubing 4 having insulation 7 on the interior is inserted into
the well bore 3 having passageway 8 therein and forming annulus 9 within
the well bore.
The emplaced system described above is employed according to one presently
preferred mode to produce heat from a formation 2 when formation 2 is
geothermically heated according to the following mode of operation: heat
is conducted from formation 2 by the solid metal conductor fin network 12
to a locus in the well bore 14; a relatively cool fluid 11 is injected
through annulus 9 passing locus 14 (having a high geothermal heat transfer
thereto by virtue of the conductor fin network 12) whereupon the fluid is
heated; with continuing flow of the fluid 10 from the well through
passageway 8. Useful heat energy is extracted from the fluid 10, which can
be, for example, steam or heated water, by conventional systems such as
heating radiators, electric power generating turbines, and the like, with
recycle of the fluid having the heat extracted therefrom as fluid 11.
According to another presently preferred mode of operation, heated fluid 11
is injected through annulus 9 to heat a subterranean formation 2 (which is
a hydrocarbon bearing formation in this mode) by conducting of heat given
up by the fluid 11 at locus 14 by the solid metal conductor fin network
12, with return of the cooled fluid through passageway 8 for optional
recycle through a surface heat source.
It is also within the scope of this invention to employ a structure having
the solid metal conductor fin network emplaced in a hydrocarbon bearing
formation to impart heat to that formation by imparting electric energy
through the conductor fin network to the formation.
Thus, according to one embodiment, as illustrated in FIG. 2, two wells
penetrating a hydrocarbon formation 2 are completed as hereinabove
described, and electrical contact is made through a conductive metal wire
15 between a surface electrical generating source 16 and the solid metal
conductor fin network 12 in the two wells. An electric current is passed
between the wells to heat the formation 2 therebetween, and mobilize
hydrocarbons therein.
PREFERRED EMBODIMENTS OF THE INVENTION
Examples
To illustrate the invention, a well bore is drilled from the surface into a
geothermically hot formation to a depth of 10,000 feet. The formation
penetrated from well bottom to more than 500 feet above that point is a
dense crystaline dry rock having a temperature of about 900.degree. F. The
well is cased and insulated from the overburden to a depth of 9,700 feet.
Thereupon, an aqueous based polymer thickened slurry containing finely
divided particles of A1 and Fe.sub.2 O.sub.4 in a stochiometric ratio of
8:3 is injected into the well at high pressure to effect extensive
fracturing in the formation below the well casing. The reactive slurry
injected also has sufficient propping agent included therein to hold the
fracture system open. A sufficient amount of less dense slurry is then
injected to further fracture the formation and move the reactive slurry
below the cased portion of the well.
A pyrotechnic device is inserted down hole into the reactive slurry.
Pressure is maintained on the well.
The pyrotechnic device is ignited by electrical means thus igniting the
reactive slurry. A thermit or Goldschmidt aluminothermic reaction occurs
in the reactive slurry forming molten iron and alumina slag. Extensive
heat energy is evolved from the thermit reaction forming an iron conductor
fin network within the formation and extending to the locus of the well
bore below the cased area. The formation in the locus of the well is
allowed to cool and the molten iron solidifies in intimate contact with
the formation forming a solid iron conductor fin network within the
formation connected to the well bore.
Thereupon, the well bore is milled to hole bottom at a dimension
approximately two-thirds of its original diameter.
Thereupon, a pipe insulated on the interior is run to within a few feet of
well bottom. Water is injected into the annulus between the casing and the
insulated tubing string passing down the annulus in the locus of the iron
conductor fin network, forming steam, and then returning to the surface
through the insulated tubing string to deliver high temperature and high
pressure steam to the surface.
The steam is employed to run a turbine which drives an electrical
generator. Condensate is recycled to the well.
By way of further exemplification, a well and structure is completed and
prepared as above but into a hydrocarbon-bearing formation instead of a
geothermically heated formation.
Upon completion, steam is injected down the annulus between the tubing
string and the casing with substantial back pressure held on the tubing
string. Outlying wells are completed in the formation. Heat imparted to
the formation along with the steam and hot water injected result in
substantial recovery of hydrocarbons from the outlying wells.
By way of further exemplification, a well and structure is completed and
prepared as above into a hydrocarbon bearing formation.
Upon completion electrical contact is made between the iron conductor fin
network and a surface generating source. Thereupon energy is imparted into
the formation by conducting electricity from the surface source down the
well bore and into the formation by means of the iron conductor fin
network.
These examples are provided in order to more fully explain the present
invention and provide information to those skilled in the art on how to
carry it out. However, it is to be understood that these examples are not
intended to function as limitations on the invention as described and
claimed herein.
Fracturing and propping of subterranean formations is well known to those
skilled in the art and much data and information on how to effect it are
widely available.
The thermit or Goldschmidt process is an aluminothermic method for the
production of molten iron or steel. The principle feature of the reaction
is the exothermic reaction of aluminum in a divided form and a metal oxide
such as iron oxide to produce liquid metal, alumina and considerable heat.
It is known to employ mixtures of metal oxides and/or metals to impart
corrosion resistance to the solidified liquid metal produced. Metals such
as nickel, copper, chromium, vanadium and the like can be employed. It is
within the scope of this invention to form structures having corrosion
resistance in this manner. The process is well known and much data and
information relating to it are available to those skilled in the art.
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Description  |
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