A method for providing a barrier against copper diffusion into a zirconium alloy tube which is lined with copper for the purpose of increasing the resistance of the tube to stress corrosion induced by fission products when the tube is used to fuel a nuclear reactor. The method involves the deposition of a copper lining on the zirconium alloy tube and the subsequent exposure of the lined tube to a substance such as steam, water, nickel oxide or carbon dioxide or another material which has the ability to oxidize the zirconium without oxidizing the copper. Thus, a zirconium oxide layer is developed between the zirconium alloy tube and the copper lining thereon.
An improved method for producing nuclear fuel containers of a composite construction having components providing therein a barrier system for resisting destructive action by volatile fission products or impurities and also interdiffusion of metal constituents, and the product thereof. The composite nuclear fuel containers of the method comprise a casing of zirconium or alloy thereof with a layer of copper overlying an oxidized surface portion of the zirconium or alloy thereof.
A method of removing electrocatalytically active protective coatings from electrodes with metal cores, in which a non-adhesive intermediate layer of a compound of the substrate metal is produced in a position between the protective coating and the substrate structure by means of controlled thermal treatment. By using the method, deactivated protective coatings can be removed in a particularly easy manner from electrodes with valve metal cores.
The zirconium cladding of a coolant-displacement rod of a nuclear reactor is precollapsed in the zirconium oxide stack of pellets which supports the cladding. Current is conducted through the cladding in an atmosphere at reduced pressure containing residual oxygen, to heat the cladding to a temperature at which its yield strength is reduced. Then, while the rod remains at this temperature, it is subjected to isostatic pressure which collapses the cladding uniformly. The formation, by reason of exposure to neutron flux, of a long unsupported gap in the cladding which might be collapsed under the pressure of the coolant is precluded. In addition, the rod retains its symmetry. The outer surface of the cladding is oxidized, facilitating the movement of the rod into its thimbles of the core and improving the resistances of the cladding to reaction with the coolant.
An improved method for producing nuclear fuel containers of a composite construction having components providing therein a barrier system for resisting destructive action by volatile fission products or impurities and also interdiffusion of metal constituents, and the product thereof. The composite nuclear fuel containers of the method comprise a casing of zirconium or alloy thereof with a layer of copper overlying an oxidized surface portion of the zirconium or alloy thereof.
Nuclear fuel rod tubes of zirconium alloy are heat treated in an induction furnace to produce a protective oxide coating two to fifteen microns in thickness. The furnace is only slightly larger than the tubes and receives the endmost eight inches of the tube. The furnace is controllable in zones along the tube. To calibrate the furnace to produce the desired temperature profile, typically a flat profile at a temperature between 650.degree. and 750.degree. C..+-.1.5.degree. C., a temperature calibration probe is provided with spaced thermocouples for sensing the temperature developed in the probe at each of the zones when heated. The probe is made of inconel 600 stainless or the like, and is dimensioned and shaped to correspond closely to the dimensions of the fuel rod tubes, including having a closed chamfered end. At the opposite end the probe protrudes from the furnace, where the thermocouple leads are terminated. The leads pass through a potting compound in the probe, such as magnesium oxide. Whereas the probe conductive structures are substantially identical to the tube, the probe responds to the electromagnetic field in the induction furnace substantially the same as does the end of the tube, permitting calibration of the induction furnace zones for a desired temperature profile, e.g., flat along the length of the tube, notwithstanding differences in induced currents that would otherwise occur due to the end of the tube or the adjacent tube material.
