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Description  |
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BACKGROUND OF THE INVENTION
Volatile silicon compounds have found wide acceptance in a number of
different types of products ranging from cosmetics to antifreeze
formulations. Such silicon compounds are good solvents for a variety of
materials and serve to give excellent feel on skin and hair.
The most common types of volatile silicon compounds are linear and cyclic
siloxanes having from one to about seven siloxane groups. While these are
the most common, there are other types which have been disclosed. Included
among such other silicon compounds are those in U.S. Pat. No. 4,207,424,
Winnick, issued June 10, 1980
##STR1##
Additional disclosures of volatile silicon compounds are in U.S. Pat. No.
4,355,062, Wang et al., issued Oct. 19, 1982. Certain alkyl linear
siloxanes such as
##STR2##
are disclosed in U.S. Pat. No. 4,376,087, Poliniak et al., issued Mar. 8,
1983. Cyclic silicones different from those mentioned above are disclosed
in U.S. Pat. No. 4,364,837, Pader, issued Dec. 21, 1982. Still other
volatile silicon compounds are disclosed in Japanese unexamined
applications JP 9108-046, Oct. 14, 1974; JP 1102-019, Sept. 7, 1976; JP
607-824, June 15, 1981; JP 6139-527, Oct. 31, 1981; and JP 7035-526, Feb.
26, 1982.
Although the references discussed above disclose a variety of volatile
silicon compounds in a variety of compositions, there is still the need
for cosmetic and household products which incorporate volatile silicon
compounds.
It is therefore an object of the present invention to provide cosmetic and
household products containing silicon materials which provide improved
solvency and compatibility with other composition components.
This and other objectives will become readily available from the detailed
disclosure below.
All percentages and ratios herein are by weight unless otherwise specified.
Additionally, all measurements are made at 25.degree. C. unless otherwise
specified.
SUMMARY OF THE INVENTION
The present invention relates to cosmetic and household products containing
volatile silicon compounds of the following structures:
(a) Linear siloxanes
##STR3##
wherein (1) X=1 to 4, (2) total carbons .ltoreq.14, (3) R can be
independently C.sub.1 -C.sub.10 a alkyl or trialkyl siloxy, and (4) at
least one R per molecule must be selected from aryl, alkylaryl, aryl
alkyl, C.sub.1 -C.sub.7 hydroxyalkyl, or --R.sub.1 -R.sub.2 wherein
R.sub.1 =C.sub.1 -C.sub.9 alkylene (preferably C.sub.1 -C.sub.4 alkylene)
and R.sub.2 is selected from
##STR4##
(b) Cyclic siloxanes
##STR5##
wherein (1) Y=1 to 4, (2) total carbons.ltoreq.14, (3) R can be
independently C.sub.1 -C.sub.10 alkyl or trialkyl siloxy, and (4) at least
one R per molecule must be selected from C.sub.1 -C.sub.7 hydroxyalkyl or
--R'.sub.1 R.sub.2 wherein R'.sub.1 =C.sub.1 -C.sub.4 alkylene and R.sub.2
is selected from
##STR6##
(c) Silanes
##STR7##
wherein (1) Z=1 to 4, (2) total carbons.ltoreq.14, (3) R can be
independently C.sub.1 -C.sub.10 alkyl or trialkyl (C.sub.1 -C.sub.3)
siloxy, and (4) at least one R per molecule must be selected from aryl,
alkylaryl, arylalkyl, C.sub.1 -C.sub.7 hydroxyalkyl, C.sub.2 -C.sub.10
alkyl, or --R.sub.1 R.sub.2 where R.sub.1 =C.sub.1 -C.sub.9 alkylene
(preferably C.sub.1 -C.sub.4 alkylene) and R.sub.2 is selected from
##STR8##
The boiling point of all of these silicon compounds at 760 mm is
.ltoreq.260.degree. C. The aryl groups used in the silicon compounds may
be substituted, for example, with --Cl or --OH moieties.
DETAILED DESCRIPTION OF THE INVENTION
The present invention, as summarized above, relates to cosmetic and
household products containing silicon compounds having improved solvency
and compatibility properties.
Examples of these material include, among many others, the following:
##STR9##
Cosmetic and Household Products
The volatile silicon compounds described above find use in a number of
different products. These include hair care products such as hairsprays,
shampoos, mousses, styling gels and lotions, cream rinses/conditioners,
hair tonics, hair dyes and colorants, home permanents and bleaches. Also
included are skin care products such as cleansers, conditioners,
lipsticks, eye makeup, fingernail polish, .suntan products,
antiperspirant/deodorant products and depilatories. Also included are
household products such as waxes, polishes, heavy and light duty liquid
cleaners, fabric softeners and window cleaners.
Given below are several detailed descriptions of suitable products of the
type mentioned above.
Hair Care Products
The hair care products of the present invention contain the volatile
silicon compounds described above along with a carrier benefiting from the
silicon compound. The term "carrier", as used herein, means one or more
compatible vehicles which are suitable for administration to the hair of a
human or lower animal. The term "compatible", as used herein, means that
the components of the carrier are capable of being commingled with the
silicon compounds of the present invention, and with each other, in a
manner such that there is no interaction which would substantially reduce
the ability of the hair care products to provide its benefit under
ordinary use situation.
Carriers suitable for use with the volatile silicon agents such as shampoos
and cream rinse conditioners to hair are well known in the art, and their
selection can be made without difficulty by a person skilled in the art.
For example, carriers which are suitable are described in more detail in
U.S. Pat. No. 3,577,517, Kubot et al., issued May 4, 1971; U.S. Pat. No.
3,907,984, Calvert et al., issued Sept. 23, 1975; U.S. Pat. No. 4,012,501,
Farber, issued Mar. 15, 1977; U.S. Pat. No. 4,223,009, Chakrabarti, issued
Sept. 16, 1980; and U.S. Pat. No. 4,283,384, Jacquet et al., issued Aug.
11, 1981; the disclosures of all these patents being incorporated herein
by reference in their entirety.
Shampoo compositions useful with the silicon compounds of this invention
utilize conventional. components. The shampoos comprise from about 0.1% to
about 20% of the volatile silicon compound; from about 5% to about 60% of
a synthetic surfactant; and the balance water. Suitable surfactants
include ammonium lauryl sulfate, ammonium laureth sulfate, triethylamine
lauryl sulfate, thiethylamine laureth sulfate, triethanolamine lauryl
sulfate, triethanolamine laureth sulfate, monoethanolamine lauryl sulfate,
monoethanolamine laureth sulfate, diethanolamine lauryl sulfate,
diethanolamine laureth sulfate, lauric monoglyceride sodium sulfate,
sodium lauryl sulfate, sodium laureth sulfate, potassium lauryl sulfate,
potassium laureth sulfate, lauryl sarcosine, cocoyl sarcosine, ammonium
cocoyl sulfate, ammonium lauryl sulfate, sodium cocoyl sulfate, sodium
lauryl sulfate, potassium cocoyl sulfate, potassium lauryl sulfate,
triethanolamine cocoyl sulfate, triethanolamine lauryl sulfate,
monoethanolamine cocoyl sulfate, monoethanolamine lauryl sulfate, sodium
tridecyl benzene sulfonate and sodium dodecyl benzene sulfonate.
Shampoos can also contain a variety of nonessential optional components.
Such conventional optional ingredients are well known to those skilled in
the art, e.g., preservatives, such as benzyl alcohol, ethyl paraben,
propyl paraben and imidazolidinyl urea; hair styling/setting polymers such
as acrylate polymers and copolymers; cationic surfactants, such as cetyl
trimethyl ammonium chloride, lauryl trimethyl ammonium chloride, tricetyl
methyl ammonium chloride, stearyldimethyl benzyl ammonium chloride, and
di(partially hydrogenated tallow) dimethylammonium chloride; thickeners
and viscosity modifiers such as a diethanolamide of a long-chain fatty
acid (e.g., PEG 3 lauramide), block polymers of ethylene oxide and
propylene oxide, sodium chloride, sodium sulfate, polyvinyl alcohol, ethyl
alcohol and water-soluble polymers such as xanthan gum, hydroxyethyl
cellulose, guar gum and starch; pH adjusting agents, such as citric acid,
succinic acid, phosphoric acid, sodium hydroxide, sodium carbonate;
perfumes; dyes; and sequestering agents, such as disodium ethylenediamine
tetraacetate. Such agents generally are used individually at a level of
from about 0.01% to about 10%, preferably from about 0.5% to about 5.0% by
weight of the composition.
Another carrier useful with the present silicon compounds are creme
rinses/conditioners. Such a carrier preferably comprises two essential
components: a lipid vehicle material and generally a o cationic surfactant
vehicle material. Such carriers are generally described in the following
documents, all incorporated by reference herein: Barry, "The Self Bodying
Action of the Mixed Emulsifier copolymers; cationic surfactants, such as
cetyl trimethyl ammonium Sodium Dodecyl Sulfate/Cetyl Alcohol", 28 . J. of
Colloid and Interface Science 82-91 (1968); Barry et al., "The
Self-Bodying Action of Alkyltrimethylammonium Bromides/Cetostearyl Alcohol
Mixed Emulsifiers; Influence of Quaternary Chain Length", 35 J. of Colloid
and Interface Science 689-708 (1971); and Barry et al., "Rheology of
Systems Containing Cetomacrogol 1000--Cetostearyl Alcohol, I. Self Bodying
Action", 38 J. of Colloid and interface Science 616-625 (1972).
Lipid materials include naturally or synthetically-derived acids, acid
derivatives, alcohols, esters, ethers, ketones, and amides with carbon
chains of from 12 to 22, preferably from 16 to 18, carbon atoms in length.
Fatty alcohols and fatty esters are preferred; fatty alcohols are
particularly preferred.
Lipid materials among those useful herein are disclosed in Bailey's
Indistrial Oil and Fat Products, (3d edition, D. Swern, ed. 1979)
(incorporated by reference herein). Fatty alcohols included among those
useful herein are disclosed in the following documents, all incorporated
by reference herein: U.S. Pat. No. 3,155,591, Hilfer, issued Nov. 3, 1964;
U.S. Pat. No. 4,165,369, Watanabe et al., issued Aug. 21, 1979; U.S. Pat.
No. 4,269,824, Villamarin et al., issued May 26, 1981; British
Specification 1,532,585, published Nov. 15, 1978; and Fukushima et al.,
"The Effect of Cetostearyl Alcohol in Cosmetic Emulsions", 98 Cosmetics &
Toiletries 89-102 (1983). Fatty esters included among those useful herein
are disclosed in U.S. Pat. No. 3,341,465, Kaufman et al., issued Sept. 12,
1967 (incorporated by reference herein).
Preferred esters for use herein include cetyl palmitate and
glycerylmonostearate. Cetyl alcohol and stearyl alcohol are preferred
alcohols. A particularly preferred lipid vehicle material is comprised of
a mixture of cetyl alcohol and stearyl alcohol containing from about 55%
to about 65% (by weight of mixture) of cetyl alcohol.
Creme rinse and conditioner compositions of the present invention generally
comprise from about 0.5% to about 12% of the silicon compound, from about
0.5% to about 3% of the lipid vehicle material, and from about 0.2% to
about 4% of the cationic surfactant vehicle material.
Deodorant/Antiperspirants
Deodorant/antiperspirant compositions utilizing the volatile silicon
compounds include a variety of components.
Antiperspirant Actives
Antiperspirant compositions comprise at least one antiperspirant active.
Antiperspirant actives useful in the present invention are well known in
the art, and are disclosed generally in Miller and Hoag, "Personal Care
Products", Handbook of Nonprescription Drugs, 8th Edition, Chapter 19,
pages 397-417 (American Pharmaceutical Association; 1986), the disclosures
of which are incorporated herein by reference in their entirety.
Antiperspirant actives useful herein are also more specifically disclosed
in European Patent Application Publication No. 28,853, published May 20,
1981, by Beckmeyer et al.; and European Patent Application Publication No.
117,070, published Aug. 29, 1984, by May, the disclosures of both these
patent specifications being incorporated herein by reference in their
entirety. Antiperspirant actives include, for example, aluminum
chlorohydrates, aluminum chloride, sodium aluminum chlorohydroxy lactate,
buffered aluminum sulfate, and aluminum zirconium chlorohydrates.
Preferred are astringent metallic salts including the inorganic and organic
salts of aluminum, zirconium and zinc, and mixtures thereof. Particularly
preferred are the aluminum and zirconium salts, such as aluminum halides,
aluminum hydroxyhalides, zirconyl oxyhalides, zirconyl hydroxyhalides, and
mixtures thereof. Such metal salts, and complexes thereof, are described
in European Patent Specification Publication No. 117,070, to May,
published Aug. 29, 1984, and U.S. Pat. No. 4,137,306, to Rubino et al.,
issued Jan. 30, 1979, the disclosures of both these patent specifications
being incorporated herein by reference in their entirety.
Preferred aluminum salts include those of the formula:
Al.sub.2 (OH).sub.a Cl.sub.b.xH.sub.2 O
wherein a is from about 2 to about 5; a+b=6; x is from about 1 to about 6;
and wherein a, b, and x may have non-integer values. Particularly
preferred are aluminum chlorhydroxides referred to as "5/6 basic
chlorhydroxide", wherein a=5; and "2/3 basic chlorhydroxide", wherein a=4.
Processes for preparing aluminum salts are disclosed in the following
documents, all incorporated by reference herein in their entirety: U.S.
Pat. No. 3,887,692, Gilman, issued June 3, 1975; U.S. Pat. No. 3,904,741,
Jones et al., issued Sept. 9, 1975; U.S. Pat. No. 4,359,456, Gosling et
al., issued Nov. 16, 1982; and British Patent Specification 2,048,229,
Fitzgerald et al., published Dec. 10, 1980. Mixtures of aluminum salts are
described in British Patent Specification 1,347,950, Shin et al.,
published Feb. 27, 1974, the disclosures of which are incorporated herein
by reference in their entirety.
Zirconium salts are also preferred for use in antiperspirant compositions
of the present invention. Such salts are of the general formula:
ZrO(OH).sub.2-a Cl.sub.a.xH.sub.2 O
wherein a is from about 1 to about 2, preferably from about 1.5 to about
1.87; x is from about 1 to about 7; and wherein a and x may have
non-integer values. These zirconium salts are disclosed in Belgium Patent
Specification 825,146, Schmitz, issued Aug. 4, 1975, the disclosures. of
which are incorporated herein by reference in their entirety. Particularly
preferred zirconium salts are those complexes also containing aluminum and
glycine, commonly known as "ZAG complexes". Such ZAG complexes contain
aluminum chlorhydroxide and zirconyl hydroxychloride of the formulae
detailed above. These compounds in ZAG complexes are disclosed in the
following patent documents, all incorporated by reference herein in their
entirety: U.S. Pat. No. 2,814,585, Daley, issued Nov. 26, 1957; U.S. Pat.
No. 3,679,068, Luedders et al, issued Feb. 12, 1974; U.S. Pat. No.
4,017,599, Rubino, issued Apr. 12, 1977; U.S. Pat. No. 4,120,948, Shelton,
issued Oct. 17, 1978; and British Patent Specification 2,144,992,
Callaghan et al., published Mar. 20, 1985.
The antiperspirant actives in total typically comprise from about 1% to
about 50% by weight of the composition of the present invention, more
preferably from about 5% to about 40%, and most preferably from about 5%
to about 30%.
Deodorant/Antiperspirant Carrier
The selection of carriers for use with the volatile silicon compounds of
the present invention is readily made by one skilled in the art based on
the form of the composition being prepared, for example, aerosol spray,
roll-on lotion, or stick. Antiperspirant carriers are described in detail
in European Patent Application No. 28,853, Beckmeyer et al., published May
20, 1981, and European Patent Application Publication No. 117,070, May,
published Aug. 29, 1984, the disclosures of both these patent
specifications being incorporated herein by reference in their entirety.
Carrier materials suitable for use for various composition forms are also
described in detail as follows:
(i) Stick Antiperspirant Carriers
Antiperspirant compositions in stick form contain the volatile silicon
compound, which may function as a liquid emollient and preferably contain
one or more non-volatile emollients. Such materials include fatty acid and
fatty alcohol esters, waterinsoluble ethers and alcohols,
polyorganosiloxanes, and mixtures thereof. Emollients among those useful
herein are described in 1 Cosmetics, Science and Technology 27-104 (M.
Balsam and E. Sagarin ed. 1972), and U.S. Pat. No. 4,202,879, Shelton,
issued May 13, 1980 (both incorporated by reference herein).
The present compositions in stick form preferably contain a non-volatile
silicone oil as an emollient material. Such silicone oils include
polyalkysiloxanes, polyalkyarylsiloxanes, and polyethersiloxane
copolymers. the essentially non-volatile polyalkyl siloxanes useful herein
include, for example, polydimethyl siloxanes with viscosities of from
about 5 to about 100,000 centistokes at 25.degree. C. Among the preferred
non-volatile emollients useful in the present compositions are the
polydimethyl siloxanes having viscosities from about 10 to about 400
centistokes at 25.degree. C. Such polyalkyl siloxanes include the Vicasil
series (sold by General Electric Company) and the Dow Corning 200 series
(sold by Dow Corning Corporation). Polyalkylaryl siloxanes include
polymethylphenyl siloxanes having viscosities of from about 15 to about 65
centistokes at 25.degree. C. These are available, for example as SF 1075
methylphenyl fluid (sold by General Electric Company) and 556 Cosmetic
Grade Fluid (sold by Dow Corning Corporation). Useful polyether siloxane
copolymers include, for example, a polyoxyalkylene ether copolymer having
a viscosity of about 1200 to 1500 centistokes at 25.degree. C. Such a
fluid is available as SF-1066 organosilicone surfactant (sold by General
Electric Company). Polysiloxane ethylene glycol ether copolymers are
preferred copolymers for use in the present compositions.
Antiperspirant compositions in stick form further preferably contain one or
more materials having wax-like characteristics and o have a melting point
of from about 65.degree. C. to about 102.degree. C. Such waxes include
beeswax, spermaceti, carnauba, baysberry, candelilla, montan, oxokerite,
ceresin, paraffin, hydrogenated castor oil (castor wax), synthetic waxes
such as Fisher-Tropsch waxes, microcrystalline wax, and mixtures thereof.
Castor wax is a preferred high-melting point wax useful herein. Such
high-melting point waxes among those useful herein are disclosed in U.S.
Pat. No. 4,049,792, Elsnau, issued Sept. 20, 1977 (incorporated by
reference herein).
(ii) Aerosol Spray Deodorant/Antiperspirant Carriers
Compositions in aerosol spray form preferably contain one or more volatile
materials, herein "aerosol propellants", which in a gaseous state, carry
the other components of the spray composition in particulate or droplet
form. The aerosol propellants useful in the present invention typically
have a boiling point within the range of from about -45.degree. C. to
about 5.degree. C. The aerosol propellants are liquified when packaged in
conventional aerosol containers under pressure. The rapid boiling of the
aerosol propellant upon leaving the aerosol container aids in the
atomization of the other components of the present invention.
Aerosol propellants useful in the compositions of the present invention in
spray form include those well known in the art. Such aerosol propellants
include the chemically-inert hydrocarbons such as propane, n-butane,
isobutane and cyclopropane, and mixtures thereof, as well as halogenated
hydrocarbons such as dichlorodifluoromethane (propellant 12),
1,1-dichloro-1,1,2,2-tetrafluoroethane (propellant 114),
1-chloro-1,1-difluoro-2,2-trifluoroethane (propellant 115),
1-chloro-1,1-difluoroethylene (propellant 142B), 1,1-difluoroethane
(propellant 152A), and monochlorodifluoromethane, and mixtures thereof.
Isobutane, used singly or admixed with other hydrocarbons, is preferred
for use in the present aerosol spray antiperspirants.
Another preferred material for use in the aerosol compositions in aerosol
spray form is a silicone gum. As referred to herein, "silicone gum"
materials useful in the present compositions are those non-functionalized
siloxanes having a viscosity of from about 500,000 to about 100,000,000
centistokes at 25.degree. C. These materials are incorporated in the
present compositions at a level of from about 0.05% to about 5.0%,
preferably from about 0.10% to about 2.0%. Preferred silicone gums include
linear and branched polydimethyl siloxanes, of the following general
formula:
(CH.sub.3).sub.3 SiO--Si (CH.sub.3).sub.2 O.sub.n --Si(CH.sub.3).sub.3
wherein n is from about 2,000 to about 15,000, preferably from about 2,000
to about 7,000. The silicone gums useful herein may also be substituted
with non-electronegative substituents. Silicone gums among those useful
herein are available from a variety of commercial sources, including
X2-1346 and Dow Corning 200 Fluid (manufactured by Dow Corning
Corporation), PS240 (manufactured by Petrarch Systems, Inc.), and SE76,
SE30 and SE32 Silicone Gums (manufactured by General Electric Company).
The aerosol compositions may also contain a bulking or suspending agent, at
levels of from about 0.1% to about 7%, preferably from about 0.4% to about
3.5%. Such bulking/suspending agents include talc, colloidal silicas,
clays and mixtures thereof. Clays and colloidal silicas are particularly
preferred. Clay bulking/suspending agents include montmorillonite clays
and hydrophobically treated montmorillonites, e.g., bentonites, hectorites
and colloidal magnesium aluminum silicates. These materials are available
from a variety of sources, including Laponite hectorite (sold by Laponite
Industries, Ltd.) and Veegum magnesium aluminum silicate (sold by R. T.
Vanderbilt Co.). A preferred clay bulking/suspending agent is
hydrophobically-treated montmorillonite, such as the Bentone bentonites
(sold by NL Industries, Inc.). Colloidal silicas are also readily
available, such as Cab-0-Sil pyrogenic colloidal silica (sold by Cabot
Corporation).
(iii) Roll-on Lotion Deodorant/Antiperspirant Carriers
Antiperspirant/deodorant compositions of the present invention in roll-on
lotion form typically comprise carrier materials similar to those utilized
in aerosol spray forms except that no aerosol propellant is required.
Antiperspirant/deodorant compositions in roll-on lotion form, and carrier
materials useful therein, are described in detail in European Patent
Application Publication No. 28,853, Beckmeyer et al., published May 20,
1981, the disclosures of which are incorporated herein by reference in
their entirety.
Additional active components include bacteriostats and fungistats. The
particular non-active components that may be useful will depend upon the
form of application that is desired. Such components include, for example,
emollients, colorants, perfumes, and emulsifiers. Optional components
useful herein are described in the following documents, all incorporated
by reference herein: U.S. Pat. No. 4,049,792, Elsnau, issued Sept. 20,
1977; Canadian Patent 1,164,347, Beckmeyer et al., issued Mar. 27, 1984;
European Patent Specification 117,070, May, published Aug. 29, 1984; and
Geria, "Formulation of Stick Antiperspirants and Deodorants," 99 Cosmetics
& Toiletries 55-60 (1984).
Generally, the deodorant/antiperspirant carriers in total comprise from
about 40% to about 99% by weight of the compositions of the present
invention, preferably from about 55% to about 95%, and most preferably
from about 67% to about 94%.
Other cosmetic and household product compositions are disclosed in U.S.
Pat. No. 4,687,592, Collins et al., issued Aug. 18, 1987; U.S. Pat. No.
4,663,157, Brock, issued May 5, 1987; U.S. Pat. No. 4,631,064, Juneja;
issued Dec. 23, 1986; and U.S. Pat. No. 4,130,121, Wetzel, issued Dec. 19,
1978. All of these references are incorporated herein by reference.
METHOD OF MANUFACTURE OF VOLATILE SILICONS
The compositions of the present invention can be prepared by methods which
are well known in the art.
The following nonlimiting examples of the present invention are given
solely for illustration and are not to be construed as limitations of this
invention. Many variations are possible without departing from the spirit
and scope thereof. The volatile silicon compounds in the various examples
are identified in previous discussion.
EXAMPLE I
The following is a highlighting rinse representative of the present
invention:
______________________________________
Component Weight %
______________________________________
D & C Red #17 0.10
Volatile Silicon Compound A
5.00
Cetyl Alcohol 2.00
Ditallow Dimethyl Ammonium Chloride
1.00
Ceteareth-20 1.00
Kathon CG 0.04
Double Reverse Osmosis Water
q.s
______________________________________
EXAMPLE II
The following is a shampoo representative of the present invention.
______________________________________
Component Weight %
______________________________________
Ammonium Lauryl Sulfate
15.00
Jaguar HP-60.sup.1 1.00
G.E. SE 30.sup.2 1.00
Volatile Silicon Compound D
1.00
Kathon CG.sup.3 0.04
Double Reverse Osmosis Water
q.s.
______________________________________
.sup.1 Hydroxypropyl guar gum offered by Hitek Polymers Inc.
.sup.2 Silicone gum offered by General Electric
.sup.3 Offered by Rohm and Haas
EXAMPLE III
The following is a men's grooming aid representative of the present
invention.
______________________________________
Component Weight %
______________________________________
Volatile Silicon Compound C
86.00
Dow Corning X2-2G13.sup.1
8.00
Perfume 1.00
Ethanol 5.00
______________________________________
.sup.1 A copolymer of methylphenyl and diphenyl siloxane offered by Dow
Corning
EXAMPLE IV
The following is a hair styling mousse representative of the present
invention.
______________________________________
Component Weight %
______________________________________
Gafquat 755 2.00
Cocamine oxide 0.50
Kathon CG 0.04
Volatile Silicon Compound C
2.00
Isobutane 6.00
Distilled Water q.s.
______________________________________
EXAMPLE V
The following is a hair conditioning rinse representative of the present
invention.
______________________________________
Component Weight %
______________________________________
Stearalkonium Chloride
2.00
Stearyl Alcohol 0.90
Cetyl Alcohol 1.10
Volatile Silicon Compound B
4.00
G.E. SE 30 Silicone Gum
1.00
Kathon CG.sup.1 0.04
Distilled Water q.s.
______________________________________
.sup.1 Offered by Rohm and Haas
EXAMPLE VI
The following is a hairspray composition representative of the present
invention.
______________________________________
Component Weight %
______________________________________
Amphomer 3.00
Aminomethyl propanol
0.50
Volatile Silicon Compound C
1.00
Ethanol 70.5
Isobutane Propellant
25.00
______________________________________
EXAMPLE VII
The following is a cold-wave hair perm representative of the present
invention.
______________________________________
Component Weight %
______________________________________
Thioglycolic Acid 7.00
Monoethanolamine 9.00
Volatile Silicon Compound C
3.00
Polyethylene Glycol 400 Monostearate
0.50
Distilled Water q.s.
______________________________________
EXAMPLE VIII
The following is a cologne representative of the present invention.
______________________________________
Component Weight %
______________________________________
Volatile Silicon Compound A
45.00
Propylene Glycol 2.00
Perfume 2.00
Polydimethylsiloxane 350 cs.
1.00
Isobutane 50.00
______________________________________
EXAMPLE IX
The following is an antiperspirant stick representative of the present
invention.
______________________________________
Component Weight %
______________________________________
Crodomol PMP.sup.1 15.00
Syncrowax BB4.sup.1 1.50
Incroquat Behenyl TMS.sup.2
12.00
Incromide BEM.sup.2 12.00
Volatile Silicon Compound D
37.00
Rezel 36q Superultrafine.sup.3
20.00
Talc 1.00
Cab-O-Sil M-5.sup.4 1.50
______________________________________
.sup.1 Offered by Croda, Inc.
.sup.2 Offered by Croda Surfactants, Inc.
.sup.3 Offered by Reheis Chemical Company
.sup.4 Offered by Cabot Corporation
EXAMPLE X
The following is a solid deodorant representative of the present invention.
______________________________________
Component Weight %
______________________________________
Volatile Silicon Compound B
39.00
Sodium Stearate 9.00
Propylene Glycol 15.00
Ethanol q.s.
PPG-10 Cetyl Ether 10.00
Isostearyl Alcohol 3.00
Perfume 0.50
______________________________________
EXAMPLE XI
The following is a roll-on antiperspirant representative of the present
invention.
______________________________________
Component Weight %
______________________________________
Volatile Silicon Compound A
64.60
Isopropyl Myristate 5.00
Tixogel VP.sup.1 3.00
Aluminum Zirconium Trichlorohydrate
25.00
Ethanol (95%/5% water) 2.00
Perfume 0.10
Cab-O-Sil M-5.sup.2 0.30
______________________________________
.sup.1 Offered by United Catalysts Inc.
.sup.2 Offered by Cabot
EXAMPLE XII
The following is a hand lotion representative of the present invention.
______________________________________
Component Weight %
______________________________________
Volatile Silicon Compound D
3.00
Mineral Oil 1.00
Polydimethylsiloxane, 350 C
1.00
Stearic Acid 3.00
Cetyl Alcohol 2.00
Triethanolamine 1.00
Glydant 0.35
Glycerine 5.00
Carbopol 941.sup.1 0.20
Distilled Water q.s.
______________________________________
.sup.1 Offered by B. F. Goodrich
* * * * *
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