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Claims  |
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What is claimed is:
1. A cosmetic composition for treatment of hair comprising a solution in a
solvent selected from the group consisting of water and a hydroalcoholic
solution of a water-soluble crosslinked polymer selected from the group
consisting of
(A) a polyamino-polyamide which is the polycondensate of methyl itaconate
and a mixture of ethylene diamine and diethylene triamine and the said
polyamino-polyamide is crosslinked with a crosslinking agent selected from
the group consisting of epichlorohydrin, methylene bisacrylamide, N,N'-bis
epoxy propyl piperazine and divinyl sulfone; and
(B) the crosslinked polymer of (A) alkylated with an alkylating agent
selected from the group consisting of glycidol, ethylene oxide, propylene
oxide, acrylamide, acrylic acid, chloracetic acid, sodium chloracetate,
propane sultone and butane sultone; said crosslinked polymer being soluble
in water in amounts of 10 weight percent thereof without essentially any
gel formation and a 10 weight percent aqueous solution of said crosslinked
polymer having a viscosity greater than 3 centipoises at 25.degree. C.,
said water soluble crosslinked polymer being present in an amount of about
0.1-5 percent by weight of said composition.
2. A cosmetic composition for treatment of the hair comprising a solution
in a solvent selected from the group consisting of water and a
hydroalcoholic solution of a water-soluble crosslinked polymer selected
from the group consisting of
(A) a polyamino-polyamide which is the polycondensate of methyl acrylate
and a mixture of ethylene diamine and diethylene triamine and the said
polyamino-polyamide is crosslinked with a crosslinking agent selected from
the group consisting of epichlorohydrin, methylene bisacrylamide, N,N'-bis
epoxy propyl piperazine and divinyl sulfone; and
(B) the crosslinked polymer of (A) alkylated with an alkylating agent
selected from the group consisting of glycidol, ethylene oxide, propylene
oxide, acrylamide, acrylic acid, chloracetic acid, sodium chloracetate,
propane sultone and butane sultone; said crosslinked polymer being soluble
in water in amounts of 10 weight percent thereof without essentially any
gel formation and a 10 weight percent aqueous solution of said crosslinked
polymer having a viscosity greater than 3 centipoises at 25.degree. C.,
said water soluble crosslinked polymer being present in an amount of about
0.1-5 percent by weight of said composition.
3. A cosmetic composition for treatment of the hair comprising a solution
in a solvent selected from the group consisting of water and a
hydroalcoholic solution of a water-soluble crosslinked polymer selected
from the group consisting of
(A) a polyamino-polyamide which is the polycondensate of methyl
methacrylate and a mixture of ethylene diamine and diethylene triamine and
the said polyamino-polyamide is crosslinked with a crosslinking agent
selected from the group consisting of epichlorohydrin, methylene bis
acrylamide, N,N'-bis epoxy propyl piperazine and divinyl sulfone; and
(B) the crosslinked polymer of (A) alkylated with an alkylating agent
selected from the group consisting of glycidol, ethylene oxide, propylene
oxide, acrylamide, acrylic acid, chloracetic acid, sodium chloracetate,
propane sultone and butane sultone; said crosslinked polymer being soluble
in water in amounts of 10 weight percent thereof without essentially any
gel formation and a 10 weight percent aqueous solution of said crosslinked
polymer having a viscosity greater than 3 centipoises at 25.degree. C.,
said water soluble crosslinked polymer being present in an amount of about
0.1-5 percent by weight of said composition.
4. A cosmetic composition for treatment of the hair comprising a solution
in a solvent selected from the group consisting of water and a
hydroalcoholic solution of a water-soluble crosslinked polymer, said
polymer being a polyamino-polyamide comprising a polycondensate of (a) an
acidic compound selected from the group consisting of (i) an organic
dicarboxylic acid selected from the group consisting of a saturated
aliphatic dicarboxylic acid, having from 6 to 10 carbon atoms and an
aromatic dicarboxylic acid, (ii) an ethylenically unsaturated carboxylic
acid selected from the group consisting of acrylic acid, methacrylic acid
and itaconic acid, (iii) an ester of said acids of (i) and (ii), and (iv)
mixtures of (i), (ii) and (iii) and (b) a polyamine selected from the
group consisting of (1) diethylene triamine, (2) dipropylene triamine, (3)
triethylene tetramine and (4) a mixture with at least one of (1), (2) and
(3) with a member selected from the group consisting of ethylene diamine,
hexamethylene diamine and piperazine, said polyamine (b) being replaceable
by a member selected from the group consisting of (1) 0-20 mole percent
hexamethylene diamine, (2) 0-40 mole percent ethylene diamine and (3) 0-40
mole percent piperazine, said polyamino-polyamide being crosslinked with a
crosslinking agent being selected from the group consisting of
epichlorohydrin, diglycidyl ether, N,N'-bis-epoxypropyl piperazine, the
dianhydride of butane tetracarboxylic acid, the dianhydride of
pyromellitic acid, divinyl sulfone and methylene bisacrylamide, and being
employed in an amount of 0.025-0.35 mole per amine group in said
polyamino-polyamide, said crosslinked polyamino-polyamide being alkylated
with an alkylating agent selected from the group consisting of glycidol,
ethylene oxide, propylene oxide, acrylamide, acrylic acid, chloroacetic
acid, propane sulfone, and butane sulfone; said crosslinked polymer being
soluble in water in amounts of 10 weight percent thereof without
essentially any gel formation and a 10 weight percent aqueous solution of
said crosslinked polymer having a viscosity greater than 3 centipoises at
25.degree. C., said water soluble crosslinked polymer being present in an
amount of about 0.1-5 percent by weight of said composition.
5. A cosmetic composition for treatment of the hair comprising a solution
in a solvent selected from the group consisting of water and a
hydroalcoholic solution of a water-soluble crosslinked polymer selected
from the group consisting of
(A) a polyamino-polyamide which is the polycondensate of (a) an acidic
compound selected from the group consisting of (i) an organic dicarboxylic
acid selected from the group consisting of a saturated aliphatic
dicarboxylic acid having from 6 to 10 carbon atoms and an aromatic
dicarboxylic acid, (ii) an ethylenically unsaturated carboxylic acid
selected from the group consisting of acrylic acid, methacrylic acid and
itaconic acid, (iii) an ester of said acids of (i) and (ii), (iv) mixtures
of (i), (ii) and (iii) and (v) the intermediate product of addition of one
mole of ethylene diamine and two moles of a methyl ester of (ii) obtained
at a temperature between 5.degree.-80.degree. C., and (b) a polyamine
selected from the group consisting of (1) diethylene triamine, (2)
dipropylene triamine, (3) triethylene tetramine and (4) a mixture of at
least one of (1), (2) and (3) with a member selected from the group
consisting of ethylene diamine, hexamethylenediamine and piperazine, said
polyamine (b) being replaceable by a member selected from the group
consisting of (1) 0-20 mole percent hexamethylene diamine, (2) 0-40 mole
percent ethylene diamine and (3) 0-40 mole percent piperazine wherein the
polycondensate is formed at a temperature of 80.degree.-250.degree. C.,
said polyamino-polyamide being crosslinked with a crosslinking agent being
selected from the group consisting of epichlorohydrin, diglycidyl ether,
N,N'-bis-epoxypropyl piperazine, the dianhydride of butane tetracarboxylic
acid, the dianhydride of pyromellitic acid, divinyl sulfone and methylene
bisacrylamide, and being employed in an amount of 0.025-0.35 mole per
amine group in said polyamino-polyamide; and
(B) the crosslinked polymer of (A) alkylated with an alkylating agent
selected from the group consisting of glycidol, ethylene oxide, propylene
oxide, acrylamide, acrylic acid, chloracetic acid, sodium chloracetate,
propane sultone and butane sultone, said crosslinked polymer being soluble
in water in an amount of 10 weight percent thereof without essentially any
gel formation and a 10 weight percent aqueous solution of said crosslinked
polymer having a viscosity greater than 3 centipoises at 25.degree. C.,
said water soluble crosslinked polymer being present in an amount of about
0.1-5 percent by weight of said composition, and
an effective amount of a surface active agent selected from the group
consisting of nonionic, anionic, cationic, amphoteric and zwitterionic
surface active agents.
6. The composition of claim 5 wherein said polyamino-polyamide is
crosslinked with 0.025 up to about 0.1 mole of said crosslinking agent per
amine group in said polyamino-polyamide.
7. A cosmetic composition for treatment of the hair comprising a solution
in a solvent selected from the group consisting of water and a
hydroalcoholic solution of a water-soluble crosslinked polymer selected
from the group consisting of
(A) a polyamino-polyamide which is the polycondensate of (a) adipic acid
and (b) a polyamine selected from the group consisting of (1) diethylene
triamine, (2) dipropylene triamine, (3) triethylene tetramine and (4) a
mixture of at least one of (1), (2) and (3) with a member selected from
the group consisting of ethylene diamine, hexamethylenediamine and
piperazine, said polyamine (b) being replaceable by a member selected from
the group consisting of (1) 0-20 mole percent hexamethylene diamine, (2)
0-40 mole percent ethylene diamine and (3) 0-40 mole percent piperazine,
wherein said polycondensate is formed at a temperature of 80.degree. to
250.degree. C., said polyamino-polyamide being crosslinked with a
crosslinking agent being selected from the group consisting of
epichlorohydrin, diglycidyl ether, N,N'-bis-epoxypropyl piperazine, the
dianhydride of butane tetracarboxylic acid, the dianhydride of
pyromellitic acid, divinyl sulfone and methylene bisacrylamide, and being
employed in an amount of 0.025-0.35 mole per amine group in said
polyamino-polyamide; and
(B) the crosslinked polymer of (A) alkylated with an alkylating agent
selected from the group consisting of glycidol, ethylene oxide, propylene
oxide, acrylamide, acrylic acid, chloracetic acid, sodium chloracetate,
propane sultone and butane sultone, said crosslinked polymer being soluble
in water in an amount of 10 weight percent thereof without essentially any
gel formation and a 10 weight percent aqueous solution of said crosslinked
polymer having a viscosity greater than 3 centipoises at 25.degree. C.,
said water soluble crosslinked polymer being present in an amount of about
0.1-5 percent by weight of said composition, and
an effective amount of a surface active agent selected from the group
consisting of nonionic, anionic, cationic, amphoteric and zwitterionic
surface active agents, wherein said polyamino-polyamide is crosslinked
with 0.025 up to about 0.1 mole of said crosslinking agent per amine group
in said polyamino-polyamide.
8. A cosmetic composition for treatment of the hair comprising a solution
in a solvent selected from the group consisting of water and a
hydroalcoholic solution of a water-soluble crosslinked polymer selected
from the group consisting of
(A) a polyamino-polyamide which is the polycondensate of (a) an acidic
compound selected from the group consisting of (i) an organic dicarboxylic
acid selected from the group consisting of a saturated aliphatic
dicarboxylic acid having from 6 to 10 carbon atoms and an aromatic
dicarboxylic acid, (ii) an ethylenically unsaturated carboxylic acid
selected from the group consisting of acrylic acid, methacrylic acid and
itaconic acid, (iii) an ester of said acids of (i) and (ii), (iv) mixtures
of (i), (ii) and (iii) and (v) the intermediate product of addition of one
mole of ethylene diamine and two moles of a methyl ester of (ii) obtained
at a temperature between 5.degree.-80.degree. C., and (b) a polyamine
selected from the group consisting of (1) diethylene triamine, (2)
dipropylene triamine, (3) triethylene tetramine and (4) a mixture of at
least one of (1), (2) and (3) with a member selected from the group
consisting of ethylene diamine, hexamethylenediamine and piperazine, said
polyamine (b) being replaceable by a member selected from the group
consisting of (1) 0-20 mole percent hexamethylene diamine, (2) 0-40 mole
percent ethylene diamine and (3) 0-40 mole percent piperazine, wherein the
polycondensate is formed at a temperature of 80.degree.-250.degree. C.,
said polyamino-polyamide being crosslinked with a crosslinking agent being
selected from the group consisting of epichlorohydrin, diglycidyl ether,
N,N'-bis-epoxypropyl piperazine, the dianhydride of butane tetracarboxylic
acid, the dianhydride of pyromellitic acid, divinyl sulfone and methylene
bisacrylamide, and being employed in an amount of 0.025-0.35 mole per
amine group in said polyamino-polyamide; and
(B) the crosslinked polymer of (A) alkylated with an alkylating agent
selected from the group consisting of glycidol, ethylene oxide, propylene
oxide, acrylamide, acrylic acid, chloracetic acid, sodium chloracetate,
propane sultone and butane sultone, said crosslinked polymer being soluble
in water in an amount of 10 weight percent thereof without essentially any
gel formation and a 10 weight percent aqueous solution of said crosslinked
polymer having a viscosity greater than 3 centipoises at 25.degree. C.,
said water soluble crosslinked polymer being present in an amount of about
0.1-5 percent by weight of said composition, and
an effective amount of a cosmetic resin.
9. The composition of claim 8 wherein said polyamino-polyamide is
crosslinked with 0.25 up to about 0.1 mole of said crosslinking agent per
amine group in said polyamino-polyamide.
10. A cosmetic composition for treatment of the hair comprising a solution
in a solvent selected from the group consisting of water and a
hydroalcoholic solution of a water-soluble crosslinked polymer selected
from the group consisting of
(A) a polyamino-polyamide which is the polycondensate of (a) adipic acid
and (b) a polyamine selected from the group consisting of (1) diethylene
triamine, (2) dipropylene triamine, (3) triethylene tetramine and (4) a
mixture of at least one of (1), (2) and (3) with a member selected from
the group consisting of ethylene diamine, hexamethylenediamine and
piperazine, said polyamine (b) being replaceable by a member selected from
the group consisting of (1) 0-20 mole percent hexamethylene diamine, (2)
0-40 mole percent ethylene diamine and (3) 0-40 mole percent piperazine,
wherein the polycondensate is formed at 80.degree.-25.degree. C., said
polyamino-polyamide being crosslinked with a crosslinking agent being
selected from the group consisting of epichlorohydrin, diglycidyl ether,
N,N'-bis-epoxypropyl piperazine, the dianhydride of butane tetracarboxylic
acid, the dianhydride of pyromellitic acid, divinyl sulfone and methylene
bisacrylamide, and being employed in an amount of 0.025-0.35 mole per
amine group in said polyamino-polyamide; and
(B) the crosslinked polymer of (A) alkylated with an alkylating agent
selected from the group consisting of glycidol, ethylene oxide, propylene
oxide, acrylamide, acrylic acid, chloracetic acid, sodium chloracetate,
propane sultone and butane sultone, said crosslinked polymer being soluble
in water in an amount of 10 weight percent thereof without essentially any
gel formation and a 10 weight percent aqueous solution of said crosslinked
polymer having a viscosity greater than 3 centipoises at 25.degree. C.,
said water soluble crosslinked polymer being present in an amount of about
0.1-5 percent by weight of said composition, and
an effective amount of a cosmetic resin, wherein said polyamino-polyamide
is crosslinked with 0.025 up to about 0.1 mole of said crosslinking agent
per amine group in said polyamino-polyamide.
11. A cosmetic composition for treatment of the hair comprising a solution
in a solvent selected from the group consisting of water and a
hydroalcoholic solution of a water-soluble crosslinked polymer selected
from the group consisting of
(A) a polyamino-polyamide which is the polycondensate of (a) an acidic
compound selected from the group consisting of (i) an organic dicarboxylic
acid selected from the group consisting of a saturated aliphatic
dicarboxylic acid having from 6 to 10 carbon atoms and an aromatic
dicarboxylic acid, (ii) an ethylenically unsaturated carboxylic acid
selected from the group consisting of acrylic acid, methacrylic acid and
itaconic acid, (iii) an ester of said acids of (i) and (ii), (iv) mixtures
of (i), (ii) and (iii) and (v) the intermediate product of addition of one
mole of ethylene diamine and two moles of a methyl ester of (ii) obtained
at a temperature between 5.degree.-80.degree. C., and (b) a polyamine
selected from the group consisting of (1) diethylene triamine, (2)
dipropylene triamine, (3) triethylene tetramine and (4) a mixture of at
least one of (1), (2) and (3) with a member selected from the group
consisting of ethylene diamine, hexamethylenediamine and piperazine, said
polyamine (b) being replaceable by a member selected from the group
consisting of (1) 0-20 mole percent hexamethylene diamine, (2) 0-40 mole
percent ethylene diamine and (3) 0-40 mole percent piperazine, wherein the
polycondensate is formed at a temperature of 80.degree.-250.degree. C.,
said polyamino-polyamide being crosslinked with a crosslinking agent being
selected from the group consisting of epichlorohydrin, diglycidyl ether,
N,N'-bis-epoxypropyl piperazine, the dianhydride of butane tetracarboxylic
acid, the dianhydride of pyromellitic acid, divinyl sulfone and methylene
bisacrylamide, and being employed in an amount of 0.025-0.35 mole per
amine group in said polyamino-polyamide; and
(B) the crosslinked polymer of (A) alkylated with an alkylating agent
selected from the group consisting of glycidol, ethylene oxide, propylene
oxide, acrylamide, acrylic acid, chloracetic acid, sodium chloracetate,
propane sultone and butane sultone, said crosslinked polymer being soluble
in water in an amount of 10 weight percent thereof without essentially any
gel formation and a 10 weight percent aqueous solution of said crosslinked
polymer having a viscosity greater than 3 centipoises at 25.degree. C.,
said water soluble crosslinked polymer being present in an amount of about
0.1-5 percent by weight of said composition, and
an effective amount of dimethylol ethylene thiourea to reinforce the
keratinic chain of the hair.
12. The composition of claim 11 wherein said polyamino-polyamide is
crosslinked with 0.025 up to about 0.1 of said crosslinking agent per
amine group in said polyamino-polyamide.
13. A cosmetic composition for treatment of the hair comprising a solution
in a solvent selected from the group consisting of water and a
hydroalcoholic solution of a water-soluble crosslinked polymer selected
from the group consisting of
(A) a polyamino-polyamide which is the polycondensate of (a) adipic acid
and (b) a polyamine selected from the group consisting of (1) diethylene
triamine, (2) dipropylene triamine, (3) triethylene tetramine and (4) a
mixture of at least one of (1), (2) and (3) with a member selected from
the group consisting of ethylene diamine, hexamethylenediamine and
piperazine, said polyamine (b) being replaceable by a member selected from
the group consisting of (1) 0-20 mole percent hexamethylene diamine, (2)
0-40 mole percent ethylene diamine and (3) 0-40 mole percent piperazine,
wherein the polycondensate is formed at 80.degree. to 250.degree. C., said
polyamino-polyamide being crosslinked with a crosslinking agent being
selected from the group consisting of epichlorohydrin, diglycidyl ether,
N,N'-bis-epoxypropyl piperazine, the dianhydride of butane tetracarboxylic
acid, the dianhydride of pyromellitic acid, divinyl sulfone and methylene
bisacrylamide, and being employed in an amount of 0.025-0.35 mole per
amine group in said polyamino-polyamide; and
(B) a crosslinked polymer of (A) alkylated with an alkylating agent
selected from the group consisting of glycidol, ethylene oxide, propylene
oxide, acrylamide, acrylic acid, chloracetic acid, sodium chloracetate,
propane sultone and butane sultone, said crosslinked polymer being soluble
in water in an amount of 10 weight percent thereof without essentially any
gel formation and a 10 weight percent aqueous solution of said crosslinked
polymer having a viscosity greater than 3 centipoises at 25.degree. C.,
said water soluble crosslinked polymer being present in an amount of about
0.1-5 percent by weight of said composition, and
an effective amount of dimethylol ethylene thiourea to reinforce the
keratinic chain of the hair,
wherein said polyamino-polyamide is crosslinked with 0.025 up to about 0.1
mole of said cross-linking agent per amine group in said
polyamino-polyamide.
14. A cosmetic composition for treatment of the hair comprising a solution
in a solvent selected from the group consisting of water and a
hydroalcoholic solution of a water-soluble crosslinked polymer selected
from the group consisting of
(A) a polyamino-polyamide which is the polycondensate of (a) an acidic
compound selected from the group consisting of (i) an organic dicarboxylic
acid selected from the group consisting of a saturated aliphatic
dicarboxylic acid having from 6 to 10 carbon atoms and an aromatic
dicarboxylic acid, (ii) an ethylenically unsaturated carboxylic acid
selected from the group consisting of acrylic acid, methacrylic acid and
itaconic acid, (iii) an ester of said acids of (i) and (ii), (iv) mixtures
of (i), (ii) and (iii) and (v) the intermediate product of addition of one
mole of ethylene diamine and two moles of a methyl ester of (ii) obtained
at a temperature between 5.degree.-80.degree. C., and (b) a polyamine
selected from the group consisting of (1) diethylene triamine, (2)
dipropylene triamine, (3) triethylene tetramine and (4) a mixture of at
least one of (1), (2) and (3) with a member selected from the group
consisting of ethylene diamine, hexamethylenediamine and piperazine, said
polyamine (b) being replaceable by a member selected from the group
consisting of (1) 0-20 mole percent hexamethylene diamine, (2) 0-40 mole
percent ethylene diamine and (3) 0-40 mole percent piperazine, wherein the
polycondensate is formed at a temperature of 80.degree.-250.degree. C.,
said polyamino-polyamide being crosslinked with a crosslinking agent being
selected from the group consisting of epichlorohydrin, diglycidyl ether,
N,N'-bis-epoxypropyl piperazine, the dianhydride of butane tetracarboxylic
acid, the dianhydride of pyromellitic acid, divinyl sulfone and methylene
bisacrylamide, and being employed in an amount of 0.025.degree.-0.35 mole
per amine group in said polyamino-polyamide; and
(B) the crosslinked polymer of (A) alkylated with an alkylating agent
selected from the group consisting of glycidol, ethylene oxide, propylene
oxide, acrylamide, acrylic acid, chloracetic acid, sodium chloracetate,
propane sultone and butane sultone, said crosslinked polymer being soluble
in water in an amount of 10 weight percent thereof without essentially any
gel formation and a 10 weight percent aqueous solution of said crosslinked
polymer having a viscosity greater than 3 centipoises at 25.degree. C.,
said water soluble crosslinked polymer being present in an amount of about
0.1-5 percent by weight of said composition, and
an effective amount of a water-soluble electrolyte so as to reduce the
tendency of said polyamino-polyamide to fix durably on the hair.
15. The composition of claim 14 wherein said polyamino-polyamide is
crosslinked with 0.025 up to about 0.1 mole of said crosslinking agent per
amine group in said polyamino-polyamide.
16. A cosmetic composition for treatment of the hair comprising a solution
in a solvent selected from the group consisting of water and a
hydroalcoholic solution of a water-soluble crosslinked polymer selected
from the group consisting of
(A) a polyamino-polyamide which is the polycondensate of (a) adipic acid
and (b) a polyamide selected from the group consisting of (1) diethylene
triamine, (2) dipropylene triamine, (3) triethylene tetramine and (4) a
mixture of at least one of (1), (2) and (3) with a member selected from
the group consisting of ethylene diamine, hexamethylenediamine and
piperazine, said polyamine (b) being replaceable by a member selected from
the group consisting of (1) 0-20 mole percent hexamethylene diamine, (2)
0-40 mole percent ethylene diamine and (3) 0-40 mole percent piperazine,
wherein the polycondensate is formed at 80.degree.-250.degree. C., said
polyamino-polyamide being crosslinked with a crosslinking agent being
selected from the group consisting of epichlorohydrin, diglycidyl ether,
N,N'-bis-epoxypropyl piperazine, the dianhydride of butane tetracarboxylic
acid, the dianhydride of pyromellitic acid, divinyl sulfone and methylene
bisacrylamide, and being employed in an amount of 0.025-0.35 mole per
amine group in said polyamino-polyamide; and
(B) the crosslinked polymer of (A) alkylated with an alkylating agent
selected from the group consisting of glycidol, ethylene oxide, propylene
oxide, acrylamide, acrylic acid, chloracetic acid, sodium chloracetate,
propane sultone and butane sultone, said crosslinked polymer being soluble
in water in an amount of 10 weight percent thereof without essentially any
gel formation and 10 weight percent aqueous solution of said crosslinked
polymer having a viscosity greater than 3 centipoises at 25.degree. C.,
said water soluble crosslinked polymer being present in an amount of about
0.1-5 percent by weight of said composition, and
an effective amount of a water-soluble electrolyte so as to reduce the
tendency of said polyamino-polyamide to fix durably on the hair,
wherein said polyamino-polyamide is crosslinked with 0.025 up to about 0.1
mole of said crosslinking agent per amine group of said
polyamino-polyamide.
17. A cosmetic composition for treatment of the hair comprising a solution
in a solvent selected from the group consisting of water and a
hydroalcoholic solution of a water-soluble crosslinked polymer selected
from the group consisting of
(A) a polyamino-polyamide which is the polycondensate of (a) an acidic
compound selected from the group consisting of (i) an organic dicarboxylic
acid selected from the group consisting of a saturated aliphatic
dicarboxylic acid having from 6 to 10 carbon atoms and an aromatic
dicarboxylic acid, (ii) an ethylenically unsaturated carboyxlic acid
selected from the group consisting of acrylic acid, methacrylic acid and
itaconic acid, (iii) an ester of said acids of (i) and (ii), (iv) mixtures
of (i), (ii) and (iii) and (v) the intermediate product of addition of one
mole of ethylene diamine and two moles of a methyl ester of (ii) obtained
at a temperature of 5.degree.-80.degree. C., and (b) a polyamine selected
from the group consisting of (1) diethylene triamine, (2) dipropylene
triamine, (3) triethylene tetramine and (4) a mixture of at least one of
(1), (2) and (3) with a member selected from the group consisting of
ethylene diamine, hexamethylenediamine and piperazine, said polyamine (b)
being replaceable by a member selected from the group consisting of (1)
0-20 mole percent hexamethylene diamine, (2) 0-40 mole percent ethylene
diamine and (3) 0-40 mole percent piperazine, wherein the polycondensate
is formed at a temperature of 80.degree.-250.degree. C., said
polyamino-polyamide being crosslinked with a crosslinking agent being
selected from the group consisting of epichlorohydrin, diglycidyl ether,
N,N'-bis-epoxypropyl piperazine, the dianhydride of butane tetracarboxylic
acid, the dianhydride of pyromellitic acid, divinyl sulfone and methylene
bisacrylamide, and being employed in an amount of 0.025-0.35 mole per
amine group in said polyamino-polyamide; and
(B) the crosslinked polymer of (A) alkylated with an alkylating agent
selected from the group consisting of glycidol, ethylene oxide, propylene
oxide, acrylamide, acrylic acid, chloracetic acid, sodium chloracetate,
propane sultone and butane sultone, said crosslinked polymer being soluble
in water in an amount of 10 weight percent thereof without essentially any
gel formation and a 10 weight percent aqueous solution of said crosslinked
polymer having a viscosity greater than 3 centipoises at 25.degree. C.,
said water soluble crosslinked polymer being present in an amount of about
0.1-5 percent by weight of said composition, and
a mixture consisting essentially of an effective amount of each of
hydroxyethyl cellulose and silicone oil to provide a hair setting
composition.
18. The composition of claim 17 wherein said polyamino-polyamide is
crosslinked with 0.025 up to about 0.1 mole of said crosslinking agent per
amine group in said polyamino-polyamide.
19. A cosmetic composition for treatment of the hair comprising a solution
in a solvent selected from the group consisting of water and a
hydroalcoholic solution of a water-soluble crosslinked polymer selected
from the group consisting of
(A) a polyamino-polyamide which is the polycondensate of (a) adipic acid
and (b) a polyamine selected from the group consisting of (1) diethylene
triamine, (2) dipropylene triamine, (3) triethylene tetramine and (4) a
mixture of at least one of (1), (2) and (3) with a member selected from
the group consisting of ethylene diamine, hexamethylenediamine and
piperazine, said polyamine (b) being replaceable by a member selected from
the group consisting of (1) 0-20 mole percent hexamethylene diamine, (2)
0-40 mole percent ethylene diamine and (3) 0-40 mole percent piperazine,
wherein the polycondensate is formed at 80.degree. to 250.degree. C., said
polyamino-polyamide being crosslinked with a crosslinking agent being
selected from the group consisting of epichlorohydrin, diglycidyl ether,
N,N'-bis-epoxypropyl piperazine, the dianhydride of butane tetracarboxylic
acid, the dianhydride of pyromellitic acid, divinyl sulfone and methylene
bisacrylamide, and being employed in an amount of 0.025-0.35 mole per
amine group in said polyamino-polyamide; and
(B) the crosslinked polymer of (A) alkylated with an alkylating agent
selected from the group consisting of glycidol, ethylene oxide, propylene
oxide, acrylamide, acrylic acid, chloracetic acid, sodium chloracetate,
propane sultone and butane sultone, said crosslinked polymer being soluble
in water in an amount of 10 weight percent thereof without essentially any
gel formation and a 10 weight percent aqueous solution of said crosslinked
polymer having a viscosity greater than 3 centipoises at 25.degree. C.,
said water soluble crosslinked polymer being present in an amount of about
0.1-5 percent by weight of said composition, and
a mixture consisting essentially of an effective amount of each of
hydroxyethyl cellulose and silicone oil to provide a hair setting
composition,
wherein said polyamino-polyamide is crosslinked with 0.025 up to about 0.1
mole of said crosslinking agent per amine group in said
polyamino-polyamide.
20. A cosmetic composition for treatment of the hair comprising a solution
in a solvent selected from the group consisting of water and a
hydroalcoholic solution of a water-soluble crosslinked polymer selected
from the group consisting of
(A) a polyamino-polyamide which is the polycondensate of (a) an acidic
compound selected from the group consisting of (i) an organic dicarboxylic
acid selected from the group consisting of a saturated aliphatic
dicarboxylic acid having from 6 to 10 carbon atoms and an aromatic
dicarboxylic acid, (ii) an ethylenically unsaturated carboxylic acid
selected from the group consisting of acrylic acid, methacrylic acid and
itaconic acid, (iii) an ester of said acids of (i) and (ii), (iv) mixtures
of (i), (ii) and (iii) and (v) the intermediate product of addition of one
mole of ethylene diamine and two moles of a methyl ester of (ii) obtained
at a temperature between 5.degree.-80.degree. C., and (b) a polyamine
selected from the group consisting of (1) diethylene triamine, (2)
dipropylene triamine, (3) triethylene tetramine and (4) a mixture of at
least one of (1), (2) and (3) with a member selected from the group
consisting of ethylene diamine, hexamethylenediamine and piperazine, said
polyamine (b) being replaceable by a member selected from the group
consisting of (1) 0-20 mole percent hexamethylene diamine, (2) 0-40 mole
percent ethylene diamine and (3) 0-40 mole percent piperazine, wherein the
polycondensate is formed at a temperature of 80.degree.-250.degree. C.,
said polyamino-polyamide being crosslinked with a crosslinking agent being
selected from the group consisting of epichlorohydrin, diglycidyl ether,
N,N'-bis-epoxypropyl piperazine, the dianhydride of butane tetracarboxylic
acid, the dianhydride of pyromellitic acid, divinyl sulfone and methylene
bisacrylamide, and being employed in an amount of 0.025-0.35 mole per
amine group in said polyaminopolyamide; and
(B) the crosslinked polymer of (A) alkylated with an alkylating agent
selected from the group consisting of glycidol, ethylene oxide, propylene
oxide, acrylamide, acrylic acid, chloracetic acid, sodium chloracetate,
propane sultone and butane sultone, said crosslinked polymer being soluble
in water in an amount of 10 weight percent thereof without essentially any
gel formation and a 10 weight percent aqueous solution of said crosslinked
polymer having a viscosity greater than 3 centipoises at 25.degree. C.,
said water soluble crosslinked polymer being present in an amount of about
0.1-5 percent by weight of said composition, and
an effective amount of a member selected from the 3.oup consisting of an
anionic, cationic, nonionic, amphoteric or zwitterionic surface active
agent; a thickener; a preservative; and a cosmetic resin.
21. The composition of claim 20 wherein said polyamino-polyamide is
crosslinked with 0.025 up to about 0.1 mole of said crosslinking agent per
amine group in said polyamino-polyamide.
22. The composition of claim 21 wherein the polyamino-polyamide is a
polycondensate of adipic acid and diethylene triamine and is crosslinked
with epichlorohydrin in an amount of 0.025 to about 0.1 mole of
epichlorohydrin per mole of amine of the polyamino-polyamide.
23. A process for conditioning the hair which comprises applying to living
human hair an effective amount of a composition comprising a solution in a
solvent selected from the group consisting of water and a hydroalcoholic
solution of a water-soluble crosslinked polymer selected from the group
consisting of
(A) a polyamino-polyamide which is the polycondensate of (a) an acidic
compound selected from the group consisting of (i) an organic dicarboxylic
acid selected from the group consisting of a saturated aliphatic
dicarboxylic acid having from 6 to 10 carbon atoms and an aromatic
dicarboxylic acid, (ii) an ethylenically unsaturated carboxylic acid
selected from the groups consisting of acrylic acid, methacrylic acid and
itaconic acid, (iii) an ester of said acids of (i) an (ii), (iv) mixtures
of (i), (ii) and (iii) and (v) the intermediate product of addition of one
mole of ethylene diamine and two moles of a methyl ester of (ii) obtained
at a temperature between 5.degree.-80.degree. C., and (b) a polyamine
selected from the group consisting of (1) diethylene triamine, (2)
dipropylene triamine, (3) triethylene tetramine and (4) a mixture of at
least one of (1), (2) and (3) with a member selected from the group
consisting of ethylene diamine, hexamethylenediamine and piperazine, said
polyamine (b) being replaceable by a member selected from the group
consisting of (1) 0-20 mole percent hexamethylene diamine, (2) 0-40 mole
percent ethylene diamine and (3) 0-40 mole percent piperazine, wherein the
polycondensate is formed at a temperature of 80.degree.-250.degree. C.,
said polyamino-polyamide being crosslinked with a crosslinking agent being
selected from the group consisting of epichlorohydrin, diglycidyl ether,
N,N'-bis-epoxypropyl piperazine, the dianhydride of butane tetracarboxylic
acid, the dianhydride of pyromellitic acid, divinyl sulfone and methylene
bisacrylamide, and being employed in an amount of 0.025-0.35 mole per
amine group in said polyamino-polyamide; and
(B) the crosslinked polymer of (A) alkylated with an alkylating agent
selected from the group consisting of glycidol, ethylene oxide, propylene
oxide, acrylamide, acrylic acid, chloracetic acid, sodium chloracetate,
propane sultone and butane sultone, said crosslinked polymer being soluble
in water in an amount of 10 weight percent thereof without essentially any
gel formation and a 10 weight percent aqueous solution of said crosslinked
polymer having a viscosity greater than 3 centipoises at 25.degree. C.,
said water soluble crosslinked polymer being present in an amount of about
0.1-5 percent by weight of said composition.
24. The process of claim 23 wherein said polyamino-polyamide is crosslinked
with 0.025 up to about 0.1 mole of said crosslinking agent per amine group
in said polyamino-polyamide.
25. A process for conditioning the hair which comprises applying to living
human hair an effective amount of a composition comprising a solution in a
solvent selected from the group consisting of water and a hydroalcoholic
solution of a water-soluble crosslinked polyamino-polyamide which is the
polycondensate of adipic acid and diethylene triamine crosslined with
epichlorohydrin, said crosslinked polyamino-polyamide being soluble in
water in amounts of 10 weight percent thereof without essentially any gel
formation and a 10 weight percent aqueous solution of said crosslinked
polyamino-polyamide having a viscosity greater than 3 centipoises at
25.degree. C., said water soluble crosslinked polyamino-polyamide being
present in an amount of about 0.1-5 percent by weight of said composition. |
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