The present invention relates to improved explosives or blasting compositions of the aqueous gel or slurry type. In general, it concerns such blasting compositions employing a combination of calcium nitrate as oxidizer salt and sulfur as fuel. This combination effectively sensitizes the composition and renders its sensitivity relatively less dependent upon temperatures. In addition, this combination imparts desirable physical properties to the composition.
The invention relates to a thermally stable, cap-sensitive water-in-oil emulsion explosive composition having a discontinuous aqueous oxidizer salt solution phase containing calcium nitrate, a continuous oil or water-immiscible liquid organic phase, an emulsifier, and a density reducing agent.
A method of producing an energetic composition comprising the steps of (a) issolving an alkali metal hydroxide in aqueous denatured alcohol to form an alcohol and alkali metal hydroxide solution; (b) kneading phenolphthalein or other reaction product of a phenolic compound and phthalic anhydride with sulfur, potassium nitrate and said alkali metal hydroxide solution formed in step (a); (c) allowing the kneaded product formed in step (b) to dry through evaporation of the aqueous denatured alcohol; (d) granulating the dried product formed in step (c); and (e) further drying the granulated product formed in step (d). An alternate method is also disclosed in which an alkali metal salt of phenolphthalein is used so as to avoid use of the alkali metal hydroxide in the aqueous denatured alcohol. Granular products are disclosed and closed bomb test results are presented. Certain products match the performance of commercial black powder.
A blasting composition, method, and system for making such is disclosed. The blasting composition consists essentially of a particulate inorganic nitrate oxidizer, a particulate metal fuel, water, and a gelling agent. The composition is prepared by blending 10-20% by weight of the total amount of water to be added to the composition, with the particulate inorganic nitrate oxidizer; adding a dry blend of gelling agent and particulate metal fuel to the damp oxidizer; briefly mixing the two components; adding the remainder of the water; and slowly subjecting the mixture to a tumbling action for a brief period of time sufficient to obtain a uniform composition.
The present invention comprises a permissible aqueous blasting composition containing at least about 15% calcium nitrate as oxidizer salt. The calcium nitrate combined with water, inert material, a sensitizer, and cross linking and thickening agents forms a stable aqueous blasting composition or slurry which will meet the permissibility requirements of the U.S. Department of Labor. The use of this minimum amount of calcium nitrate particularly is effective in increasing storage stability.
