As improved corrosion inhibitors, reaction products of alkylene oxides and blocked phenols wherein two substituents of the phenol are non-oxyalkylatable, saturated tertiary-amino alkylene groups, and acid-stable salts of these products.
This is a division of application Ser. No. 223,768, filed 2/4/72, now abandoned, which is a continuation of application Ser. No. 763,580, filed Sept. 30, 1968, now abandoned.
A metal article is protected from corrosion under prolonged exposure to normal ambient atmospheric conditions which cause such corrosion by coating the metal article with an adherent organic coating which does not exude corrosive acid, which comprises an effective amount of an aromatic amine compound containing a p-phenylenediamine moiety which is not an epoxy crosslinking agent but which is capable of being oxidized in air, an air oxidation product thereof, or a mixture of the amine and air oxidation product for corrosion protection of the metal article, before the coated metal article is placed in contact with such atmospheric conditions which cause such corrosion.
A composition is provided which, when applied to a metal surface, forms a corrosion-inhibiting film thereon. The composition comprises an epoxy resin, and a petroleum sulfonate, usually in a hydrocarbon diluent. The composition can further comprise a polyamine, an alcohol or both. The composition is applied by contacting the metal surface with the composition as one solution or as a hydrocarbon solution of the epoxy resin and a solution comprising the petroleum sulfonate. The composition is particularly useful in the treatment of downhole metal surfaces in oil and gas wells to inhibit the corrosion of the metal.
A composition is provided which, when applied to a metal surface, forms a corrosion-inhibiting film thereon. The composition comprises an amine, a hydrocarbon or alcohol diluent and carbon dioxide. The composition can be prepared by pressuring carbon dioxide gas into a solution of the amine. The composition is particularly useful in the treatment of down-well metal surfaces in oil and gas wells to inhibit the corrosion of the metal.
A composition is provided which, when applied to a metal surface, forms a corrosion-inhibiting film thereon. The composition comprises an amine, a hydrocarbon or alcohol diluent and carbon dioxide. The composition can be prepared by pressuring carbon dioxide gas into a solution of the amine. The composition is particularly useful in the treatment of down-well metal surfaces in oil and gas wells to inhibit the corrosion of the metal.
Removal of ambient oxygen from aqueous liquids is effectively catalyzed by enzymatic deoxygenation systems comprising alcohol oxidase in the presence of alcohol optionally with catalase. Suitable deoxygenation systems described can be used to alleviate corrosion and oxidative degradation in areas such as oil field fluids, circulating water systems, water storage tanks, alcoholic beverages and foodstuffs. As desired, the enzymatic systems can be immobilized on supports or used in solution.
