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Claims  |
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What is claimed is:
1. In an automotive internal combustion engine including a mixture supply
system for producing from air and fuel delivered thereto an air-fuel
mixture to be fed to the cylinders of the engine and an exhaust system
having incorporated therein a catalytic converter which is reactive to at
least one predetermined type of air contaminative compound in the exhaust
gases emitted from the engine cylinders and which exhibits its maximum
conversion efficiency to the exhaust gases resulting from an air-fuel
mixture having a predetermined air-to-fuel ratio, a method of controlling
the air-to-fuel ratio of the mixture to be produced in the mixture supply
system, comprising detecting the concentration of at least one
predetermined type of chemical component of the exhaust gases from the
engine cylinders by means of an exhaust sensor 1ocated in the exhaust
system downstream of the branch tube portions of the exhaust manifold of
the exhaust system and upstream of the catalytic converter, said exhaust
sensor having an external portion projecting outwardly from the exhaust
system, producing a signal representative of the detected concentration of
said chemical component, controlling the delivery rate of at least one of
air and fuel to the mixture supply system in accordance with said signal
for regulating the air-to-fuel ratio of the mixture in the mixture supply
system toward said predetermined air-to-fuel ratio, detecting high-load
operating conditions of the engine, and inducing a forced flow of cooling
fluid through said external portion of the exhaust sensor under high-load
operating conditions of the engine.
2. A method as set forth in claim 1, in which exhaust sensor is located in
that portion of the exhaust system in which the exhaust gases passed
therethrough have a temperature within a predetermined range under
low-to-medium load operating conditions of the engine.
3. A method as set forth in claim 2, in which said predetermined range of
the exhaust temperature is from about 400.degree. C to about 900.degree.
C.
4. A method as set forth in claim 1, in which said cooling fluid is engine
cooling water circulated from the engine cooling water circuit.
5. A method as set forth in claim 1, in which said cooling fluid is
atmospheric air.
6. A mixture control system for an automotive internal combustion engine
including a mixture supply system for producing from air and fuel
delivered thereto an air-fuel mixture to be fed to the cylinders of the
engine and an exhaust system having incorporated therein a catalytic
converter which is reactive to at least one predetermined type of air
contaminative compound in the exhaust gases emitted from the engine
cylinders and which exhibits its maximum conversion efficiency to the
exhaust gases resulting from an air-fuel mixture having a predetermined
air-to-fuel ratio, comprising electrically operated valve means for
regulating the delivery rate of at least one of air and fuel to the
mixture supply system, an exhaust sensor disposed in the exhaust system
for detecting. the concentration of at least one predetermined type of
chemical component of the exhaust gases from the engine cylinders and
producing a signal representative of the detected concentration of said
chemical component, the exhaust sensor being located downstream of the
branch portions of the exhaust manifold of the exhaust and upstream of
said catalytic converter and having an external portion projecting
outwardly from the exhaust system, an electric control circuit for
controlling said valve means in accordance with said signal so that the
delivery rate of at least one of air and fuel to said mixture supply
system is controlled to regulate the air-to-fuel ratio of the mixture in
the mixture supply system toward said predetermined air-to-fuel ratio,
passageway means communicating with a source of cooling fluid and having a
chamber portion enclosing said external portion of said exhaust sensor,
flow inducing means for inducing a forced flow of said cooling fluid
through said chamber portion, and control means responsive to high-load
operating conditions of the engine and operative to actuate said flow
inducing means for establishing said forced flow of said cooling fluid
through said chamber portion under high-load operating conditions of the
engine.
7. A mixture control system as set forth in claim 6, in which said exhaust
sensor is located in that portion of the exhaust system in which the
exhaust gases being passed therethrough has a temperature within a
predetermined range under low-to-medium load operating conditions of the
engine.
8. A mixture control system as set forth in claim 7, in which said
predetermined range of the exhaust temperature is from about 400.degree. C
to about 900.degree. C.
9. A mixture control system as set forth in claim 6, in which said source
of cooling fluid is the cooling water circuit of the engine.
10. A mixture control system as set forth in claim 6, in which said cooling
fluid is atmospheric air.
11. A mixture control system as set forth in claim 10, in which said
external exhaust sensor is provided with radiator fins surrounding said
portion thereof. |
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Claims  |
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Description  |
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The present invention relates in general to internal combustion engines of
automotive vehicles and specifically to a gasoline-powered automotive
internal combustion engine of the type using a catalytic converter in the
exhaust system for exhaust cleaning purposes. More specifically, the
present invention is concerned with a method of controlling the
air-to-fuel ratio of the combustible mixture to be produced in the mixture
supply system of the internal combustion engine of the particular type and
with a mixture control system adapted to put the method into practice in
an internal combustion engine of the specified type.
Some modernized automotive vehicles are equipped with catalytic converters
in the exhaust systems of the engines for converting the toxic air
contaminants in the exhaust emissions into harmless compounds. A typical
example of the known catalytic converters uses an oxidative catalyst which
is especially effective to re-combust the unburned combustible compounds
such as hydrocarbons (HC) and carbon monoxide (CO) contained in the
exhaust gases emitted from the engine cylinders. The oxidative catalyst is
not only reactive to these combustible compounds but is operable to reduce
nitric oxides (NO.sub.x) in the exhaust gases if the exhaust gases to be
processed by the catalyst have a chemical composition within a certain
range which is dictated by the air-to-fuel ratio of the mixture supplied
to the engine cylinders. Thus, the catalytic converter using the oxidative
catalyst provides triple effects to process the most important three kinds
of air contaminative compounds in the exhaust gases when the air-to-fuel
mixture supplied to the engine cylinders is proportioned to an air-to-fuel
ratio within a certain range. Experiments have revealed that it is the
stoichiometric air-to-fuel ratio of about 14.8:1 (for a gasoline powered
engine) that enables the triple effect or "three-way" catalytic converter
to produce its maximum conversion efficiency against the three types of
air contaminative compounds. It is, for this reason, desirable in an
internal combustion engine using such a catalytic converter that the
mixture supply system of the engine be arranged with mixture control means
adapted to regulate the air-to-fuel ratio of the mixture toward the
stoichiometric level or maintain the air-to-fuel ratio within a
predetermined range containing the stoichiometric level.
If, however, the mixture control means used in combination with the
triple-effect catalytic converter is of an "open-loop" type which operates
without respect to the conditions of the exhaust emission of the engine,
problems arise in accurately controlling the air-to-fuel ratio of the
mixture because of the fluctuations in the operational and/or
environmental variables of the engine such as for example the pressure and
temperature of atmospheric air and the temperature of fuel to be fed into
the mixture supply system. These variables are predominant over the
desnity and viscosity of the fuel delivered into the mixture supply system
and, as a consequence, the fluctuations in the variables cause the
air-to-fuel ratio of the mixture to fluctuate over a wide range. The
fluctuations in the air-to-fuel ratio of the mixture supplied to the
engine cylinders result, in turn, in fluctuations in the concentrations of
air contaminative compounds in the exhaust gases emitted from the
cylinders. Insofar as the catalytic converter of the described type is
used in combination with the mixture control means of the open-loop type,
the potential capabilities of the catalytic converter could not be
exploited satisfactorily. Extreme difficulties would be encountered if
attempts were to be made to solve these problems merely by recourse to
sophisticated design considerations tailored to the performance
characteristics of individual engines.
To provide a solution to the problems arising from the use of the open-loop
mixture control means operative irrespective of the varying conditions of
the exhaust system, a "closed-loop" or "feedback" type mixture control
system has been proposed which is adapted to control the air-to-fuel ratio
of the mixture on the basis of information fed back from the exhaust
system.
The closed-loop or feedback mixture control system involves an exhaust
sensor operative to detect the concentration of a prescribed type of
chemical component contained in the exhaust gases emitted from the engine
cylinders and produce an analog electric signal, usually voltage,
indicative of the detected concentration of the chemical component. The
chemical composition of the exhaust gases is a faithful representation of
the air-to-fuel ratio of the mixture delivered to the engine cylinders
and, for this reason, the closed-loop or feedback mixture control system
is capable of accurately monitoring the air-to-fuel ratio of the mixture
produced in the mixture supply system of the engine and regulating the
ratio toward the stoichiometric level irrespective of the fluctuations in
the pressure and temperature of atmospheric air and the temperature of the
fuel delivered into the mixture supply system of the engine. The chemical
component of the exhaust gases to be detected may be oxygen, carbon
monoxide, carbon dioxide, hydrocarbons or nitric oxides wherein oxygen in
particular is the most preferred for ease of detection. The catalytic
converter has been exemplified as being of a tripple-effect type but the
closed-loop or feedback type mixture control system is useful also for an
internal combustion engine arranged with a catalytic converter reactive to
one or two of the above mentioned three types of air contaminative
compounds if the mixture control system is designed to regulate the
air-to-fuel ratio of the mixture toward a level optimum for the particular
function of the converter or maintain the air-to-fuel ratio within a
predetermined range containing the optimum level.
The performance efficiency of a catalytic converter is affected not only by
the proportion between the air and fuel components in the air-fuel mixture
supplied to the engine cylinders but by the temperature of the exhaust
gases passed through the converter, as is well known in the art. If the
temperature of the exhaust gases passed through a catalytic converter is
lower than a predetermined level of, for example, about 400.degree. C for
a converter using an oxidative catalyst, the catalytic converter is unable
to produce its maximum conversion efficiency even though the air-to-fuel
ratio of the mixture supplied to the engine cylinders may be controlled
appropriately for the converter. It is, for this reason, important that
the catalytic converter provided in the exhaust system be located as close
to the exhaust ports of the cylinders as possible and arranged with heat
insulating means to minimize liberation of heat from the exhaust system
upstream of the catalytic converter. On the other hand, the exhaust sensor
to detect the chemical composition of the exhaust gases is usually so
designed as to properly operate when the temperature of the exhaust gases
contacting the sensor is within a predetermined range of, for example,
from about 400.degree. C to about 900.degree. C for a sensor using a
sintered electrolyte of zirconium oxide coated with microporous platinum
layers. For the mere purpose of enabling the exhaust sensor to properly
operate, the sensor may therefore be located anywhere in the exhaust
system provided the temperature of the exhaust gases contacting the sensor
falls within the predetermined range.
The analog signal produced by the exhaust sensor is fed to an electric
control circuit and is compared with a fixed reference signal which may be
representative of the air-to-fuel ratio optimum for the total performance
characteristics of the catalytic converter. The air-to-fuel ratio of the
mixture to be produced in the mixture supply system of the engine is
regulated by electrically operated air and/or fuel flow control means
controlled in accordance with the output signal delivered from the control
circuit. The air-to-fuel ratio determined in this fashion on the basis of
the signal produced by the exhaust sensor is monitored by the exhaust
sensor which detects the concentration of a prescribed type of chemical
component of the exhaust gases resulting from the air-fuel ratio thus
controlled. A considerable time delay is therefore involved in feeding
back information to the mixture supply system from the exhauses gases
resulting from the mixture produced in the supply system. Such a time lag
will become the longer as the exhaust sensor is located farther from the
exhaust ports of the engine cylinders. The time lag deteriorates the
performance accuracy of the mixture control system and accordingly the
performance efficiency of the catalytic converter. From the view point of
enabling the catalytic converter to produce its maximum conversion
efficiency, therefore, it is desirable that the exhaust sensor be located
as close to the exhaust ports of the engine cylinders as possible. If,
however, the exhaust sensor is located either in one of the exhaust ports
or at the upstream end of one of the branch portions of the exhaust
manifold, then the information delivered from the exhaust sensor could not
be a faithful representation of the air-to-fuel ratio of the mixture
produced in the mixture supply system because the the mixture delivered
from the mixture supply system is not always distributed uniformly to the
individual cylinders and as a consequence the chemical components of the
exhaust gases from one cylinder are not similarly proportioned to those of
the exhaust gases from another cylinder in a usual multi-cylinder internal
combustion engine. If the exhaust sensor is located downstream of the
catalytic converter, the information produced by the sensor would also be
unreliable because the sensor only detects the composition of the exhaust
gases which have been processed by the catalytic converter.
The temperature of the exhaust gases varies markedly depending upon the
operating conditions of the engine, peaking up when the engine is
operating under full-power conditions. If, therefore, the location of the
exhaust sensor in the exhaust system is selected in consideration of the
temperature range of the exhaust gases under low-to-medium load operating
conditions alone of the engine, the exhaust sensor may be subjected to a
temperature higher than a predetermined range that will enable the sensor
to operate properly. This will critically impair the total performances of
the exhaust sensor and the catalytic converter and, furthermore, shorten
the service life of not only the sensor due to an increased thermal load
but the converter because of an increased amount of burden that will be
imposed on the converter due to increased concentrations of air
contaminative compounds to be processed by the converter.
As is well known in the art, the requirement for the control of vehicular
exhaust emission is far more serious in urban areas where engines are
usually operated under low-to-medium load conditions than in suburban
areas which are less inhabited and in which engines are usually operated
under high-power conditions producing extremely reduced quantities of
noxious compounds in the exhaust gases. From this point of view, the
purpose of controlling the exhaust emission can be practically
accomplished by accurately controlling the air-to-fuel ratio of the
mixture only when the engine is being operated under medium-to-low load
conditions producing exhaust gases having a temperature lower than a
certain limit.
When the temperature of the exhaust gases rises beyond such a level under
high-power conditions of the engine, the exhaust sensor arranged in the
exhaust system on the basis of the above described principle will be
subjected to an increased thermal load that might cause the component
parts of the exhaust sensor to fracture and disable the sensor from
functioning.
The present invention contemplates solution of all these problems that have
been encountered in an automotive internal combustion engine using a known
closed-loop or feedback mixture control system combined in effect with a
catalytic converter.
It is, accordingly, a prime object of the present invention to provide an
improved method of controlling the air-to-fuel ratio of the mixture to be
produced in the mixture supply system of an internal combustion engine of
the type arranged with a catalytic converter in the exhaust system so that
the catalytic converter is enabled to produce its maximum conversion
efficiency against one or more types of air contaminative compounds
contained in the exhaust gases from the engine cylinders.
It is another object of the present invention to provide a method of
controlling the air-to-fuel ratio of the mixture to be produced in the
mixture supply system of an internal combustion engine of the described
type through accurate detection of the conditions of the exhaust gases
especially under medium-to-low load operating conditions of the engine.
Yet, it is another prime object of the present invention to provide an
improved mixture control system adapted to carry the method into practice
in the internal combustion engine of the described type.
In accordance with one important aspect of the present invention, there is
provided in an automotive internal combustion engine including a mixture
supply system for producing from air and fuel delivered thereto an
air-fuel mixture to be fed to the engine cylinders and an exhaust system
having incorporated therein a catalytic converter which is reactive to at
least one type of air contaminative compound in the exhaust gases passed
therethrough and which exhibits its maximum conversion efficiency to the
exhaust gases resulting from a mixture having a predetermined air-to-fuel
ratio, a method of controlling the air-to-fuel ratio of the mixture to be
produced in the mixture supply system comprising detecting the
concentration of at least one type chemical component of the exhaust gases
from the engine cylinders by means of an exhaust sensor located in the
exhaust system downstream of the branch portions of the exhaust maniflod
and upstream of the catalytic converter, producing a signal representative
of the detected concentration of the aforesaid chemical component and
regulating the delivery rate of at least one of air and fuel to the
mixture supply system by means of the signal for thereby controlling the
air-to-fuel ratio of the mixture produced in the mixture supply system
toward the above mentioned predetermined air-to-fuel ratio. The exhaust
sensor is preferably located in that portion of the exhaust system in
which the temperature of the exhaust gases passed therethrough falls
within a predetermined range under low-to-medium load operating conditions
of the engine so that the control system can be accurately responsive to
the conditions of the exhaust gases especially during low-to-medium load
conditions of the engine. To protect the exhaust sensor from being
subjected to excessive thermal load resulting from a rise of temperature
under high-power conditions of the engine, the method according to the
present invention may further comprise detecting high-load operating
conditions of the engine and subjecting the exhaust sensor to a forced
flow of cooling medium externally of the exhaust system under the
high-load operating conditions of the engine.
In accordance with another important aspect of the present invention, there
is provided a mixture control system for an automotive internal combustion
engine including a mixture supply system for producing from air and fuel
delivered thereto an air-fuel mixture to be fed to the engine cylinders
and an exhaust system having incorporated therein a catalytic converter
which is reactive to at least one type of air contaminative compound in
the exhaust gases passed therethrough and which exhibits its maximum
conversion efficiency to the exhaust gases resulting from a mixture having
a predetermined air-to-fuel ratio, the control system comprising
electrically operated valve means for regulating the delivery rate of at
least one of air and fuel to the mixture supply system, an exhaust sensor
arranged in the exhaust system for detecting the concentration of at least
one type of chemical component of the exhaust gases emitted from the
engine cylinders for producing an electrical signal representative of the
detected concentration, the exhaust sensor being located downstream of the
branch portions of the exhaust maniflod and upstream of the catalytic
converter in the exhaust system, and an electric control circuit for
controlling the valve means by the signal from the exhaust sensor so that
the delivery rate of at least one of air and fuel to the mixture supply
system is regulated to control the air-to-fuel ratio of the mixture to be
produced in the mixture supply system toward the above mentioned
predetermined air-to-fuel ratio. In the control system thus arranged, the
exhaust sensor is located preferably in that portion of the exhaust system
in which the temperature of the exhaust gases passed therethrough falls
within a predetermined range under low-to-medium load operating conditions
of the engine as previously mentioned. To protect the exhaust sensor from
an excessive thermal load, the control system may further comprise
passageway means communicating with a source of cooling medium and having
a chamber portion enclosing a portion of the exhaust sensor projecting
externally of the exhaust system, flow inducing means for establishing a
forced flow of the cooling medium through the chamber portion of the
passageway means and control means responsive to high-power conditions of
the engine for actuating the flow inducing means to establish the flow of
the cooling medium in the chamber portion under high-power conditions of
the engine.
The features and advantages of the method and control system according to
the present invention will become more apparent from the following
description taken in conjunction with the accompanying drawings in which
like reference numerals designate similar units, members and elements and
in which:
FIG. 1 is a graph which shows curves indicating representative examples of
the variation in the conversion percentages with respect to air-to-fuel
ratio as achieved by a triple-effect catalytic converter reactive to three
typical types of air contaminative compounds in exhaust gases from an
automotive internal combustion engine;
FIG. 2 is a schematic view showing an internal combustion engine
incorporating a preferred embodiment of the mixture control system
according to the present invention;
FIG. 3 is a partially cut-away external view of an example of an exhaust
sensor employed in the mixture control system of the engine illustrated in
FIG. 2;
FIG. 4 is a graph which shows a curve indicating an example of the waveform
of an output signal produced by the exhaust sensor illustrated in FIG. 3
with respect to air-to-fuel ratio;
FIG. 5 is a block diagram showing a preferred example of an electric
control circuit which may be employed in a mixture control system
embodying the present invention;
FIG. 6 is a schematic view showing an internal combustion engine
incorporating another preferred embodiment of the mixture control system
according to the present invention;
FIG. 7 is a fragmentary sectional view showing part of a preferred example
of an exhaust sensor cooling arrangement incorporated in the mixture
control system illustrated in FIG. 6; and
FIG. 8 is a view similar to FIG. 7 but shows part of another preferred
example of the exhaust sensor cooling arrangement which may be used in a
mixture control system embodying the present invention.
Reference will now be made to the drawings, first to FIG. 1 which shows
curves indicating typical examples of the variation of the percentages of
conversion of hydrocarbons (HC), carbon monoxide (CO) and nitric oxides
(NO.sub.x) in exhaust gases from an automotive gasoline-powered internal
combustion engine as achieved by a tripple-effect catalytic converter when
the air-to-fuel ratio of the mixture supplied to the engine cylinders is
varied in the neighbourhood of the stoichiometric ratio of about 14.8:1.
The percentage of conversion herein referred to is the percentage of the
quantity by weight of the hydrocarbons, carbon monoxide or nitric oxides
converted into harmless compounds (such as water and carbon dioxide from
hydrocarbons or carbon monoxide) by a triple-effect catalytic converter
versus the quantity by weight of each of these air contaminative compounds
contained in the exhaust gases to be passed through the catalytic
converter. From the curves shown, it is evident that the conversion
percentages of hydrocarbons and carbon monoxide increase abruptly and the
conversion percentage of nitric oxides drop abruptly when the air-to-fuel
ratio of the mixture supplied to engine cylinders is increased beyond the
stoichiometric ratio of about 14.8:1 and vice versa. The air-to-fuel ratio
of the mixture providing the best compromise between the acceptable ranges
of the conversion percentages of the three types of air contaminative
compounds is, therefore, approximately 14.8:1, viz., in the vicinity of
the stoichiometric ratio.
If, thus, the air-to-fuel ratio of the mixture supplied to engine cylinders
is controlled in such a manner as to constantly approximate the
stoichiometric ratio in a gasoline-powered internal combustion engine
arranged with a triple-effect catalytic converter in the exhaust system,
the catalytic converter will be enabled to exhibit its maximum total
performance efficiency in processing the above mentioned three types of
air contaminative compounds in the exhaust gases passed through the
converter. If it is desired to achieve higher conversion percentages of
particularly for hydrocarbons and carbon monoxide which are contained in
higher concentrations in the exhaust gases emitted under medium-to-high
load operating conditions of the engine, then the air-to-fuel ratio may be
controlled to be slightly higher than 14.8:1 so as to make the mixture
leaner than the stoichiometric mixure. If, conversely, it is desired to
have nitric oxides processed more efficiently than hydrocarbons and carbon
monoxide with a view to further reducing the concentration of the nitric
oxides which are contained in an increased concentration under full-power
conditions of the engine, then the air-to-fuel ratio may be controlled to
be slightly lower than 14.8:1 to make the mixture richer than the
stoichiometric mixture.
FIG. 2 illustrates an internal combustion engine provided with a
closed-loop or feedback mixture control system arranged to realize the
above described basic principle in controlling the air-to-fuel ratio on
the basis of the information fed back from the exhaust system equipped
with a catalytic converter.
Referring to FIG. 2, an internal combustion engine is shown to be of a
multi-cylinder type having a cylinder block 10 formed with a plurality of
engine cylinders (not shown). Though not shown, these cylinders
communicate across respective intake valves with engine intake ports which
are formed in the cylinder head as is customary in the art. The intake
ports are, in turn, jointly in communication with an intake manifold 12
connected to an air-fuel mixture supply system 14 which may be a
carburetor or of a fuel-injection type. The mixture supply system 14 is
provided with air and fuel delivery means through which air and fuel are
delivered to the mixture supply system 14 so that a mixture of air and
fuel is produced in the system with an air-to-fuel ratio which is dictated
by the ratio between the rates at which air and fuel are delivered into
the system, as well known. The engine cylinders in the cylinder block 10
are, furthermore, in communication across respective exhaust valves with
engine exhaust ports which are usually formed in the cylinder head. The
exhaust ports are, in turn, jointly in communication with an exhaust
manifold 16 having branch portions 16a respectively communicating upstream
with the exhaust ports and a "plenum" tube portion 16b into which the
individual branch portions 16a coverage. The exhaust ports and the exhaust
manifold 16 form part of the exhaust system which further comprises an
exhaust pipe 18 leading from the downstream end of the plenum tube portion
16b of the exhaust manifold 16. The exhaust pipe 18, in turn, leads
through a muffler or mufflers to a tail pipe which is open to the
atmosphere at its terminal end, though not shown.
The exhaust system is arranged with a catalytic converter 20 which is shown
located in the exhaust pipe 18 but which may be located in the plenum tube
portion 16b of the exhaust manifold 16 if desired. The catalytic converter
20 is assumed, by way of example, to be of the previously described
triple-effect type which is capable of processing hydrocarbons, carbon
monoxide and nitric oxides in the exhaust gases passed therethrough. As
previously discussed, the catalytic converter of this type exhibits its
maximum total conversion efficiency in processing the three kinds of air
contaminative compounds particularly when the air-fuel mixture supplied to
the engine cylinders is proportioned to a stoichiometric ratio or to a
ratio which is variable within a certain narrow range containing the
stoichiometric ratio. To achieve this end, the air delivery means or the
fuel delivery means or both of air and fuel delivery means of the mixture
control system 14 are operated under the control of a mixture control
system which comprises an exhaust sensor 22, an electric control circuit
24 and a solenoid-operated valve unit 26. The exhaust sensor 22 is
provided in the exhaust system and detects the concentration of a
predetermined type of chemical component of the exhaust gases emitted from
the engine cylinders. For the purpose of description, the exhaust sensor
22 is assumed to be of the type which is adapted to detect the
concentration of oxygen in the exhaust gases. FIG. 3 illustrates the
construction of a representative example of the exhaust sensor 22 of this
type.
Referring to FIG. 3, the exhaust sensor 22 comprises a tubular electrolytic
element 28 of, for example, sintered zirconium oxide coated with outer and
inner layers 30 and 30' of microporous platinum. The electrolytic element
28 having the platinum layers 30 and 30' is enclosed within a casing 32
formed with a plurality of openings 34. The casing 32 is connected to or
integral with a socket 36 by which the exhaust sensor 22 is mounted on a
predetermined wall portion of the exhaust system so that the casing 32
projects into a passageway portion of the exhaust system. The outer
platinum layer 30 is thus exposed to the exhaust gases admitted into the
casing 32 through the openings 34, while the inner platinum layer 30' is
exposed to atmospheric air through a passageway (not shown) formed in the
socket 36. The solid electrolytic element 28 is oxygen ion conductive at a
temperature within a certain range of, for example, between 400.degree. C
and 900.degree. C and produces between the outer and inner platinum layers
30 and 30' a voltage that varies with the difference between the partial
pressures of oxygen to which the outer and inner platinum layers 30 and
30' are exposed, viz., between the concentration of oxygen in the exhaust
gases and the concentration of oxygen in atmospheric air. The
concentration of oxygen in the exhaust gases varies substantially in
relationship to the air-to-fuel ratio of the mixture combusted in the
engine cylinders and, for this reason, the voltage developed between the
outer and inner platinum layers 30 and 30' varies with the air-to-fuel
ratio fed to the engine cylinders. A typical example of the relationship
between the air-to-fuel ratio and the resultant voltage thus produced by
the exhaust sensor 22 is indicated by the curve shown in FIG. 4. As will
be seen from FIG. 4, the voltage produced by the exhaust sensor 22 is
highly dependent on the air-to-fuel ratio and changes abruptly or
substantially stepwise between the order of 20 milli-volts and the order
of 1000 milli-volts when the air-to-fuel ratio of the mixture is in the
vicinity of the stoichiometric level fo about 14.8:1, reaching
approximately 400 milli-volts at the stoichiometric air-to-fuel ratio.
Though not shown in FIG. 3, the two platinum layers 30 and 30' are
provided with respective contact terminals so that the voltage produced
between the platinum layers is delivered from the exhaust sensor 22 to the
previously mentioned electric control circuit 24 (FIG. 2). The exhaust
sensor 22 has been assumed to be of the type responsive to the oxygen
component of the exhaust gases but, if desired, may be of any other type
responsive to, for example, hydrocarbons, carbon monoxide, carbon dioxide
or nitrogen oxides in the exhaust gases.
FIG. 5 illustrates an example of the electrical arrangement of the control
circuit 24 connected to the exhaust sensor 22 of the nature above
described. The control circuit 24 comprises a comparator 38, a combination
proportional amplifier and integrator 40, a saw-tooth or triangular wave
generator 42 and a pulsewidth modulator 44. The comparator 38 has an input
terminal connected to the output terminal of the above mentioned exhaust
sensor 22 and is supplied therefrom a signal voltage Vo that varies with
the air-to-fuel ratio as indicated by the curve shown in FIG. 4. The
comparator 38 has another input terminal through which a constant
reference voltage Vr is impressed on the comparator 38. The reference
voltage Vr is herein assumed to be set at 400 milli-volts which is
produced when the air-to-fuel ratio is on the stoichiometric level of
about 14.8:1 as above noted with reference to FIG. 4. The comparator 38 is
operative to compare the signal voltage Vo from the exhaust sensor 22 with
the reference voltage Vr and delivers a binary output signal So which
assumes a logic "0" value when the former is higher than the latter (viz.,
when the air-fuel mixture fed to the engine cylinders is richer than the
stoichiometric mixture) and a logic "1" value when the former is lower
than the latter (viz., when the mixture fed to the engine cylinders is
leaner than the stoichiometric mixture). The binary signal So is supplied
to the combination proportional amplifier and integrator 40 which is
arranged to produce a linear ramp signal Si that increases or decreases in
response to the input signal So of the logic "0" or "1" value,
respectively. The saw-tooth or triangular wave generator 42 is operative
to produce a train of saw-tooth or triangular pulses Sp having equal
pulsewidths and a predetermined frequency. The ramp signal Si from the
combination proportional amplifier and integrator 40 and the train of
saw-tooth or triangular pulses Sp from the pulse generator 42 are fed to
the pulse modulator 44. The pulse modulator 44 is, in effect, a comparator
which is operative to compare the ramp signal Si with the saw-tooth or
triangular pulses Sp and produce a train of square-shaped pulses having
positive durations when the pulses Sp are higher in magnitude than the
ramp signal Si. The square-shaped pulses are delivered from the pulse
modulator 44 as the output signal Sc of the control circuit 24 to be
solenoid-operated valve unit 26.
Turning back to FIG. 2, the solenoid-operated valve unit 26 is assumed to
be of a two-position type which is actuated to open and close by the
signal pulses Sc from the control circuit 24 and regulates the rate or
rates at which air and/or fuel are to be delivered into the mixture supply
system 14 in such a manner as to control the air-to-fuel ratio of the
mixture produced in the mixture supply system toward the stoichiometric
ratio of about 14.8:1. The closed-loop or feedback mixture control system
thus controls the air-to-fuel ratio of the mixture to be supplied to the
engine on the basis of the analog signal fed back from the exhaust system
to the mixture supply system for enabling the catalytic converter 20 to
produce its maximum total conversion efficiency.
The performance characterisitics of the closed-loop or feed-back mixture
control system used in combination with the catalytic converter of the
described character are, thus, definitely dictated by the performance of
the exhaust sensor 22 producing a basic signal on the basis of which the
control system is to operate. If, therefore, the exhaust sensor 22 fails
to reliably monitor the air-to-fuel ratio of the mixture due to the time
leg involved in feeding back the information from the exhaust system to
the mixture control system or to the rise of the temperature of the
exhaust gases beyond a predetermined range enabling the sensor to properly
operate as previously discussed, then the mixture control system is
disabled from accurately controlling the air-to-fuel ratio of the mixture
in the mixture supply system 14 and will disable the catalytic converter
20 from achieving its maximum total conversion efficiency especially under
low-to-medium load operating conditions of the engine. When the engine is
being operated under full-power, high-load conditions, the mixture
supplied to the engine cylinders is combusted substantially completely so
that the exhaust gases emitted from the cylinders contain reduced
quantities of unburned combustible residues of hydrocarbons and carbon
monoxide. Under the full-power, high-load op | | |