An improved release coating for heat transferable laminate and improved method for curing the release coating for heat transferable laminates wherein an ink design layer is transferred from a carrier web onto an article such as a plastic or glass container upon application of heat and pressure. The improved release coating does not contain wax components but exhibits release properties similar to wax based formulations. The improved release contains U-V curable components which are cured by exposure to ultraviolet light after the laminate containing the ink design, is transferred to a receiving article. The heat transferable laminate preferably includes a barrier layer intermediate the release layer and ink design layer. The barrier layer also contains U-V curable components. The barrier layer is cured by exposure to ultraviolet radiation during formation of the laminate structure and prior to transfer of the laminate to a receiving article. The improved release formulation upon curing by ultraviolet radiation produces a hard, glossy, optically clear protective layer exhibiting enhanced resistance to abrasion, scuffing and solvent attack.
An improved release system for heat transferable laminates wherein a transferable substrate which contains a design layer is transferred from a carrier web onto an article such as a plastic bottle or container upon application of heat and pressure. The carrier web includes a nonwax polyethylene layer. The improved release system includes a polyethylene layer portion of the carrier web in contact with and adhered to a nonwax transfer layer portion of the transferable substrate. The transferable substrate including the ink design layer transfers to the article upon application of heat to the carrier while the article contacts the laminate. The transferred substrate on the article is clear and exhibits improved scuff and abrasion resistance. The nonwax transfer layer portion of the transferable substrate advantageously contains an oil which becomes activated upon application of heat to promote release of the transferable substrate from the carrier web to the article.
An improved release system for heat transferable laminates wherein a transferable substrate which contains a design layer is transferred from a carrier web onto an article such as a plastic bottle or container upon application of heat and pressure. The carrier web includes a nonwax polyethylene layer. The improved release system includes a polyethylene layer portion of the carrier web in contact with and adhered to a nonwax transfer layer portion of the transferable substrate. The transferable substrate including the ink design layer transfers to the article upon application of heat to the carrier while the article contacts the laminate. The transferred substrate with design layers on the article is clear and exhibits improved scuff and abrasion resistance.
A thermo-transfer sheet is composed of a base film and an ink layer to be transferred having a softening point of more than 120.degree. C. A label is formed by the thermo-transfer sheet and provided with an image ink layer formed on a thermo-transfer image receiving sheet through a temperature-sensitive adhesive layer and the image ink layer has a softening point of more than 120.degree. C. The thermo-transfer sheet and the thermo-transfer image receiving sheet are prepared and a temperature-sensitive adhesive layer is formed on at least one of the surface of the thermo-transfer sheet or the transfer ink layer of the thermo-transfer image receiving sheet. These sheets are laminated and the laminated sheets are heated by means of a thermal head to thereby transfer the image ink layer having a softening point of more than 120.degree. C. on the thermo-transfer image receiving sheet. According to these processes, a label such as bar code is manufactured with an excellent durability such as friction-proof property, solvent-proof property and heat-proof property.
A thermo-transfer sheet is composed of a base film and an ink layer to be transferred having a softening point of more than 120.degree. C. A label is formed by the thermo-transfer sheet and provided with an image ink layer formed on a thermo-transfer image receiving sheet through a temperature-sensitive adhesive layer and the image ink layer has a softening point of more than 120.degree. C. The thermo-transfer sheet and the thermo-transfer image receiving sheet are prepared and a temperature-sensitive adhesive layer is formed on at least one of the surface of the thermo-transfer sheet or the transfer ink layer of the thermo-transfer image receiving sheet. These sheets are laminated and the laminated sheets are heated by means of a thermal head to thereby transfer the image ink layer having a softening point of more than 120.degree. C. on the thermo-transfer image receiving sheet. According to these processes, a label such as bar code is manufactured with an excellent durability such as friction-proof property, solvent-proof property and heat-proof property.
This invention related to a packaging container and a container closure having excellent curability, aesthetic beauty of an ultraviolet ray hardened coating, transferability of a container, heat-resistant treatability, retortability, and sanitary characteristics. The present invention provides to a packaging container and a container closure having, on the outer surface, a coating layer of a resin composition which comprises a cationic curable resin comprising an alicyclic epoxy resin, a photo-cationic-curing catalyst comprising a compound of the following formula (1), ##STR1## wherein each of R.sub.1 and R.sub.2 is an alkyl group, and they may be the same or different, and R.sub.3 is an alkyl group, a sensitizer comprising a thioxanthone sensitizer, and a pigment comprising titanium dioxide, wherein the amount of said titanium dioxide is at least 0.30 mg per 1 cm.sup.2 of said coating layer, the amount of said photo-cationic-curing catalyst is 1 to 20% by weight with regards to said titanium dioxide, and the amount of said sensitizer is 1.5 to 5% by weight with regards to said titanium dioxide.
