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Low energy recovery compounding and fabricating apparatus for plastic materials    
United States Patent4137023   
Link to this pagehttp://www.wikipatents.com/4137023.html
Inventor(s)Moked; Isaac (New Brunswick, NJ); Handwerk; Richard H. (Somerville, NJ); Marshall; Walter R. (Bloomfield, NJ)
AbstractPlastics recovery, compounding and fabricating apparatus is disclosed utilizing a gear pump specially designed to include a media free space between the gear face and side walls with minimum sealing to improve volumetric pump efficiencies and provide pumping capacity insensitivity to viscosity over a wide range.
   














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Drawing from US Patent 4137023
Low energy recovery compounding and fabricating apparatus for plastic

     materials - US Patent 4137023 Drawing
Low energy recovery compounding and fabricating apparatus for plastic materials
Inventor     Moked; Isaac (New Brunswick, NJ); Handwerk; Richard H. (Somerville, NJ); Marshall; Walter R. (Bloomfield, NJ)
Owner/Assignee     Union Carbide Corporation (New York, NY)
Patent assignment
All assignments
Publication Date     January 30, 1979
Application Number     05/783,438
PAIR File History     Application Data   Transaction History
Image File Wrapper   Patent Term   Fees
Litigation
Filing Date     March 31, 1977
US Classification     418/15 366/72 366/102 418/178 418/202 425/376.1 425/382.3
Int'l Classification     F04C 001/10 F04C 015/00 F01C 021/10 B29F 003/00
Examiner     Vrablik; John J.
Assistant Examiner    
Attorney/Law Firm     O'Brien, Jr.; Gerald R.
Address
Parent Case     This application is a continuation-in-part of our prior U.S. application Ser. No. 609,947 filed on Sept. 3, 1975, now U.S. Pat. No. 4,032,391.
Priority Data    
USPTO Field of Search     418/15 418/178 418/202 418/205 418/206 366/71 366/72 366/73 366/91 366/101 366/102 425/376 A
Patent Tags     low energy recovery compounding fabricating plastic materials
   
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What is claimed is:

1. A gear pump for pumping highly viscous media comprising: housing means defining an inlet passage at one end, an outlet passage at an opposite end and a chamber therebetween; a pair of pump gears generally horizontally positioned within said chamber having intermeshing teeth and being rotatably mounted in said housing, said chamber and said pump gears defining therebetween a media free space; said chamber and each of said gears defining gear sealing zones adjacent said outlet passage, each sealing zone having a minimum length equal to the circumferential distance between two adjacent gear teeth across the full axial length of the gears at the outside diameter of said gears; said media free space expanding from the end of said seal zones remote from said outlet passage such that an increasing hydraulic radius is produced at least to the plane of the tops of said gears, said increasing hydraulic radius being produced by an increasing horizontal dimension of the chamber from the end of said seal zones remote from said outlet passage to the plane of the tops of said gears, whereby a pressure gradient is created to fill the gear cavities with said viscous media; said outlet passage adjacent said sealing zones having a cross-sectional area of from 0.2 to 2.0 times the product of the gear width and the gear tooth height; and said chamber increasing in cross-sectional area above the tops of said gears to the top of said chamber, thereby enhancing the pumping capacity and volumetric efficiency of said gear pump.

2. The pump in accordance with claim 1 wherein said outlet is generally rectangular in shape having a width equal to the gear face width and a length equal to the gear tooth height with the major dimension being parallel to the gear axis.

3. The pump of claim 1, wherein the ratio of media free space clearance to the circumferential distance from said seal zone is in the range of about 0.2 to 0.9.

4. The pump of claim 1, wherein said media free space is defined by the interior surface of said housing such that the free space increases in cross section from said seal zone in a smooth continuous curve, to a location upstream of said gears.

5. The pump of claim 1, wherein said housing comprises a pair of modular housing portions defining said media free space at their interior surfaces and symmetrical about the mesh line of said gears; a pair of end structure modules abutting the axial ends of said housing portions and rotatably mounting said gears, said end structures extending beyond said housing portions; and a modular outlet structure nested with the outlet of said housing portions between said end structures, and means interconnecting said modules.

6. The pump of claim 1, further including means in said housing means for introducing an additive to said viscous media.

7. The pump of claim 6, wherein said introducing means includes an extruder having its outlet positioned adjacent said free space and its inlet exterior of said housing.

8. The pump of claim 7, wherein said housing means defines a feedback chamber extending from said pump outlet to a point upstream of said extruder outlet, whereby polymer may be initially mixed with the additive in said extruder.

9. The pump of claim 8, wherein introducing means is positioned to introduce the additive at a location upstream of said chamber.

10. The pump of claim 1, further including a pair of feed rollers rotatably mounted upstream of said pair of gears, the axis of each roller being substantially parallel to the axis of the associated gear, and said rollers being spaced apart to define a media nip substantially coplanar with the mesh line of said gears; said housing means including wiper means adjacent each roller; and means for rotating said rollers to draw said media into and feed said gears.

11. The pump of claim 10, wherein said means for rotating said rollers includes a gear train operatively coupling each roller to its associated gear, whereby the rollers are driven conjointly with said gears.

12. The pump of claim 10, wherein said means for rotating said rollers includes a drive means operatively coupled to said rollers, whereby said rollers are driven independently of said gears.

13. The pump of claim 10, wherein said rollers are modular in construction, whereby the axial length thereof may be varied.

14. The pump of claim 1, wherein said housing is modular and includes two interconnected portions.

15. The pump of claim 14, wherein said housing modular portions are symmetrical about the mesh line of the gears.

16. The pump of claim 14, wherein said housing modular portions are symmetrical about the plane extending transversely to said gear axes.

17. The pump of claim 16, further including modular housing insert means interposed between and complementary to said modular portions.

18. The pump of claim 14, wherein said housing includes removable central insert means, said insert means defining said media free space at their inner surface.

19. The pump of claim 18, wherein said insert means extends the full axial dimension of said gear face width.

20. A gear pump for pumping highly viscous media provided to the pump in rope-like strand form comprising: housing means defining an inlet passage at one end, an outlet passage at an opposite end and a chamber therebetween; a pair of pump gears located within said chamber having intermeshing teeth and being rotatably mounted in said housing, said chamber and said pump gears defining a media free space; said chamber and each of said gears defining gear sealing zones adjacent said outlet passage, each sealing zone having a minimum length equal to the circumferential distance between two adjacent gear teeth across the full axial length of the gears at the outside diameter of said gears; said media free space expanding from the end of said seal zones remote from said outlet passage such that an increasing hydraulic radius is produced at least to the plane of the tops of said gears, said increasing hydraulic radius being produced by a dimension of the chamber measured in a plane parallel to the plane passing through the axes of said gears, said dimension increasing from the end of said seal zones remote from said outlet passage to the plane of the tops of said gears, whereby a pressure gradient is created to fill the gear cavities with said viscous media; said outlet passage adjacent said sealing zones having a cross-sectional area of from 0.2 to 2.0 times the product of the gear width and the gear tooth height; said chamber increasing in cross-sectional area above the tops of said gears to the top of said chamber, thereby enhancing the pumping capacity and volumetric efficiency of said gear pump; and a pair of feed rollers rotatably mounted in said chamber upstream of said gears, the axis of each roller being substantially parallel to the axis of the associated gear and said rollers being spaced apart to define a media nip substantially coplanar with the mesh line of said gears, and means for rotating said gears and rollers, whereby said rope strand is drawn into and feeds the gear cavities and thereafter pumped by said gears.

21. The pump in accordance with claim 20, wherein said outlet is generally rectangular in shape having a width equal to the gear face width and a length equal to the gear tooth height with the major dimension being parallel to the gear axis.

22. The pump of claim 20, wherein the ratio of media free space clearance to the circumferential distance from said seal zone is in the range of about 0.2 to 0.9.

23. The pump of claim 20, wherein said means for rotating said rollers includes a gear train operatively coupling each roller to its associated gear, whereby the rollers are driven conjointly with said gears.

24. The pump of claim 20, wherein wiper means are provided adjacent each of said rollers.
 Description Submit all comments and votes
 


The present invention relates to apparatus for handling polymers and more particularly to apparatus for handling compositions of polymers and volatile constituents, such as polyethylene and ethylene, and means for increasing the efficiency of compounding systems for these compositions.

As employed herein, the term "polymer(s)" is understood to mean organic homopolymers, copolymers, and polymeric mixtures either alone or containing additives of the type normally encountered in the plastics field, e.g., stabilizers, fillers, processing aids, colorants and other additives (such as anti-block, anti-oxidation, anti-static and the like).

BACKGROUND

In the typical production of low density polyethylene, a reactor discharges a stream which is a mixture of polymer and unreacted materials to a product receiver. The product receiver operates at a pressure substantially below the reactor pressure and flow of the reactor discharge is controlled by the product valve. In the product receiver, the major portion of the unreacted materials are removed due to flashing which results from the drop in pressure experienced by the mixture. The flashed material, commonly referred to as the return gas, is subsequently returned to the reactor. The remaining polymerized material settles in the product receiver and still contains some unreacted materials which are removed in the remainder of the polymer recovery system.

The polymer discharged from the product receiver is fed to an extruder through a polymer flow control system. The extruder performs two functions in this system: (1) final devolatilization to remove the remaining unreacted material; (2) pumping of the polymer through a screen pack, if one is being used, and a pelletizer die plate.

The material enters the side of the extruder and the unreacted materials flash and form a foam having a very low density. Therefore an extruder having a very large volumetric conveying capacity in the feed section is necessary to handle the material as the final devolatilization is occurring. Normally, an extruder having a two-diameter screw or an oversize single-diameter screw is necessary to obtain the necessary conveying capacity to handle the material entering the extruder. In some installations a portion of the flashed material is removed from the extruder through a top mounted vent stack.

As the production rate of single low density polyethylene (LDPE) reactors are increased, larger and larger extruders, which become prohibitively expensive, are needed. In an effort to eliminate the use of two-diameter extruders or oversized extruders, some existing units have been modified to include a secondary ethylene separation (flashing) operation upstream of the extruder inlet subsequent to the primary product receiver ethylene separation (flashing) operation.

This system differs from the side fed extruder top mounted vent stack type in that the material is fed into the top of the vent stack and essentially all of the remaining unreacted materials are released before the polymer stream enters the extruder. This provides a material to the extruder which has a much greater density and eliminates the need for two-diameter extruders or large single-diameter extruders. The devolatilization and pumping functions of the original, two-diameter extruder system have now been separated, i.e. the final devolatilization is performed in the vent stack and only the polymer pumping is performed by the extruder. However, extruders pump polymer by developing viscous drag, and are very inefficient pumps.

SUMMARY OF THE INVENTION

The present invention has utility in a plastics recovery system in which polymer produced in a reactor is partially devolatilized in a product receiver, transferred to the top of a vent stack for further devolatilization and flood feed to a low net positive suction head gear pump.

The use of the specially designed gear pump of the present invention having a free filling space surrounding substantially the entire periphery of the gears allows an interaction of the material being pumped caused by the rotating gears and the pump body above the sealing zones to generate pressure above the pump inlet pressure, similar to the pressure generation that occurs in a hydrodynamic bearing, to facilitate filling of the gear tooth cavities. Additionally, the shear areas and energy dissipation in shear is an order of magnitude lower than comparable positive displacement pumps.

Specifically, the gear pump includes a pair of intermeshing, rotatable gears surrounded by a filling chamber increasing in volume toward the pump inlet. Horizontal gear axis orientation is preferred, but not essential. The gears seal with the housing at a minimum seal area sized to seal substantially the distance between adjacent teeth across the fill axial length near the outlet of the pump, said outlet having a cross-sectional area from 0.2 to 2.0 times the product of the gear tooth height and the gear face width.

The outlet is preferably rectangular in shape with the major dimension parallel to the axes of the gears. The outlet may, however, be circular, oval or of any other cross-sectional shape desired from the operating standpoint.

In some polymer processing systems where the polymer is discharged in the form of a rope, a pair of rollers is provided directly above the gears. The rollers pull the polymer rope into a charging area between the rollers and gears to fill the gear cavities and also densify the foamed polymer.

Suitable instrumentation is disclosed for monitoring pump parameters to provide on line viscosity and production rate control.

Thus, the features to be described in greater detail below include a comprehensive low density polymer recovery system which includes a novel gear pump for reduced capital, operational and maintenance cost.

Another feature is a novel gear pump structure for handling a broad range of production rates.

A further feature is a gear pump having roller charging capabilities for pumping polymer material produced in the form of strand or rope.

Yet another feature is the provision of on line additive injection at the pump of a recovery system and modular construction of the pump body, feed gears and rollers.

These and still other features will be readily apparent from the drawings and disclosure to follow.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a schematic view of a low energy recovery system in accordance with the present invention;

FIG. 2 is an enlarged cross-sectional view of a gear pump for use in the low energy recovery system of FIG. 1;

FIG. 3 is a cross-sectional view with certain portions broken away for clarity taken generally along line 3--3 in FIG. 2;

FIG. 4 is a top plane view taken generally along line 4--4 of the pump in FIG. 2;

FIG. 5 is a cross-sectional view of a gear pump with feed rollers for handling feed in rope form;

FIG. 6 is a sectional view taken along line 6--6 in FIG. 5;

FIG. 7 is a top plane view of the pump of FIG. 5;

FIGS. 8A and 8B are schematic views illustrating compounding systems equipped with the pump of FIGS. 2 and 5, respectively;

FIG. 9 is a schematic view illustrating the use of a gear pump of the present invention in combination with an extrusion die or mold in a fabrication process;

FIG. 10 is a cross-sectional view of a modular gear pump with feed rollers wherein the entire inlet/gear cylinder section is replaceable;

FIG. 11 is a sectional view taken along line 11--11 in FIG. 10;

FIG. 12 is a cross-sectional view of a modular gear pump wherein the body is formed by two halves for increasing the gear width by modular additions;

FIG. 13 is a sectional view taken along line 13--13 in FIG. 12;

FIG. 14 is a top plane view of a modular gear pump with feed rollers wherein the gears and rollers are modular for increasing the capacity of the pump;

FIG. 15 is a cross-sectional view taken generally along line 15--15 in FIG. 14;

FIG. 16 is a cross-sectional view taken generally along line 16--16 in FIG. 15;

FIG. 16A is a cross-sectional view similar to FIG. 16, illustrating an external drive for the feed rollers;

FIG. 17 is a side elevation view with certain portions broken away in cross-section illustrating a completely modular gear pump embodiment; and

FIG. 18 is a front elevation view of the pump of FIG. 17 with certain portions broken away in cross-section.

DETAILED DESCRIPTION OF A PREFERRED EMBODIMENT

While this invention is susceptible of embodiment in many different forms, there is shown in the drawings and will hereinafter be described in detail a preferred embodiment of the invention, and modifications thereto, with the understanding that the present disclosure is to be considered as an exemplification of the principles of the invention and is not intended to limit the invention to the embodiments illustrated.

THE RECOVERY SYSTEM

FIG. 1 illustrates an integrated system for the production of low density polyethylene in accordance with the present invention. A composition of liquid polyethylene and entrained ethylene is produced in a reactor (not shown), as is well known in the art. The composition is discharged from the reactor through line 10 into a product receiver 12. The mixture flow to product receiver 12 is controlled by a product valve 14 and a pressure relief valve 16 in line 10. The bulk of the entrained ethylene gas is removed from the mixture by flashing in product receiver 12 and the thus removed ethylene gas is condensed and recycled to the reactor through line 12A for further use. The partially devolatilized polyethylene collects at the lower portion of product receiver 12 and is transferred through line 20 to the inlet of vent stack 22.

Transfer of the liquid polyethylene to the vent stack is accomplished by a pressure gradient which exists between product receiver 12 and vent stack 22. The product receiver operates at pressures in the order of 1000 p.s.i. or higher and the vent stack is operated at pressures at or slightly above or below atmospheric pressure. The flow rate of polyethylene to vent stack 22 is controlled by a feed control valve 24 in line 20, and a sufficient level of liquid polyethylene is maintained in the product receiver to prevent blow through of ethylene directly to the vent stack.

As the polyethylene enters vent stack 22, substantially all of the remaining entrained ethylene flashes from the mixture due to the pressure-equilibrium relationship at the pressure of the vent stack. The low pressure in the vent stack and removal of the ethylene is accomplished through a return line 26 which includes a pumping means 28, such as a venturi nozzle or vacuum line. The return fluid in line 26 is collected for further processing in the reactor.

Polyethylene melt P settles in the vent stack and is allowed to achieve a liquid level L. The lower portion of vent stack 22 is in fluid communication with a gear pump 30, described in greater detail below, through a tapered outlet portion 22A. The level of the liquid polymer in the vent stack is preferably maintained such that polyethylene-ethylene interface is above the pump inlet and the diameter of the vent stack is such that the pressure drop caused by the flowing polymer pool is equal to, preferably less than the pressure head formed by the liquid level of the polymer. Thus, gear pump 30 is flood-fed by the liquid polymer P in the vent stack.

Gear pump 30 is driven by a variable speed drive 32 and torque coupling 34 to withdraw polymer from the lower portion of the vent stack and pump it under pressure through conduit 36 into a pelletizer 38 for final processing and delivery of the polymer to product hopper 40.

Control of the system is provided by a central process control 42 which, in addition to monitoring the function and operation of the reactor, as is known in the industry, monitors and controls the above-mentioned equipment. More specifically, a liquid level controller 44, which may be either of the displacement or rate types, as discussed more fully below, senses the level (or rate of change of level) of polymer in the vent stack. This variable is utilized by the process control 42 to set the variable speed drive 32 to insure flood feed operation and full capacity capability of the pump. Also, the level control may be utilized to provide an indication of production rates, as discussed below.

Additionally, the process control unit monitors power input to the pump, and inlet and outlet pressures and temperatures at the pump through lines 46. The exact instrument for monitoring these variables are well known in the instrumentation art and include torque meters, pressure transducers, either mechanical or electrical, e.g., piezoelectric transducers and thermocouples or thermistors, respectively. From these measured variables on-line viscosity monitoring is achieved. Viscosity is inversely related to the product melt index which is a primary control variable for reactor control in the production of polymers. Thus, these measured variables are fed back in the process control unit 42 to provide control of polymer production in the reactor.

The Gear Pump

FIGS. 2-4 illustrate gear pump 30 specifically designed to provide a minimum net positive suction head and improved polymer pumping capability. Pump 30 is modular in construction and includes an inlet structure 50, gear housing 52, and steam jacket 54. Inlet structure 50 includes two plate-like elements 50A and 50B of generally L-shaped configuration and having interlocking end portions 50C And 50D as best illustrated in FIG. 4. Inlet structure 50 is coupled to a peripheral flange 22B on the outlet of vent stack 22A and to gear housing 52 by a plurality of fasteners 56, FIG. 2.

Gear housing 52 is generally rectangular in outer dimension and includes an upper flange portion 52A, which abuts against the lower surface of inlet structure 50, and sidewalls which define a gear chamber 58 at their inner surface and taper downwardly at two opposite outer surfaces 60 to define the inner surface of the steam chest. The steam jackets 54 are removably mounted to the gear housing 52 by means, not shown, and complement the tapered sides 60 to form a steam chest about the gear pump. The steam jackets include a steam inlet 54A and condensate outlet 54B for admitting steam from a source (not shown) to maintain the pump at a temperature above the melting temperature of the polymer. Alternatively, passageways such as drilling, described below, may be utilized in a solid pump body configuration.

Referring particularly to FIGS. 2 and 3, inlet structure 50 defines an inlet 66 whose width (parallel to the gear axis) is approximately equal to the gear width, FIG. 3, and whose minimum length (normal to the gear axis) taper downwardly to complement the gear chamber 58.

A pair of rotating, intermeshing gears 70 are positioned in gear housing 52. Any one of a wide variety of gear pairs may be employed, intermeshing herringbone gears being preferred.

As shown in FIG. 3, a pair of intermeshing herringbone gears 70 are rotatably mounted in gear housing 52 by means of journal bearings 71 and end plates 72. One of the gears (the drive gear) includes a drive shaft 70A which extends outwardly from the gear pump to be coupled to the torque coupling 34 and thereby provide power input to the pump. The other gear is driven by the intermeshing relationship of the herringbone gears.

Journal bearings 71 are lubricated by the polymer melt, and as discussed below provide a means for monitoring the viscosity of the polymer melt. The length and diameter of the bearings and clearances are such that high pressure leakage is minimized by a throttling effect.

The chamber 58 in which the intermeshing gears 70 are located is designed to achieve an inlet of minimum restriction of polymer flow to improve volumetric efficiency. Substantially all of the faces of the gears are exposed to the media free space (the volume between the gear faces and walls of chamber 58). This configuration permits the development of a pressure gradient within the media free space to facilitate the filling of the gear tooth cavities with polymer.

To achieve the necessary large media free space and still provide the necessary seal between the outlet 103 and the low pressure inlet of the pump, the pump discharge opening 103 and seal zone 74 must be minimized. The portion of outlet 103 in direct communication with the gear chamber defines a generally rectangular shaped opening having a width 103A, FIG. 3, equal to the gear face width and a length 103B, FIG. 2, equal to about the gear tooth height.

The outlet is defined, in part, by high wear resistant seal zone inserts 75, which are removably secured to a seat 58A in the gear housing as by bolts, not shown. Each seal zone extends from the tip 75A of the inserts 75 for a circumferential distance at least equal to the distance between adjacent teeth across the full axial length of the gears to provide an effective seal between the gear teeth and gear housing. The start of the seal zone is generally indicated by numeral 75B, and the seal extends to tip 75A. It should be noted that a seal length larger than that just specified does not significantly increase seal effectiveness.

The inner surface of chamber 58 increases in dimension from the start of the seal 75B in a continuous smooth curve to join the inlet structure chamber 66 just above the top of gears 70. In one pump embodiment the gear chamber or media free space boundary extended from a location 75B 53.degree. below the horizontal passing through the center of gear axis in a circular arc to a location 15.degree. below the horizontal to provide a radial distance between the tooth tip and chamber surface of 1/2 inch at that point, and extended linearly from the 15.degree. point to the top of the pump. In general, the ratio of free media space expansion to the circumferential distance (as measured from the end of seal zone 75B) is optimized in accordance with lubrication theory to achieve an increasing hydraulic radius in the media free space to fill the gear tooth cavities with polymer. The media free space increases from the seal zone 75B to produce a maximum pressure gradient at a point preferably below the horizontal elevation of the gear axes. The optimal media free space configuration is a function of the particular polymer being pumped. A ratio of the clearance (gear tooth tie to chamber wall) to the circumferential distance from the seal zone in the range of about 0.2 to 0.9 is a typical value for polymers having viscosities in the range of 0.2 to 1.4 lb. sec/in.sup.2, respectively.

With particular reference to FIGS. 2 and 3, the outlet 103 changes from the slot-like opening adjacent the gears to a circular discharge outlet 103C at its lower end, which is in fluid communication with conduit 36.

The herringbone gears 70 may have helix angles ranging up to 30.degree.; however, smaller helix angles, 15.degree. or less, are preferred to avoid leakage at gear intermesh. Most preferably, herringbone gears with a helix angle of 7.degree.-10.degree. are used to avoid trapping polymer in the tooth cavities. The use of herringbone pattern gears is preferred to constant helical or spur gears due to reduced stress loading on the gears and housing realized with the herringbone gears.

The use of a gear pump and more particularly a gear pump with herringbone gears provides economic savings in capital cost, operating cost and improved performance in comparison to screw extruders used for the polymer recovery system. More specifically, for a recovery system capable of handling 30-50,000 lbs/hr, system investment cost may be up to 50% less for a gear pump equipped system. In gear pump recovery systems for the indicated capacities, horsepower requirements ranged from 7 to 17 horsepower as opposed to 35 to 60 horsepower for a comparable extruder system. A comparable reduction in shaft horsepower equates to an annual cost savings for a 50,000 lb/hr system in the order of $150,000/year assuming 3.6 cents/kw. hr. electric costs.

Finally, the viscous shear dissipation work is greatly reduced by the use of the gear pump as compared to a screw extruder. The reduction in this work is about one order of magnitude. This reduction, of course, results in a reduction in the temperature rise of the polymer as it passes through the gear pump. Steady state temperature rises of 1.degree. to 4.degree. C. have been experienced with the gear pump of this invention, as compared to 10.degree. to 35.degree. C. for a comparable screw extruder. The reduced temperature rise provides better product property control and less thermal degradation of the polymer product.

The gear tooth helix angle and media free space of the gear pump provide improved handling and volumetric efficiency. Table I indicates a comparison of operating parameters for several configurations which illustrate the effects of gear tooth angle and media free space on gear pump performance. The body types include the one described above and designated as "FULL" and one designated "MIN" which had a media free space inlet dimension located 25.degree. above the horizontal gear axis and extended therefrom in a circular arc to a location 20.degree. below the horizontal gear axis (the start of the seal zone). Each unit was equipped with herringbone gears with the indicated helix angles and identical outlet shapes.

From Table I, it will be noted that the FULL media space configuration, i.e., the least restricted inlet configuration, provided volumetric capacities which were essentially constant for the range of product tested. The gear pump of the present invention is essentially insensitive to viscosity and pressure conditions with respect to its pumping capacity, and its volumetric efficiencies are essentially 100% over a range of gear pitch line velocities up to 150 ft/min.

The designations MIN and FULL as well as the characteristics of the pump structure given in connection with Table I are illustrative embodiments and should not be interpreted as setting forth the limits of applicants' invention. The values listed in the first six columns from left to right represent short tests for peak performance of the gear pump, while the last two columns represent long term steady-state operating conditions for a reactor system having the indicated production rates.

An additional advantage of the gear pump is increased recovery system operation. Unlike a screw extruder system which is highly sensitive to polymer viscosity, the gear pump being a positive displacement pump will continue to pump even if large changes in viscosity are experienced. An extruder on the other hand, would have to be shut down and cleaned, when high or low viscosity are introduced into it. Thus, reactor down time is decreased and reliability is greatly increased with the gear pump.

TABLE I __________________________________________________________________________ Body Type Min. Min. Min. Full Min. Full Full Full __________________________________________________________________________ Gear Angle (Degrees) 30 15 15 15 15 15 15 15 Melt Index 5.7 5.7 2.1 2.1 0.1 0.1 0.1 2.1 Rate (lbs./hr.) 10,000 9,000 8,500 9,000 7,60