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Description  |
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BACKGROUND OF THE INVENTION
The present invention relates to coatings and more particularly to a
process for preparing color-developer materials useful as coatings in
pressure-sensitive copy systems.
One type of pressure-sensitive copy paper produces a distinctive color in a
region of localized pressure as a result of an acid-base reaction in the
region. Generally, an electron-donating or basic, colorless, chromogenic
compound reacts with an electron accepting or acidic material in the
region through the medium of a oily, water-immiscible solvent.
This type of pressure-sensitive copy paper may consist of a transferring
paper coated with a layer of microcapsules, containing an
electron-donating, colorless chromogenic compound dissolved in an oily
solvent, and juxtaposed receiving paper coated with a layer of an
electron-accepting material and a suitable binder. When localized pressure
is applied, e.g., by handwriting or typewriting, the microcapsules rupture
in the region under pressure. The colorless chromogenic compound released
from the ruptured microcapsules is transferred to the receiving paper and
reacts with the electron-accepting material to form a definite colored
mark.
A variant form of such pressure-sensitive copy paper consists of a sheet on
which microcapsules containing a chromogenic compound dissolved in an oil
are intermixed with microcapsules containing an electron-accepting
material. Examples of such pressure-sensitive copy papers and
microcapsules are described in U.S. Pat. Nos., 2,712,507; 2,730,456;
2,730,457 and 2,800,457.
Another variant form of such pressure-sensitive copy paper consists of a
sheet on which microcapsules containing a chromogenic compound dissolved
in an oil are coated on a substrate and dried, followed by a second
coating containing an electron-accepting material. An example of such a
pressure-sensitive copy paper is described in U.S. Pat. 3,906,123.
Pressure-sensitive copy papers comprising colorless, chromogenic compounds
and acidic receptor materials on the same surface are known as
"self-contained" systems.
When organic acid compounds or metal salts of organic acid compounds have
been used as an acidic receptor in coatings for pressure-sensitive copy
systems they generally are provided in a finely dispersed form, either by
grinding the organic material together with an extender or by
precipitating it in the presence of an extender. It is important that the
organic acid receptor material be extended with an inert or adsorbent
particulate filler, usually an inorganic filler such as clay or alumina,
to make the most efficient use of the relatively costly organic material
and to present a large surface area for reaction with the oily solution of
basic chromogenic comound to facilitate rapid color development. In one
instance, the organic acidic material has been extended by dissolving it
in finely divided organic polymeric particles, in contrast to the
inorganic extenders commonly used.
A process for making an activated, clay-coated paper for use as a
pressure-sensitive copy paper is described in U.S. Pat. No. 3,928,702.
Acidic activated clay is mixed with a water-dispersible emulsion of a
hydrophobic oily material. This patent is concerned with making the
non-chromogenic acid in the clay more accessible to colorless,
electron-accepting, chromogenic material contained either in microcapsules
or on an independent layer.
It is an object of this invention to provide a uniform distribution of acid
organic acceptor material on an inert or reactive adsorptive, particulate
extender. It is a further object of this invention to provide a means for
dispersing and extending soft, amorphous, oily or tacky organic acid
acceptor materials which would be incompatible or more difficult to
process with a grinding or precipitation method of dispersion.
In addition to pressure-sensitive copy systems, the resulting emulsions or
dispersions also are useful in coatings for heat-sensitive and stencil
copy systems using colorless, chromogenic compounds.
SUMMARY OF THE INVENTION
The present invention is a process wherein an acidic, organic acceptor
material, such as an organic acid compound or a metal compound thereof,
capable of developing an intense persistent color when brought into
contact with a colorless, basic chromogenic material, is dissolved in an
oily, water-immiscible liquid, after which the oily solution is emulsified
in water to form an oil-in-water emulsion. An insoluble, oil-adsorbant
particulate solid is dispersed in the oil-in-water emulsion, and the
resulting emulsion-dispersion is coated on a substrate or is mixed with
other coating materials and dried to produce a highly reactive,
color-developer coating.
In an alternative embodiment of the invention, the oil-in-water emulsion is
mixed with a reactive particulate material which is capable of reacting
with the organic acid material of the metal compound of the organic acid
compound in the emulsion droplets to form an improved color developer. The
resulting emulsion-dispersion optionally may be further extended with an
inert or reactive, oil absorbent particulate extender before formulating
into a coating for a pressure sensitive copy system.
One advantage of the present invention is that soft, amorphous, oily or
tacky materials which are not suitable for grinding or precipitation
methods of dispersion can be easily dispersed to form dry, non-tacky
coatings. Another advantage is that the fluid emulsion droplets can flow
onto the surface of the particulate extender, giving uniform surface
coverage to facilitate rapid color development. Crystals or amorphous
particles produced by grinding or precipitation, or solutions of organic
acid reporter materials dissolved in a polymeric matrix may, in some
cases, develop color from basic, chromogenic compounds more slowly without
the great surface area for reaction provided by the present invention.
Moreover, persistent oily solvents retained in the coating can facilitate
the rapid mixing of acidic and base color-forming reactants. A further
advantage of the present invention is that an improved color developer,
such as the metal salt of an acidic organic compound can be formed "in
situ" by reaction of the oil-in-water emulsion droplets with a reactive
particulate material, thereby eliminating the isolation of the improved
color developer before formulation into a receptor coating in a
pressure-sensitive copy system. In particular, the coating of the present
invention requires only standard mixing equipment for its preparation and
is particularly easy to formulate and coat, as it requires no special
materials, processing or coating steps.
DETAILED DESCRIPTION OF THE INVENTION
The first step in preparing a color-developer coating in accordance with
this invention is the dissolution of an acidic organic material in an
oily, water-immiscible liquid.
Examples of suitable acidic organic materials which are soluble in oily,
water-immiscible liquids are widely available in the literature and
include organic carboxylic acids, such as those described in U.S. Pat.
Nos. 3,488,207 and 3,843,383; metal salts of organic carboxylic acids,
such as those described in U.S. Pat. Nos. 3,843,383; 3,900,215; 3,682,680
and 3,864,146; metallic compounds of polymers of organic carboxylic acids,
such as those described in U.S. Pat. Nos. 3,772,052 and 3,767,449. Also
suitable are phenolic compounds, such as those described in U.S. Pat. Nos.
3,244,550 and 3,244,548; metallic compounds with phenolic materials such
as those described in U.S. Pat. No. 3,834,929; acidic phenolic polymer
resins, such as those described in U.S. Pat. Nos. 3,455,721; 3,672,935;
3,663,256; 3,466,184; 3,649,357 and 3,694,461; or metallic compounds of
phenolic organic polymeric resins such as those described in U.S. Pat.
Nos. 3,723,156 and 3,723,120. Mixtures of two or more oil-soluble, acidic
materials can also be used.
Specific examples of suitable acidic materials include substituted
salicylic acids such as hexadecylsalicylic acid, 5-tert-octylsalicylic
acid, 3,5-di(.alpha.,.alpha.-dimethylbenzyl) salicylic acid,
3,5-dichlorosalicylic acid, 3,5-diisopropylsalicylic acid; substituted
hydroxynaphthoic acids such as
7-(.alpha.,.alpha.-dimethylbenzyl)-1-hydroxynaphthoic acid,
4,7-diisopropyl-1-hydroxy-2-naphthoic acid,
6,8-dioctyl-2-hydroxy-3-naphthoic acid and other hydroxy naphthoic acids
such as 1-hydroxy-2-naphthoic acid, 2-hydroxy-1-naphthoic acid and
3-hydroxy-2-naphthoic acid; polymers of salicylic acid and salicylic acid
derivatives with an aldehyde or an acetylene; phenols; such as
4,4'-isopropylidenediphenol, xylenol, dichlorobiphenol, alkylated
2-naphthol, nonylphenol and the like; phenol aldehyde condensation
polymers derived from cresol, 4,4'-isopropylidenediphenol,
paraphenylphenol and the like.
These materials may be used alone or in combination with a metal ion such
as those derived from zinc, calcium, aluminum, titanium, magnesium,
vanadium, zirconium, manganese, nickel, cobalt, iron, copper and tin.
The oily, water-immiscible material can be any oil in which the selected
acidic material is soluble. Examples of suitable oils include aromatic,
naphthenic and paraffinic oils, esters, ketones, chlorinated hydrocarbons,
mineral oils, phosphate esters and the like, and mixtures thereof.
Specific examples include aromatic oils, such as toluene, xylene, other
alkylated biphenyls, terphenyls, diphenylmethanes and the like, naphthenic
and paraffinic oils and oil blends, motor and lubricating oils, esters
such as phthalate esters, fatty esters, adipate esters, phosphate esters,
such as tricresyl phosphate, polyhalogenated biphenyls, polychlorinated
paraffins and the like.
The second step in the process is the emulsification of the oily solution
of acidic material in water by mixing it under shear with an emulsifying
agent to form an oil-in-water emulsion. The emulsifying agent can be a
polymeric material such as polyvinyl alcohol, gelatin, starch, cellulose
esters or ethers, gums and the like. The emulsifier may also serve as a
binding agent to help adhere the acidic coating to a substrate or other
receptor. Depending on the binding properties of the emulsifier, a
supplementary adhesive may have to be added to the solution.
Alternatively, the emulsifying agent can be a non-adhesive surfactant or
emulsifier suitable for promoting a stable oil-in-water emulsion. Where
such surfactants or emulsifiers are used, a supplementary adhesive is
required to promote binding of the coating to a substrate.
Examples of suitable polymeric emulsifiers having adhesive properties are
polyvinyl alcohol, starches, modified starches such as benzylated starch,
methylcellulose, sodium carboxymethyl cellulose, hydroxyethyl cellulose,
styrene maleic anhydride copolymers, gelatins other animal and vegetable
proteins, gums such as gum arabic, alginates and the like.
Examples of suitable surfactants and emulsifiers which promote the
formation of oil-in-water emulsions, but lack adhesive properties, are
anionic surfactants, such as salts of sulfate and phosphate esters,
sulfonates and the like, and nonionic surfactants, such as
poly(oxyethylene) derivatives of phenols, alcohols, carboxylic acid
derivatives and the like.
An emulsion-dispersion is then formed by thoroughly dispersing an
oil-adsorbent particulate material in the emulsion.
Commercially available oil-adsorbent, particulate materials may be utilized
in the practice of the present invention. Examples of suitable particulate
materials include typical paper coating pigments such as clays, for
example, kaolin, montmorillinite and attapulgite clays, heat-treated
clays, talc, calcium carbonate, zinc oxide, aluminum oxide, satin white,
calcium sulfide and the like. Mixtures of the above materials are also
suitable.
It was found that highly acidic particulate extenders, such as attapulgite
clay and calcined alumina, which themselves react with the basic,
colorless chromogenic compounds to give a colored species and are suitable
alone for use in pressure-sensitive copy systems of this type, actually
produce less color when used in conjunction with an oily solution of
acidic organic material of the invention than inert extenders when used in
conjunction with the same oily solutions of acidic organic material.
Moreover, in comparison with inert particulate extenders, images formed
with coatings containing these acidic, reactive extenders had reduced
resistance to heat and light, the coatings losing some of their
color-developing activity when exposed to heat or light. Presumably the
highly reactive surface of such extenders contribute to decomposition of
the organic acid components of the developer coating.
When the oil-adsorbent material is dispersed in the emulsion, the oily
solution of acidic material in the emulsion droplets readily transfers to
the particles upon contact since the oily solution is not protected by a
substantially impermeable membrane as would be the case for an
encapsulated oil droplet. It is theorized that the oily solution is
transferred to the particulate material either immediately upon mixing or
upon drying to form a color-developer coating. Once the transfer has been
accomplished, the oily solvent may either remain as a residual component
of the receptor sheet or be removed through evaporation, leaving the
acidic material adsorbed on the particulate substrate. Oily solvent
remaining in the receptor sheet can be expected to promote mixing of the
color-forming components.
Alternatively, instead of emulsifying an oily solution of a metal salt of
an organic acidic compound, the metal salt can be formed "in situ" by
adding to the emulsion of the oily solution of acidic organic compound a
metallic compound capable of reacting with the organic compound to form a
metal salt. Thus, a particulate or colloidal metal oxide, hydroxide or
carbonate, for example, can be added to the oil-in-water emulsion where it
can come into contact with the acidic organic compound to form a metal
salt which gives a stronger and more stable color reaction with the basic,
chromogenic compound than the parent organic acid itself.
The preceding description indicates that the oil-adsorbent, particulate
material is added after the oily solution of acidic material is emulsified
in an aqueous solution of the emulsifying agent. However, if desired, the
particulate material can be combined with either the oily solution of
acidic material or with the emulsifying agent before the two are mixed
under shear.
Acidic coatings prepared according to the above-described steps can be used
in a number of ways. Such coatings may be used in conjunction with
coatings containing microcapsules of an oily solution of colorless, basic,
chromogenic material to form a carbonless record system in which the two
types of coating are applied to opposite sides of paper substrates. The
paper substrates are mated to form a pressure-sensitive, mark-forming
manifold. Alternatively , the new acidic coating may be deposited on a
coating containing encapsulated colorless, basic, chromogenic compound to
form a self-contained carbonless record system or such a self-contained
system may be produced by depositing a coating of encapsulated, colorless
basic chromogenic material over an acidic coating prepared in accordance
with the present invention. In another embodiment, microcapsules
containing and completely isolating a colorless, basic, chromogenic
material may be added to the emulsion-dispersion during one step in the
process to form a self-contained coating material.
When localized pressure is applied to a pressure-sensitive sheet or
manifold having the acidic coating, the oily solution of colorless,
chromogenic material is released from ruptured capsules in the region
under pressure. The chromogenic material reacts with the acidic material
adsorbed on the particulate material to form a persistent, colored mark.
Alternatively, oily droplets containing the acidic material may be
entrapped in the binder matrix of the dry receptor coating. The oily
droplets would be released under pressure in a pressure-sensitive,
carbon-less, record system and would be co-adsorbed with the oily solution
of chromogenic material on the particulate oil-adsorbent material of the
receptor coating. In any case, the particulate oil-adsorbent material
provides a substrate for intimate mixing of color-forming components.
Examples of basic chromogenic materials include leuco triarylmethane dyes
such as 3,3-bis(p-dimethylaminophenyl) 6-dimethylaminophthalate (crystal
violet lactone), 3,3-bis(p-dimethylaminophenyl) phthalide (malachite green
lactone), 3-(p-dimethylaminophenyl)-3-(1,2-dimethylindol-3-yl) phthalide,
3-(p-dimethylaminophenyl)-3-(2-phenylindol-3-yl) phthalide
3,3-bis(1,2-dimethylindol-3-yl)-5-dimethylaminophthalide, 3,3-bis
(1,2-dimethylindol-3-yl)-6-dimethylaminophthalide, 3,3-bis
(9-ethylcarbazol-3-yl)-5-dimethylaminophthalide,
3-p-dimethylaminophenyl-3-(1-methylpyrrol-2-yl)-6-dimethylaminophthalide,
7-(1-ethyl-2-methylindol-3-yl)-7-(3-ethoxydiethylaminophen-4-yl)-5,7-dihyd
rofuro [3,4-b] pyrazin-5-one,
3-(p-dimethylaminophenyl)-3-(1-methylpyrrol-2-yl)-4,5,6,7-tetrachlorophtha
lide, 7-(1-ethyl-2-methylindol-3-yl)-7-(3-methyldimethylaminophen-4-yl),
5,7-dihydrofuro [3,4-b] pyridin-7-one,
3-(4-diethylaminophenyl)-3-(1,2-dimethylindol-3-yl) naphthalide;
diphenylmethane compounds such as leuco auramine, N-halophenyl leuco
auramine, 4,4'-bis-dimethylaminobenzhydrine benzyl ether; xanthene
compounds such as rhodamine B lactam, rhodamine B-(p-chloroanilino)
lactam, 7-dimethylamino-2-mathoxyfluoran, 2,2'-iminobis
(6-dimethylaminofluoran),
3-diethylamino-7-(N'-paramethoxyphenyl)piperazinofluoran,
2'-[N-(carbethoxymethyl)amino]-6'-diethylaminofluoran,
6'-diethylamino-2'-[N-(N'-dimethylcarbamoyl)methlamino] fluoran,
6'-diethylamino-2'-(p-nitrobenzenesulfonamido) fluoran; spiropyran and
benzopyran compounds such as 3,3'-dichlorospiro-dinaphthopyran,
3-benzyl-spiro-dinaphthopyran, 3-propyl-spiro-dibenzopyran,
2-(2,5-dichloroanilino)-2-(p-methoxyphenyl)-2(H) benzopyran,
5-dimethylamino-spiro-[isofuran-1(3H)-2'(2H)]-1-benzopyran-3-one; acridan
dyes such as 9-(p-dimethylaminophthalyl-3)-10-methylacridan and others,
including benzoyl leuco methylene blue. Mixtures of colorless, basic
chromogenic compounds are also suitable for use with the coating of the
invention.
DESCRIPTION OF SPECIFIC EMBODIMENTS
The following examples are intended to exemplify the actual practice of the
present invention without limiting the scope of the invention. Unless
otherwise noted, all percentages and parts are by weight.
EXAMPLE 1
A coating emulsion-dispersion was prepared as follows: 9.1 grams of zinc
alkyl salicylate (alkyl = C.sub.16 - C.sub.18 mixture) formed be the
reaction of the corresponding alkyl salicylic acid with zinc acetate in
xylene, were dissolved in 40.9 grams of an oil comprising a mixture of
mono- and diisopropylnaphthalenes. This oil solution then was emulsified,
using a blender, in 36.7 grams of 7% aqueous solution of a high molecular
weight, 87% hydrolyzed Covol 9740 poly(vinyl alcohol), CPC International.
35 grams of water were blended in, and 36.4 grams of kaolin clay were
dispersed in the emulsion. An additional 3 grams of 7% poly(vinyl alcohol)
solution were blended in to complete the emulsion-dispersion. The acidic
receptor sheet was formed by coating the emulsion-dispersion on paper
using a Mayer rod and drying to provide a 2.9 lb./ream (3300 sq. ft.)
coating.
This coating exhibited rapid and intense color development when pressure
mated with a sheet coated with a microencapsulated oil solution of a basic
colorless chromogenic material (crystal violet lactone). The acidic
receptor sheet showed no loss of activity after accelerated aging at
100.degree. C. for 18 hours. The developed crystal violet lactone image
exhibited excellent fade resistance to the action of atmosphere and light.
EXAMPLE 2
A coating emulsion-dispersion was prepared as follows: 9.1 grams of zinc
alkyl salicylate (alkyl = C.sub.16 - C.sub.18 mixture) was dissolved in
40.9 grams of an oil comprising a mixture of mono- and
diisopropylnaphthalenes. This oil solution was emulsified using a blender,
in 107 grams of a 7% solution of Covol 9740 poly(vinyl alcohol). Then,
36.4 grams of kaolin clay and 35 grams of water were blended in to
complete the emulsion-dispersion. The emulsion-dispersion was coated on
paper as described in Example 1 and dried. The resulting product was
substantially indistinguishable from that described in Example 1.
EXAMPLE 3
Ten grams of zinc alkyl salicylate (alkyl = C.sub.16 - C.sub.18 mixture)
were dissolved in 35 grams of xylene. This solution was emulsified, using
a blender, in 107 grams of a 7% solution of Covol 9740 poly(vinyl
alcohol). Next 36.4 grams of kaolin clay and 85 grams of water were
blended in. This emulsion-dispersion was coated onto paper using a Mayer
rod and dried to provide a 2.5 lb./ream coating.
This coating exhibited rapid and intense color development when pressure
mated with a sheet coated with a microencapsulated oil solution of a basic
colorless chromogenic dye precursor (crystal violet lactone). The sheet
showed no loss of activity after accelerated aging at 100.degree. C. for
18 hours. The developed crystal violet lactone image exhibited excellent
fade resistance to the action of atmosphere and light.
EXAMPLE 4
7.0 grams of phenolic novolak resin were dissolved in 38 grams of oil of
the type used in Example 1. This solution was emulsified in 107 grams of
7% solution of Covol 9740 poly(vinyl alcohol). The emulsion was mixed with
36.4 grams of kaolin clay and 100 grams of water. This emulsion-dispersion
was coated onto paper using a Mayer rod and dried to give a coating of 3.0
lb./ream.
The resulting product exhibited color development when pressure mated with
a sheet coated with a microencapsulated oil solution of crystal violet
lactone. The coating showed little loss of activity after accelerated
aging at 100.degree. C. for 18 hours. The developed crystal violet lactone
image exhibited excellent fade resistance to the action of atmosphere and
light.
EXAMPLE 5
Benzoic acid in an amount of 12.2 grams was heated with 11.9 grams of zinc
acetate dihydrate in an oil mixture of 85 grams of oil described in
Example 1 with 50 grams of xylene. 18.5 grams of a phenolic novolak resin
were added and the mixture was heated at reflux, allowing the xylene to
distill off, with the pot reaching a temperature of about 165.degree. C.
45 grams of the resulting mixture were emulsified, using a blender, in 53
grams of a 7% solution of Covol 9740 poly(vinyl alcohol). 35.0 grams of
water and 36.4 grams of heat-treated kaolin clay were blended in to
complete the emulsion-dispersion. This emulsion-dispersion was coated on
paper using a Mayer rod and dried to give a 2.4 lb./ream coating.
The product exhibited rapid and intense color development when pressure
mated with a sheet coated with a microencapsulated oil solution of crystal
violet lactone. The acidic receptor sheet showed no loss of activity after
accelerated aging at 100.degree. C. for 18 hours. The developed crystal
violet lactone image exhibited excellent fade resistance to the action of
atmosphere and light.
EXAMPLE 6
A coating emulsion-dispersion is prepared as in Example 1. Then, 100 grams
of a slurry containing encapsulated crystal violet lactone, which had been
prepared as disclosed in U.S. Pat. No. 2,800,457 are added to 100 grams of
the emulsion-dispersion. The combined emulsion-slurry was coated onto a
substrate and dried to provide a substantially colorless, self-contained
record sheet which, under the force of pressure from a scribe or
typewriter, exhibited rapid and intense color development and showed
little loss of activity after accelerating aging at 100.degree. C. for 3
hours. The developed crystal violet lactone image exhibited excellent fade
resistance to the action of atmosphere and light.
EXAMPLE 7
The emulsion-dispersion of Example 1 was coated onto a substrate previously
coated with microcapsules containing crystal violet lactone, and was
dried. The resulting product was a self-contained, pressure-sensitive
record system which exhibited rapid and intense color development under
pressure and showed little loss of activity of development of premature
coloration after accelerated aging at 100.degree. C for 3 hours.
EXAMPLE 8
6 grams of a 64 percent solution of hexadecysalicylic acid in xylene were
emulsified in 100 milliliters of a 1.4 percent solution of a
high-molecular weight, 87 percent hydrolyzed Covol 9740 poly(vinyl
alcohol.) While maintaining agitation, a slurry of 3 grams of zinc
carbonate in 10 milliliters of water was added, and the
emulsion-dispersion then was heated for about 1/2 hour to distill off the
xylene as an aqueous azeotrope and to promote reaction between the
alkylsalicylic acid and zinc carbonate. 20 grams of paper coating grade of
hydrated alumina were added to the cooled emulsion-slurry, followed by 10
grams of 50 percent solids latex adhesive. This receptor coating was
coated on paper to give an acid receptor sheet. At a dry coat weight of
3.2 pounds/ream, this sheet exhibited excellent image developing
capabilities when pressure mated with a sheet coated with microcapsules
containing an oily solution of crystal violet lactone. The image resisted
fading when exposed to heat and light, and the receptor sheet retained its
color-developing capabilities under the same conditions.
EXAMPLE 9
The procedure of Example 8 was repeated using 3 grams of zinc oxide in
place of the zinc carbonate. The coating showed the same excellent
capability for developing color with crystal violet lactone and, in
addition, showed exceptional resistance of the developed image to fading
when exposed to fluorescent light.
EXAMPLE 10
The procedure of Example 8 was repeated using 3 grams of zinc oxide in
place of the zinc carbonate and 20 grams of flux calcined diatomaceous
earth in place of the hydrated alumina. The coating showed the same
excellent capability for developing color with crystal violet lactone and,
in addition, showed exceptional resistance of the developed image to
fading when exposed to fluorescent light.
While preferred embodiments of the invention have been described in detail,
variations and modifications thereof will occur to those skilled in the
art once they become acquainted with the basic concepts of the invention.
Therefore, it is intended that the appended claims shall be construed to
include all such variations and modifications as fall within the true
spirit and scope of the invention.
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