A method for reducing the desire of a person to smoke tobacco includes orally administering to the person an aqueous solution containing a polyvalent cation derived from a metal selected from the group consisting of palladium, copper, zinc, aluminum, tin, and bismuth. The method includes smoking tobacco by the person to whom the solution is administered, subsequent to the oral administration of the solution.

A tobacco smoke filter a copper-containing porphyrin or an iron analog of C.I. Reactive Blue 21 dye. A method of making a first tobacco smoke filter segment, comprising the steps of, first, providing one or more than one substance; producing a mixture of cellulose fiber and the substance; heating the mixture for a sufficient time at one or more than one temperature sufficient to covalently link the substance to the cellulose fiber; and forming the cellulose fiber with covalently bound substance into the first tobacco smoke filter segment. The substance can be a copper-containing porphyrin or an iron analog of C.I. Reactive Blue 21 dye.

A cigarette filter has a humectant, preferably sodium pyroglutamate, and optionally a surfactant. The humectant absorbs moisture from the tobacco smoke for wet-filtration of the tobacco smoke.

A tobacco smoke filter containing a porous substrate having dry water and microcapsules dispersed therein. The microcapsules contain at least one compound selected from the group consisting of chlorophyllin, methylcellulose, sodium pyroglutamate and a vegetable oil. The tobacco smoke filter can also contain one or more substances such as a porphyrin, and sodium pyroglutamate.

A tobacco smoke filter comprising a porous substrate comprising dry water and a porphyrin dispersed therein. The porous substrate can further comprise microcapsules. The microcapsules can comprise one or more substances selected from the group consisting of chlorophyllin, methylcellulose, sodium pyroglutamate and a vegetable oil. The porous substrate can further comprise sodium pyroglutamate.