This invention provides an underwater antifoulant coating that is of a pa-like viscosity and is applied to an underwater surface by brush and comprises a mixture of multiple chlorinated and/or fluorinated waxes, an antifoulant biocide, and a fumed silica utilized as a thickener and produces a viscosity of about 26.75 poises at 25.degree. C., and a density of about 1.28.
A low leaching nonpolluting marine antifouling coating formulation and a cess for preparing the same which comprises surface pretreatment of the metal oxide pigment particles with a water-dispersed organic polymeric resinous material, such as by intensively mixing or milling the metal oxide pigment and the resin, in order to recover a water-dispersable polymeric resin modified metal oxide pigment for subsequent incorporation into new water-based coating formulations.
Copolymers of at least three monomer units selected from the group consisting of fluorinated acrylic (methacrylic) monomers, triorganosilylacrylic (e.g. trimethylsilyl methacrylate) monomers and acrylic monomers not containing an organosilyl moiety, (e.g. methyl methacrylate) and optionally containing from 0-5 weight percent of a cross-linking agent are novel compositions useful as polymeric binders in long life marine antifoulant coatings. The erosion rate and resistance to cracking of the copolymer of the present invention when used as a binder in a marine antifoulant paint is controlled by adjusting the proportions of each monomer and the amount of crosslinking agent in the copolymer of the present invention
A wax coating composition capable of underwater application to submerged faces consisting of a mixture of from about 3.5% to about 6.0% of a polyethylene homopolymer having a softening point at 85.degree. C. (ASTM E28), a hardness of 90 (ASTM D5), a density of 0.88 g/cc (ASTM D1505), a viscosity of 40 cps at 140.degree. C. (Brookfield), and an acid number of mil mg./kOH gram; of about 27% to about 31% of a mixture of Chlorowaxes selected from the group consisting of Chlorowax 70L, Chlorowax 40, Chlorowax 500, Chlorowax 100, and Indramic 30 Laminating wax; of about 3.5% to about 6.0% USP white mineral oil; of about 18.0% to about 20.0% Nopcocide N96; of about 40.5% to about 42.5% USP petrolatum; and of about 0.6% to about 1.05% Autofast Black 104 in xylene. An application method utilizing the composition.
An underwater coating composition for protecting a submerged steel structure from corrosion includes a base resin selected from the group consisting of an epoxidized polysulfide resin and a mixture of an epoxidized polysulfide resin and an epoxy resin, a moisture barrier pigment and an effective amount of a curing agent suitable for curing the composition while the composition is submerged in water and a method for protecting an underwater structure by coating the structure with the above described coating composition.
The present invention describes in detail new environmentally safe marine vessel hull coating formulations for all outer surfaces of all marine vessel surfaces specifically designed to fully comply with all existing and anticipated environmental regulations. These formulations absolutely prevent water ingress, galvanic corrosion, wood decay, worm ingress, attachment by grass, algae and marine organisms, flex to accommodate to hull motions and protect against impact damages and may last for 20 years of the economic life of the marine vessel. These inventive formulations embody specific encapsulation techniques that allow aluminum and large steel hulls to now use these advanced coating products since they do not contain any toxins or co-toxins thereby eliminating the concern about the existing TBT exemptions. The specific materials which are applied to the marine vessel hulls are specified and include an epoxy adhesive resin mixed with copper powder and a thixotropic agent to cause the coating to maintain its shape and configuration while curing. Also included are grass and algae retardants consisting of pH reducers as well as biocides. The use of isopropyl alcohol is also described along with a unique hardener. A relationship between the particle sizes of the thixotropic agent and the copper powder is described. Their mixing procedures, mixing ratios, storage procedures, packaging procedures, shipping procedures, application procedures and maintenance procedures are also fully disclosed in detail. Also disclosed are the specific formulation variables to adapt the products to meet a wide range of end user specifications including a fairing composition incorporating solid or hollow ceramic particles.
