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| United States Patent | 4905265 |
| Link to this page | http://www.wikipatents.com/4905265.html |
| Inventor(s) | Cox; John D. (Gainesville, FL);
Jacobs; Alan M. (Gainesville, FL);
Scott; Stephen A. (Gainesville, FL);
Juang; Yi-Shung (Gainesville, FL) |
| Abstract | The x-ray imaging system comprises an x-ray source for producing an x-ray
beam and an x-ray detector. The x-ray detector comprises a solid state
integrated circuit having a silicon substrate and a plurality of charge
storage devices. A circuit is provided for placing a charge on the charge
storage devices and the integrated circuit is disposed in an x-ray
permeable material. The detector is positioned in an x-ray beam such that
the charge is dissipated by secondary radiation produced by interaction
between the x-ray beam and the silicon substrate of the integrated
circuit. |
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Title Information  |
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Drawing from US Patent 4905265 |
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X-ray imaging system and solid state detector therefor |
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| Publication Date |
February 27, 1990 |
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| Filing Date |
February 1, 1988 |
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| Parent Case |
CROSS REFERNCE TO RELATED APPLICATIONS
This is a continuation in part of U.S. application Ser. No. 807,650, filed
Dec. 11, 1985. |
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Title Information  |
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References  |
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| *references marked with an asterisk below are user-added references |
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U.S. References |
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| | Reference | Relevancy | Comments | Reference | Relevancy | Comments | 3781827
|      Your vote accepted [0 after 0 votes] | | 3916268
|      Your vote accepted [0 after 0 votes] | | 4675739 Catchpole 378/98.8 Jun,1987 |      Your vote accepted [0 after 0 votes] | | 4504865 Nishizawa 348/281 Mar,1985 |      Your vote accepted [0 after 0 votes] | | 4486778 Risch 378/29 Dec,1984 |      Your vote accepted [0 after 0 votes] | | 4471378 Ng 348/162 Sep,1984 |      Your vote accepted [0 after 0 votes] | | 4441125 Parkinson 348/302 Apr,1984 |      Your vote accepted [0 after 0 votes] | | 4415980 Buchanan 378/58 Nov,1983 |      Your vote accepted [0 after 0 votes] | | 4413280 Adlerstein 378/98.8 Nov,1983 |      Your vote accepted [0 after 0 votes] | | 4413283 Aoki 348/304 Nov,1983 |      Your vote accepted [0 after 0 votes] | | 4407010 Baji 348/301 Sep,1983 |      Your vote accepted [0 after 0 votes] | | 4397002 Brosch 365/190 Aug,1983 |      Your vote accepted [0 after 0 votes] | | 4390791 Hatanaka 250/208.1 Jun,1983 |      Your vote accepted [0 after 0 votes] | | 4383327 Kruger 378/19 May,1983 |      Your vote accepted [0 after 0 votes] | | 4346406 Kato 348/162 Aug,1982 |      Your vote accepted [0 after 0 votes] | | 4344091 Gardner 348/294 Aug,1982 |      Your vote accepted [0 after 0 votes] | | 4291392 Proebsting 365/203 Sep,1981 |      Your vote accepted [0 after 0 votes] | | 4160997 Schwartz 348/66 Jul,1979 |      Your vote accepted [0 after 0 votes] | | 4119841 Jantsch 250/214VT Oct,1978 |      Your vote accepted [0 after 0 votes] | | 4120002 Lieber 378/98.2 Oct,1978 |      Your vote accepted [0 after 0 votes] | | 4011442 Engeler 365/183 Mar,1977 |      Your vote accepted [0 after 0 votes] | | 3950738 Hayashi 365/185.04 Apr,1976 |      Your vote accepted [0 after 0 votes] | | 3648258 Sewell, Jr. 365/184 Mar,1972 |      Your vote accepted [0 after 0 votes] | | | | | |
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| Market Size |
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| Reasonable Royalty |
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Public's "Guesstimation" of Royalty Value
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Market Review  |
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Technical Review  |
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Claims  |
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What is claimed is:
1. An x-ray imaging system comprising:
an x-ray source for producing an x-ray field having sufficient energy such
that compton scattering and pair production have a higher combined
probability of producing free electrons in silicon than the photoelectric
effect; and
an x-ray detector comprising a solid state device having a plurality of
layers, one of said layers including a semiconductor material with a
plurality of charge storage devices, said detector having an extra
absorber material for the purpose of enhancing x-ray absorption, said
extra absorber material being exposed to said x-ray field to produce free
electrons and being positioned sufficiently close to said semiconductor
material to permit said free electrons to interact with said charge
storage devices.
2. An x-ray imaging system as claimed in claim 1 wherein said detector is
placed between said source and an object to be viewed such that said x-ray
field passes through said detector, impinges on said object and forms an
image of said object in said detector by back scatter from said object.
3. An x-ray system as claimed in claim 2 including means for subtracting an
image of said source from the image produced in said detector.
4. An x-ray imaging system as claimed in claim 1 wherein said detector
comprises a thin film device and wherein another of said layers comprises
preprocessor circuitry connected to said charge storage devices.
5. An x-ray imaging system as claimed in claim 1 including a support
housing for said detector, said support housing having means for removably
receiving said detector.
6. An x-ray imaging system as claimed in claim 1 wherein said charge
storage devices are part of a dynamic random access memory.
7. An x-ray imaging system as claimed in claim 1 including means for
normalizing the soak times required for discharging all of the charge
storage devices which are intended to discharge simultaneously.
8. An x-ray imaging system as claimed in claim 7 wherein said normalization
means comprises means for storing a different normalizing factor for each
of said charge storage devices.
9. An x-ray imaging system as claimed in claim 1 wherein each said charge
storage device forms a single pixel of an image formed on said detector.
10. An x-ray imaging system as claimed in claim 1 including an
interconnection layer for providing external connections to said detector,
said interconnection layer being separate from said layer containing said
charge storage devices.
11. An x-ray imaging system as claimed in claim 4 including an
interconnection layer for providing external connections to said
preprocessors, said interconnection layer being between said layer
containing said charge storage devices and said layer containing said
preprocessors.
12. An x-ray imaging system as claimed in claim 1 including means for
reading analog voltages from said charge storage devices.
13. An x-ray imaging system as claimed in claim 1 wherein said extra
absorber material is on one side of said layer containing said charge
storage devices and a metallization layer is on an opposite side of said
layer containing said charge storage devices.
14. An x-ray imaging system as claimed in claim 1 wherein said detector is
an integrated circuit and the absorber material is a metallization layer
of the integrated circuit.
15. An x-ray imaging system as claimed in claim 1 wherein each of said
charge storage devices is at least about 50 microns on a side.
16. An x-ray imaging system as claimed in claim 1 wherein said x-ray
detector is about 14 inches by 17 inches.
17. An x-ray imaging system as claimed in claim 16 wherein each charge
storage device is arranged in a basic cell about 0.1 mm square.
18. An x-ray imaging system as claimed in claim 1 wherein said extra
absorber material comprises an increased thickness gate oxide layer.
19. An x-ray imaging system as claimed in claim 1 wherein said detector is
a dynamic random access device in which charges are stored on each of said
charge storage devices and dissipated by free electrons resulting from
said x-ray field.
20. An x-ray imaging system comprising:
an x-ray source for producing an x-ray field having an energy level
sufficiently high that compton scattering and pair production have a
higher combined probability of producing free electrons in silicon than
the photoelectric effect;
an x-ray detector comprising a solid state integrated random access circuit
having a semiconductor substrate, a plurality of charge storage devices,
and circuit means including a plurality of conductor lines for randomly
accessing each of said charge storage devices, said detector being
positioned to be exposed to said x-ray field such that charges on said
charge storage devices are affected by free electrons produced by said
x-ray field; and
means for sensing a charge on each of said charge storage devices through
said circuit means.
21. An x-ray imaging system as claimed in claim 20 wherein said detector is
placed between said source and an object to be imaged such that said x-ray
field passes through said detector, impinges on said object and forms an
image of said object in said detector by back scatter from said object.
22. An x-ray system as claimed in claim 21 including means for subtracting
an image of said source from the image produced in said detector.
23. An x-ray imaging system as claimed in claim 20 wherein said charge
storage devices are divided into groups to form pixels, each pixel having
a plurality of charge storage devices and means for varying the
sensitivity of said charge storage devices in a single pixel to provide a
gray scale.
24. An x-ray imaging system as claimed in claim 20 including a support
housing for said detector, said support housing having means for removably
receiving said detector.
25. An x-ray imaging system as claimed in claim 24 wherein said detector
has a thickness on the order of 1/2 mm.
26. An x-ray imaging system as claimed in claim 20 wherein each of said
charge storage devices is contained within a cell having a greatest
dimension of approximately 10 microns.
27. An x-ray imaging system as claimed in claim 20 wherein said integrated
circuit comprises a dynamic random access memory circuit including at
least one sense amplifier for comparing the charge of said charge storage
devices to a threshold value, and including means external to said
integrated circuit for supplying said threshold value to said integrated
circuit.
28. An x-ray imaging system as claimed in claim 20 wherein said circuit
means comprises transistors for connecting said charge storage devices to
a voltage source.
29. An x-ray imaging system as claimed in claim 20 including means for
moving one of said x-ray source and said detector relative to the other by
a distance approximating the distance between charge storage devices in
said detector.
30. An x-ray imaging system as claimed in claim 20 including means for
normalizing the soak times required for discharging all of the charge
storage devices which are intended to discharge simultaneously.
31. An x-ray imaging system as claimed in claim 30 wherein said
normalization means comprises means for storing a different normalizing
factor for each of said cells.
32. An x-ray imaging system as claimed in claim 20 including a plurality of
x-ray detectors positioned over one another such that the cells of each
x-ray detector are staggered with the cells of the other x-ray detectors
such that any one cell of any one x-ray detector is positioned between two
cells of another x-ray detector.
33. An x-ray imaging system as claimed in claim 20 including means for
exposing the detector to said source for sequential lengths of time to
produce a plurality of images, and adding said images together to provide
a gray scale.
34. An x-ray imaging system as claimed in claim 33 wherein the intervals
between said sequential exposure times are assigned different gray scale
values.
35. An x-ray imaging system as claimed in claim 23 wherein said varying
means comprises different thickness oxide layers in said charge storage
devices.
36. An x-ray imaging system as claimed in claim 23 wherein said varying
means comprises different comparison voltage levels for determining the
charge on said charge storage devices.
37. An x-ray imaging system as claimed in claim 20 wherein each said charge
storage device forms a single pixel of an image formed on said detector.
38. A method of detecting an x-ray image comprising:
storing charges on a plurality of charge storage devices formed in a random
access integrated circuit;
producing an x-ray field having an energy level sufficiently high that
compton scattering and pair production have a combined probability of
producing free electrons in silicon greater than the photoelectric effect;
exposing an object to be imaged to said x-ray field;
exposing said integrated circuit to the x-ray field from said object such
that said x-ray field interacts with said integrated circuit to produce
said free electrons to reduce the charge on said charge storage devices;
and
sensing the charge on said charge storage devices.
39. A method according to claim 38 including producing an image having a
gray scale by sequentially exposing said integrated circuit with different
exposure times and digitally adding the images obtained at each of said
exposure times.
40. A method according to claim 38 comprising producing a back scattered
image by positioning said integrated circuit between said source and an
object to be viewed, causing said x-ray field to pass through said
integrated circuit and forming an image in said integrated circuit through
back scattering from said object.
41. A method according to claim 38 including normalizing the outputs from
said charge storage devices to compensate for different sensitivities of
said charge storage devices. |
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Claims  |
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Description  |
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BACKGROUND OF THE INVENTION
1. Field of the Invention
This invention relates to x-ray imaging systems and particularly to an
x-ray imaging system which utilizes a solid state x-ray detector.
2. Discussion of Related Art
Presently, x-ray imaging systems are utilized in a variety of applications,
both as medical diagnostic tools and for industrial quality control. The
most common form of x-ray detection resides in the use of silver halide
film. However, the use of such film requires the performance of several
wet, control requiring chemical developing steps. In addition, this film
is expensive, thus increasing the cost of x-ray images produced in this
manner.
It would be highly desirable, therefore, to produce an x-ray imaging system
which does not require the use of silver halide film. Several detectors
have been proposed for this purpose.
For example, U.S. Pat. No. 4,471,378 to Ng discloses a light and particle
image intensifier which includes a scintillator and photocathode unit for
converting incident image conveying light or charged particles to
photoelectrons and a charge coupled device for detecting the
photoelectrons and transmitting to data processing and video equipment
information relating to the quantity or energy level as well as the
location of the electrons impinging on the sensing areas of the charge
couple device.
U.S. Pat. No. 4,413,280 to Adlerstein et al discloses an x-ray imaging
apparatus which includes a transducer for converting incident x-radiation
to a corresponding pattern of electrical charges. The charges generated by
the transducer are accelerated onto an array of charge detecting or charge
storing devices which store the charges in the form of an electrical
signal corresponding to the charge pattern.
SUMMARY OF THE INVENTION
One object of the present invention is to provide a solid state imaging
system and detector which are highly sensitive to x-radiation and can
produce highly accurate x-ray images.
Another object of the present invention is to provide an x-ray imaging
system and detector which can be produced by conventional solid state
fabrication technology.
A further object of the present invention is to provide a solid state
imaging detector which can be produced in such small sizes as to enable
its use in very confined areas.
Another object of the present invention is to provide an x-ray imaging
detector which can be substituted directly for x-ray film used in
conventional x-ray imaging systems.
Yet another object of the present invention is provide an x-ray detector
which is relatively inexpensive to fabricate so as to enable its use in
fixed locations for ease of periodic x-ray analysis of mechanical
structures and the like.
In accordance with the above and other objects, the present invention is an
x-ray imaging system comprising an x-ray source for producing an x-ray
field, and an x-ray detector. The x-ray detector comprises a solid state
integrated circuit having a plurality of charge storage devices and a
circuit for placing a charge on the charge storage devices. The charge
storage devices are disposed in an x-ray permeable material and the
detector is positioned in the x-ray field such that the charge is
dissipated by secondary radiation produced by interaction of the x-ray
field in the silicon substrate of the solid state integrated circuit.
The charge storage devices may be divided into groups to form pixels. Each
pixel comprises one or a plurality of charge storage devices and the
exposure times for discharging the charge storage devices in a single
pixel can be different from one another to provide a gray scale.
In accordance with other aspects of the invention, the integrated circuit
may be a dynamic random access memory.
Each charge storage device comprises a single cell of the integrated
circuit. The cells are spaced from each other such that dead space exists
therebetween. Also, the cells are produced in banks of 32,000 with about
1/4 mm dead space between banks. A plurality of detectors may be stacked
with the cells of the detectors staggered such that each cell of one
detector is positioned behind the gap between cells of another detector so
as to eliminate all dead space.
The imaging system also includes processing circuitry for accessing the
cells of a detector. The processing circuitry may include a system for
normalizing the outputs of all of the cells to compensate for various
inherent differences in radiation sensitivities of the various cells.
One of the most important aspects of the digital radiography technique
employed in the present invention compared to conventional systems using
silver halide film is the ability to perform quantitative radiography.
This is achieved practically through image digitization and makes
subtraction of radiographic images an extremely useful enhancement
technique.
The x-ray image detection system according to the present invention is
based on direct acquisition of digital information, utilizing solid-state
silicon and hybrid detectors. An x-ray image of an object is projected
directly onto the sensor without any intermediate x-ray-to-light
conversion and signal magnification. Secondary electrons produced by x-ray
interactions with the silicon substrate are collected and digitized using
techniques similar to those employed for visible light detection.
One of the major concerns of direct x-ray sensing is designing a
solid-state sensor that can withstand the radiation dose accumulation
sufficiently to justify the cost of replacing the degraded detectors. The
sensor must have good x-ray sensitivity compared to other systems with
typical x-ray spectra (30 kVp to 200 kVp), and should have a capability of
sensing a continuous large format image. To solve this problem, the sensor
used in the present invention is a convention DRAM device. The cost of
producing such a device is orders of magnitude less than producing other
types of sensors, such as CCD and CID arrays.
BRIEF DESCRIPTION OF THE DRAWINGS
The above and other objects of the present invention will become more
readily apparent as the invention is more clearly understood from the
detailed description to follow, reference being had to the accompanying
drawings in which like reference numerals represent like parts throughout,
and in which:
FIG. 1 is a block diagram of the x-ray imaging system of the present
invention;
FIG. 2 is a circuit diagram of an integrated circuit detector used in the
imaging system of Figure 1;
FIG. 3 is an enlarged schematic showing one charge storage capacitor of the
circuit diagram of FIG. 2;
FIG. 4 is a cross section of a chip showing the structure depicted
schematically in FIG. 3;
FIG. 5 is a view of a portion of the detector of the present invention
stacked over additional detectors to fill up the dead space between cells;
FIG. 6 is an end elevational view of the stacked detectors of FIG. 5;
FIG. 7 is a diagrammatic representation showing the system of the present
invention used in place of x-ray film;
FIG. 8 is a flow diagram depicting a method of normalizing the cells of the
present invention;
FIG. 9 shows the orientation of the detector and the detector leads;
FIG. 10 is a graph showing pixel logic hold time as a function of
accumulated radiation exposure based on data taken at 120 kVp filtered
through 0.25 mm Al with 50% of total detecting pixels discharged beyond
the threshold point;
FIG. 11 is a graph showing pixel integration time as a function of
accumulated exposure based on data taken at 120 kVp filtered through 0.25
mm Al;
FIG. 12 shows a thin film detector embodiment of the present invention;
FIG. 13 is a cross section of one detector of the embodiment of FIG. 12;
FIG. 14 is a circuit diagram of the detector of FIG. 12; and
FIG. 15 is a cross section showing the interconnection between the sensing
layer and the preprocessor portion of the detector of FIG. 12.
DESCRIPTION OF THE PREFERRED EMBODIMENT
FIG. 1 shows the x-ray system 10 to comprise a high energy x-ray source 12
and a detector 14 positioned to receive the radiation from source 12.
Source 12 can be any standard high energy x-radiation source having an
output in the range of 8 Kev or higher. Sources such as this are well
known and manufactured by, for example, G.E. or Siemens. Alternatively,
source 12 be an ultra small focal spot source such as manufactured by
Ridge or Magnaflux, also having an output in the range of 8 Kev or higher.
Any size focal spot source can be used. Currently, the smallest focal spot
available is one micron. Also, the source 12 and detector can be placed as
close to the object 0 to be x-rayed as desired due to the configuration of
the detector 14, as will become readily apparent.
Detector 14 may be a dynamic random access memory such as the IS32 OpticRAM
sold by Micron Technology, Inc. of Boise, Idaho. This device is an
integrated circuit DRAM having 65,536 elements and is used as a solid
state light sensitive detector. The Micron DRAM is specifically adapted to
sense light inasmuch as there is no opaque surface covering the integrated
circuit. However, any type of dynamic random access memory may be used for
detector 14 as long as the covering is transparent to x-radiation. In
fact, as will become apparent, any type of dynamic memory element may be
used as detector 14. The memory element does not have to be a random
access memory, although the use of a random access memory facilitates
preprocessing and image processing routines.
The IS32 OpticRAM image sensor is a solidstate device capable of sensing an
image and translating it to digital computer-compatible signals. The chip
contains two arrays each of which contains 32,768 sensors arranged as 128
rows by 256 columns of sensors (4,420 microns.times.876.8 microns). Each
pixel, 6.4 microns on a side, consists of two elements, a MOS capacitor
and a MOS switch. The fill factor is 50 percent. The sensor is a random
access device and thus, pixels may be individually accessed.
The detector 14 operates by the projection of radiation penetrating the
object onto the 65,536 radiation-sensitive elements of the array-pair.
Radiation striking a particular element will cause the capacitor, which is
initially charged to five volts, to discharge toward zero volts. The
capacitor will discharge at a rate proportional to the intensity of the
radiation field to which it is exposed.
To determine whether a particular element is black or white, one can read
the appropriate row and column address associated with the physical
location of the element. The sensor reads the voltage value of the
capacitor and performs a digital comparison between the voltage of the
capacitor and a fixed externally applied threshold voltage bias. A white
pixel indicates the capacitor is exposed to a radiation field sufficient
to discharge the MOS capacitor below the threshold point, whereas a black
pixel has not received sufficient exposure.
The output of detector 14 is passed to preprocessor 16 which serves the
function of normalizing the outputs of all of the cells of detector 14.
That is, the sensitivity of the cells of detector 14 will inherently vary.
A normalization value can be stored in preprocessor 16 so as to normalize
the output of each of the cells to ensure a field describing reading.
The normalized output of preprocessor 16 is passed to image processor 18
which manipulates the data using conventional image processing programs as
well as new image processing programs which will be made possible by the
present invention, such as "zoom" programs which are not currently in
existence. This image can be displayed on a high resolution monitor 20,
can be stored on a laser disc recorder 22, can be printed using a dry
silver printer 24, or can be sent via satellite to remote image processors
(not shown). A menu driven program is displayed on a computer monitor 26
prompting appropriate instructions and data which can be entered into the
image processor 18 using a keyboard 28.
FIG. 2 shows a schematic diagram of a portion of a typical DRAM used in
detector 14. The circuit 30 comprises a plurality of cells 32, each of
which contains a memory capacitor 34 and an access transistor 36. The
individual cells are accessed through left and right digit lines 38 and
40, respectively, as well as word lines 42 and 44. A sense amplifier 46 is
provided in the form of a cross coupled MOSFET detector circuit. The sense
amplifier 46 has nodes A and B which are coupled to the left digit line 38
and to the right digit line 40, respectively. The cells 32 are divided
into a left array 50 and a right array 52. The left array 50 is accessed
by the left digit line 38 and the right array 52 is accessed by the right
digit line 40. The word lines 42 access the individual cells of array 50
and the word lines 44 access cells of the array 52.
A pair of equilibrate transistors 56 and 58 couple the digit lines together
to allow equalization of the digit lines at the end of a refresh cycle and
during the recharge state of the next cycle.
The common drains of the cross coupled sense amplifier transistors at node
C are connected through an isolation transistor 60 to a pad 62 on the
periphery of the integrated circuit chip. The pad 62 is bonded to one of
the leads of the circuit chip package.
A pair of pull up circuits 66, 68 are coupled, respectively, to the nodes A
and B. The pull up circuits 66, 68 are voltage divider circuits operable
to control the voltage level of the digit lines 38 and 40.
FIG. 3 shows one cell of the circuit 30. For convenience, the cell is shown
to be one of the array 52 but it could be any of the cells. As shown, the
capacitor 34 has two plates 70 and 72 between which a charge is stored.
Initially, the capacitor is charged by applying a high potential on word
line 44 and a high potential on right digit line 40. This corresponds to a
"1" state of the cell. In the presence of incident x-radiation, the charge
on capacitor 34 is dissipated as will be discussed below.
With reference to FIG. 4, the portion of the integrated circuit containing
the cell shown in FIG. 3 is set forth in cross section. The circuit
comprises a p-type silicon substrate 80 onto which an n+ region 82 has
been added. A silicon dioxide layer 84 is deposited over the substrate and
n+region 82 to form an insulating layer. The lead 40 is connected to the
n+ region to form the drain of transistor 34. A metal plate 86 is formed
on the oxide layer 84 to form an insulated gate of transistor 36. The
capacitor 34 is formed by a metal plate 72 and the interface 70 between
p-type substrate 80 and oxide layer 84, which forms the other capacitor
plate.
When the cell of FIGS. 3 and 4 is set to the "1" state, charge is built up
on the interface 70 to charge the capacitor 34. The gate voltage is then
lowered so as to discontinue communication between the drain voltage at
line 40 and the capacitor 34. This charge is dissipated due to the
absorbtion of x-ray photons in the substrate 80. In FIG. 4, the direction
of incident x-radiation is shown by the arrow 88.
The x-radiation can produce free electrons in the substrate 80 either by
photoelectric effect, Compton scattering, or pair production. However,
because of the high energy of the source used in the present system, the
number of electrons produced through photoelectric effect is negligible.
The x-ray energy is in the range where compton scattering and pair
production have the highest probabilities of producing free electrons.
It is noted that interconnections between components of a cell and between
cells are provided on the oxide layer of the semi-conductor. This is
indicated in FIG. 4 by showing the leads 40, 44 a 45 extending out of the
oxide layer. Such leads represent the interconnections produced by the
metalization layer of an integrated circuit.
Irradiation of the cell 30 from either side results in virtually all of the
x-radiation being received in the substrate 80 so that the total electron
production for any given energy level of radiation is achieved. The free
electrons produced by interaction between the substrate and the
x-radiation decrease the charge at junction 70 and thus decrease the
charge on capacitor 34.
In conventional x-ray systems, compton scattering and the photoelectric
effect are the relevant interactions causing the appearance of free
electrons. Rayleigh scattering, a type of coherent scattering may also be
responsible for the production of some free electrons. The relative
occurrences of the different reactions depends on the energy of the x-ray.
As discussed above, the present invention uses a high energy source.
Rayleigh scattering and photoelect | | |