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Optical disk employing electron trapping material as a storage medium    
United States Patent5142493   
Link to this pagehttp://www.wikipatents.com/5142493.html
Inventor(s)Lindmayer; Joseph (Rockville, MD)
AbstractAn erasable optical disk drive system is disclosed which utilizes an electron trapping media coated on the disk surface to store data in the form of light energy. Data is written onto the disk, which is contained in a light-tight contamination-free environment similar to a Winchester hard disk drive system, using a near infrared light laser beam. Data is read from the disk using a visible light laser beam. The entire optical disk drive system is designed to fit within a standard mini or 51/4 inch disk drive form factor for personal computers.



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Drawing from US Patent 5142493
Optical disk employing electron trapping material as a storage medium - US Patent 5142493 Drawing
Optical disk employing electron trapping material as a storage medium
Inventor     Lindmayer; Joseph (Rockville, MD)
Owner/Assignee     Quantex Corporation (Rockville, MD)
Patent assignment
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Publication Date     August 25, 1992
Application Number     07/495,421
PAIR File History     Application Data   Transaction History
Image File Wrapper   Patent Term   Fees
Litigation
Filing Date     March 19, 1990
US Classification     365/119 346/135.1 369/100 430/58.1
Int'l Classification     G11C 013/00 G11B 007/00
Examiner     Popek; Joseph A.
Assistant Examiner    
Attorney/Law Firm     Ostrolenk, Faber, Gerb & Soffen
Address
Parent Case     This application is a divisional application of U.S. patent application Ser. No. 07/225,846, filed Jul. 29, 1988, and entitled "Optical Disk Drive System", now U.S. Pat. No. 5,007,037.
Priority Data    
USPTO Field of Search     369/100 346/76 L 430/58 430/85 365/119 365/122 365/106
Patent Tags     optical disk employing electron trapping material storage medium
   
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What is claimed is:

1. An optical disk for use with a computer optical disk drive system, comprising:

a substrate; and

an electron trapping material disposed on said substrate, said electron trapping material having a plurality of energy levels including a ground level and a trapping level;

wherein writing storable data on said optical disk is accomplished by raising electrons in said material from said ground level to said trapping level at selected locations by subjecting said selected locations to a charging light of a first wavelength within an activation bandwidth of said electron trapping material;

wherein reading of said storable data on said optical disk is accomplished by releasing electrons from said trapping level such that they fall back to said ground level by subjecting said selected locations to infrared light of a second wavelength within a stimulation bandwidth of said electron trapping material; and

wherein the electrons emit visible light upon falling back to said ground level.

2. An optical disk according to claim 1, wherein said electron trapping material comprises:

a base material selected from a group of alkaline earth metal sulfides;

a first dopant for establishing an electron trapping level; and

a second dopant for establishing a communication band.

3. An optical disk according to claim 2, wherein said base material comprises strontium sulfide.

4. An optical disk according to claim 2, wherein said base material comprises calcium sulfide.

5. An optical disk according to claim 2, wherein said base material comprises a combination of strontium sulfide and calcium sulfide.

6. An optical disk according to claim 2, wherein said first dopant comprises about 50 to about 600 parts per million samarium.

7. An optical disk according to claim 6, wherein said second dopant is a material selected from the group consisting of europium oxide, europium fluoride, europium sulfide, and cerium oxide.

8. An optical disk according to claim 6, wherein said second dopant comprises about 300 to about 800 parts per million of a material selected from the group consisting of europium oxide, europium fluoride, and europium sulfide.

9. An optical disk according to claim 7, wherein said second dopant comprises about 300 to about 1500 parts per million cerium oxide.

10. An optical disk according to claim 2, further comprising a plurality of additional, differently doped electron trapping materials, each of said electron trapping materials outputting the visible light of a different wavelength.

11. An optical disk according to claim 1, wherein the thickness of the electron trapping material is about 5 microns.

12. An optical disk according to claim 1, wherein said substrate is comprised of alumina.

13. An optical disk according to claim 1, further comprising an interlayer material disposed between said substrate and said electron trapping material providing a chemical barrier to prevent any leaching of said substrate into said electron trapping material.

14. An optical disk according to claim 1, further comprising a first protective layer disposed on top of said electron trapping material for preventing chemical contamination of said electron trapping material.

15. An optical disk according to claim 14, further comprising a second protective layer disposed on top of said first protective layer for preventing environmental contamination of said optical disk.
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BACKGROUND OF THE INVENTION

Cross Reference to Related Application

The assignee herein is also the assignee of U.S. patent application Ser. No. 870,877, filed Jun. 5, 1986, and entitled "Optical Memory Method and System," which issued as U.S. Pat. No. 4,864,536 on Sep. 5, 1989, and U.S. patent application Ser. No. 184,263, filed Apr. 21, 1988, and entitled Method of Making Thin Film Photoluminescent Articles, now U.S. Pat. No. 4,915,982. The disclosures of both of those applications are incorporated by reference herein.

The present invention relates generally to mass storage devices for data storage. More particularly, the present invention relates to a method of and apparatus for mass data or information storage utilizing purely photoelectronic processes for writing, reading, and erasing stored data.

Optical storage devices presently known generally permit two to three orders of magnitude more data to be stored per disk than with magnetic methods and apparatus. Because of the potential for much greater storage of data and also because of the enormous projected market for such optical memories, active development of optical storage devices is currently occurring in several different directions. Such activities are directed towards read-only, write-once-read many times (WORM) and erasable optical memory systems. While read only and WORM optical memories are already available, erasable optical memory systems have encountered much greater developmental difficulties than read-only WORM systems because the qualities of the storage media required present problems of much greater technical complexity.

Read-only optical memory devices for use as computer peripherals, such as CD-ROMs, became commercially available with the advent of the digital audio compact disk. Current disk data storage capacity for such units is 200-600 megabytes. Such disks are factory fabricated using a molding press and metalizing operations and are suitable for low cost distribution of large fixed database information.

WORM devices allow the user to encode his own data on the disk, however only once. Data bits are stored at physical locations by irreversibly "burning" the medium with a laser. Such permanent encoding can be read back indefinitely, thus making WORM technology suitable for archival storage of large quantities of information, including digitized images, where random access to a large database is desirable.

It is the third category of optical disk storage devices, namely erasable storage devices, that is believed to embody the greatest utility for mass storage purposes. Such devices will be competitive with present magnetic tape and disk mass storage, and will have a major impact on computer technology in the years ahead. At present, the three most active approaches now being pursued for erasable optical storage involve magneto-optical material systems, dye polymers, and techniques that produce crystal structure or phase transformation in the storage medium at the spot being written to. All of these approaches require heat which usually changes the physical or chemical structure of the materials in performing the write or erase function. Thus, the time to write data to such systems is dependent upon a certain "dwell" time during which the spot to which data is being written must be heated or otherwise physically transformed.

Another drawback with such approaches is that media performance is highly sensitive to impurities, impurity diffusion, oxidation, and other imperfections that propagate into defects and that only show up after multiple switching cycles or at times later than the manufacturing and testing of the devices. Of the three approaches discussed above, progress has been greatest with magneto-optic materials. Laboratory results in this area have reported millions of write/erase cycles. See, for example, H-P. D. Shieh Ph.D. Thesis, Carnegie-Mellon University, Pittsburgh, Pa. (1987).

In order to utilize erasable optical media for mass storage, the optical media must be fast enough to be marked at high data rates using low power lasers. The media must also maintain almost error-free data at acceptable computer industry standards for at least ten years, for example, no more than one uncorrectable error in 10.sup.12 bits. Thus, finding the right physical phenomenon to serve as the basis for erasability in a high-speed, high-resolution optical storage medium for use with an optical disk storage system has been very difficult. Most of the effort in this area over the past ten years, as described above, has gone into the use of magneto-optic materials. However, the commercial realization of erasable magneto-optical storage has not yet been achieved, nor are there yet any guarantees that it ever will be. Unfortunately, the performance of the other approaches discussed above generally is not comparable.

In order to overcome the problems of the prior art, and provide a basis for a workable optical disk storage system, a new approach to the optical storage materials problem which satisfies the optical media requirements of density, speed and long cycle life has been developed. This development utilizes the phenomenon of electron trapping in a class of new materials which comprise an alkaline earth crystal typically doped with rare earth elements. Thin crystalline films of such materials are formed on various substrates, such as glass or alumina, in order to provide the disk storage medium.

Since the trapping phenomenon is a purely electronic process, read/write/erase operations can be performed very fast. In addition, the physical trapping phenomenon suggests that media life may be practically limitless. Also, the effect of electron trapping yields a linear response characteristic, which provides an analog dimension to the storage capability. Thus, for example, the potential disk storage capacity of a single 51/4 inch disk could be extended to several gigabytes. Obviously, the density of stored information is extremely high.

The materials to be used as the media for the optical disk storage system described herein are the subject of U.S. patent application Ser. No. 184,263, filed Apr. 21, 1988 now U.S. Pat. No. 4,915,982 which is a continuation-in-part of U.S. patent application Ser. Nos. 870,877 and 870,809, both filed Jun. 5, 1986, now U.S. Pat. Nos. 4,864,536 and 4,830,875, respectively. Other materials useful as the storage media herein are disclosed in co-pending U.S. patent application Ser. Nos. 034,332 and 034,334 both filed in Apr. 3, 1987, now U.S. Pat. Nos. 4,839,092 and 4,806,772, respectively; 147,215 filed Jan. 22, 1988 now U.S. Pat. No. 4,842,960; and 078,829 filed Jul. 28, 1987, now U.S. Pat. No. 4,842,960. The assignee herein is the assignee in each of those applications. The disclosure of each of those applications is incorporated by reference herein.

The material described in U.S. Pat. No. 184,263 demonstrates an extremely linear relationship between the write input and the read output. Thus, this capability demonstrates a large noise margin for binary storage, as well as the possibility of increased information storage density when employed as an analog or multi-level digital memory medium. Multi-level refers to the fact that by writing with a plurality of intensities of the same laser beam, the linearity of the resulting emissions upon being impinged by a read laser beam is such that information can be stored and recognized at various "levels" of intensity, for example, at 0.2, 0.4, 0.6, 0.8 and 1 intensity. This particular media is in the form of a thin film and can be "charged" and "discharged" with light by exciting ground state electrons to an elevated energy level. Specifically, upon illumination by visible light, electrons are raised to high energy trapping states, where they can remain indefinitely. When later illuminated by infrared light, the electrons are released from the traps, emitting a new visible light. Thus, with such materials, digital data is stored and retrieved by using low energy lasers to trap and read the electrons at a particular location.

Such solid state photonic materials have electrons having bi-stable equilibrium states; one with electrons in a ground state, and the other in which electrons are "trapped" in a well-defined, specific elevated energy state. Electrons are raised to the higher energy state by the absorption of visible light photons, thus filling available trap sites. An electron in the elevated energy state can be released from its trap site by inputting sufficient energy to the electron to permit it to escape from the well. When that occurs, the electron falls back to its ground state and emits a corresponding visible photon. The number of electrons in the elevated energy state is proportional to the visible light intensity used for recording. Thus, as a result of such characteristics, such materials can, in effect, "store" light energy.

The purely photo-electronic mechanisms involved in such electron trapping materials obviate the need for any thermal excursions and, therefore, the number of electrons trapped in the material is inherently linear. Since localized resolution of the "write" step depends only on the performance of the addressing optics, an optical writing spot diameter of one micron will allow at least 550 megabytes of storage on a 130 mm or 51/4" disk coated with the thin film material as disclosed herein. With the use of encoding techniques such as MFM, modified MFM, or record length limiting (RLL), which techniques are commonly used with magnetic disk recording, the storage capacity can be increased by up to a factor of 3 over the use of FM or frequency modulation coding. The rise and fall times associated with optical read and write pulses are in the nanosecond range. Thus, the read and write data transfer rates have been found to be at least 200 megabits per second for optical disk drive media utilizing electron trapping materials.

Rotating disk memory systems require directions for the retrieval of the stored information. One set of those directions informs the drive mechanism where the requested information is or will be stored. The other set provides alignment for the read/ write mechanism during processing. The alignment parameters include focusing, speed, tracks, and mark locations. The writing of information is dependent upon the media used such as write once, magneto-optic, dye polymer, or phase change, but in all cases, involves a change in the reflection parameters in the spot written to. The read method is based on detecting such reflectivity changes at the surface of the disk.

The common method presently used for tracking with reflective surface optical disks, such as the compact disc, is to rely on a grouped track as the principal mode of aligning and focusing the read/write head in the middle of the track. The speed information is either contained in the repetitive pattern of marks or in a depth modulation of the group.

Yet another tracking method presently utilized is known as the "Sampled Servo" system. This system relies on changes in the reflection of spots on the disk surface. The spots are located in the manner which provide information about the track location, the speed of the disk and the adequacy of focusing.

The erasable optical disk memory systems disclosed herein, which rely upon a thin film of electron trapping material as the media, do not rely on reflection for readout. Rather, the emission of the media under infrared stimulation can be utilized to retrieve pre-written tracking information from the disk.

SUMMARY AND OBJECTS OF THE INVENTION

In view of the foregoing, it should be apparent that there exists a need in the art for a method of and apparatus for operating and constructing an erasable optical disk memory system in which electron trapping material used as the storage media permits writing, reading, and erasing essentially an unlimited number of times. It is, therefore, a primary object of this invention to provide a method of and apparatus for operating and constructing an erasable optical disk drive system which is characterized by an electron trapping media such that the write, read, and erase functions can be accomplished with high density, speed and without serious degradation over a large number of erased functions.

More particularly, it is an object of this invention to provide an erasable optical disk memory system for information storage which is capable of storing orders of magnitude more data per disk than inductive magnetic media systems.

Still more particularly, it is an object of this invention to provide an erasable optical disk drive memory system in which data is stored as light energy and which is not dependent upon the reflective properties of the disk for effecting storage or readout of stored information.

Briefly described, these and other objects of the invention are accomplished in accordance with its apparatus aspects by providing a disk containing a coating of thin film electron trapping material which is rotated in a manner similar to that of magnetic hard disk drives, also known as Winchester disk drives. Data is read onto the disk in the form of a write laser operating at a wavelength of visible light, preferably with wavelengths peaking between 450 and 600 nanometers and preferably at about 450 nanometers. A read laser is utilized to irradiate the disk with near infrared radiation having a wavelength with peaks between 700 and 1,450 nanometers, but preferably at about 1,000 nanometers. When stimulated by the near infrared read radiation, any stored bits (representing, for example, a binary one) will cause a predetermined radiation emission characteristic that peaks in the orange light band, at about 620 nanometers. Such a detected emission corresponds to a binary one recorded at that point. The absence of such radiation emission characteristic corresponds to a binary zero recorded at that point.

The optical disk memory storage system of the present invention also includes an optical processing unit for transmitting both the read and write laser beams to the read/write head, as well as various detector electronics and positioning electronics for positioning the head over the disk. Data output and data input is handled by a standard computer interface.

With these and other objects, advantages and features of the invention that may become hereinafter apparent, the nature of the invention may be more clearly understood by reference to the following detailed description of the invention, the appended claims and to the several drawings attached herein.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a diagram showing the principles of operation of the thin film storage media applied to the surface of the disk used with the present invention;

FIG. 2 is a graph showing the trap-filling efficiency of a particular electron trapping film suitable for use with the present invention as a function of the wavelength of the exciting energy;

FIG. 3 graph showing the relative infrared sensitivity for the read and erase functions for the same particular electron trapping material as FIG. 2;

FIG. 4 is a graph showing the wavelengths of emission from the disk upon their infrared illumination for the same particular electron trapping material shown in FIGS. 2 and 3;

FIG. 5 is a graph of the relative luminescence or read output as a function of write energy for the same particular electron trapping material as shown in FIGS. 2-4;

FIG. 6 is a pictorial diagram of the structure of the optical disk used with the present erasable optical disk memory system;

FIG. 7 is a schematic block diagram of the electronics and optics necessary for reading, writing, and erasing data onto and from the disk;

FIG. 8 is a pictorial partially cut-away drawing of the optical disk storage system of the present invention;

FIGS. 9A and 9B are schematic block diagrams of the position servo tracking and velocity servo tracking circuitry for use with the optical disk drive memory system of the present invention; and

FIG. 10 is a schematic block diagram of the optical processing unit and actuator arm assembly for use with the optical disk drive memory system of the present invention.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

Referring now in detail to the drawings wherein like parts are designated by like reference numerals throughout, there is illustrated in FIG. 1 an explanation of the basis of the operation of the class of optical storage media electron trapping materials used with the erasable optical disk drive memory system of the present invention. As illustrated in FIG. 1, the wide bandgap host material includes selected impurities which are associated with energy levels ET. The narrow E band is designated as the communication band since electron interaction is allowed there. At level T, which is referred to as the trapping level, the trapping sites are non-communicating because they do not allow electron interaction.

As indicated in FIG. 1, visible radiation, or charging light, excites carriers so that they can fill the trapping sites. The trapped depth in these group II-VI phosphors, of about 1.2 electron volts, is sufficiently above the thermal energy range of the phosphors such that electrons cannot be dislodged by thermal agitation. By controlling the trapped density, the tunneling interchange at trapping level T may be cut off. Under such conditions, the trapped electrons cannot communicate with each other, and the possibility of recombination is thus eliminated.

When the charging radiation terminates and the electron trapping material is in its electronically energized state, the traps are filled, communication band E is empty, and recombination from trapping level T to valence band G is nonexistent. As a consequence, the electrons in the trapping level T will remain or be "stored" there for a time which approaches infinity.

If the charged electron trapping material is then exposed to infrared or near infrared light, sufficient energy equal to the difference between the energy of an electron in the communication band E minus the energy of an electron at trapping level T is provided which serves to move electrons from the trapping level T to the communication band E. While in the communication band E, the electrons may interact and then return to the ground state or valence band G. However, as the electrons return from the communication band D to the valence band G, a photon of energy E minus G is emitted. By the selection of an appropriate doping rare earth element, the wavelengths of light given off by the photon emitted when an electron falls from the communication band E down to the valence band G can be predetermined. The sensing of the occurrence of such an emission serves to indicate whether a particular point being addressed on the disk surface contained a bit (signifying a 1) or no bit (signifying a 0), or vice versa.

In contrast to the physical changes which occur by the use of a writing laser beam in known approaches to erasable (and non-erasable) optical storage systems, the writing and erasing of a spot on the surface of electron trapping materials requires only a change in the energy state of the electrons at that spot. Since no heating is involved, latent, defect induced read, write, and erasable forms of degradation do not occur. Consequently, the number of switching cycles in the electron trapping material is virtually unlimited, exceeding 10 million write/erase cycles with no observed change in the thin film.

The filling of the traps at trapping level T requires that a threshold energy be exceeded. A characteristic curve for the preferred electron trapping material for use as the storage media with the present invention, is shown in FIG. 2. That preferred material is disclosed in U.S. Pat. No. 4,842,960. As shown in FIG. 2, the threshold energy level which must be exceeded in order to fill the trapping level T begins at wavelengths of visible light shorter than 600 nanometers.

After the traps contained in the trapping level T are filled, impingement of near infrared radiation can cause electrons to be released. A graph showing the relative infrared sensitivity versus the peaks of the infrared radiation is shown in FIG. 3. In all instances, the graphs shown in FIGS. 2-5 are for the same material described in connection with FIG. 2. As shown in FIG. 3, for the material discussed herein for use with the preferred embodiment, the most efficient rate of release occurs at wavelengths having peaks of just under 1 micron, or at about 1,000 nanometers.

As shown in FIG. 4, when the thin phosphor film disclosed herein for use in the preferred embodiment is stimulated by infrared radiation having peaks whose wavelengths are shown in FIG. 3, the phosphor film displays an emission characteristic that peaks in the orange light band, at about 620 nanometers. It should be noted, however, that FIGS. 2-5 are only representative and that peak wavelengths can be altered by changing the rare earth element dopants. In addition, the spectral widths of the responses can also be altered within certain limits.

The number of electrons trapped in the higher energy state at trapping level T is proportional to the amount of writing energy incident on the surface of the thin film electron trapping material. As shown in FIG. 5, saturation is reached, for the thin film material useful for the preferred embodiment, at a level of about 5 milijoules per square centimeter. At lower flux levels, linearity is observed through orders of magnitude. In addition, the read-out emission is also linear with respect to the intensity of the write beam. This linearity characteristic of the electron trapping material allows such material, using the optical disk drive system disclosed herein, to record and read back analog signals, such as video or analog data transactions, using amplitude modulation, which is not possible with other optical disk drive systems.

If the traps contained in the trapping level T are physically separated by more than a tunneling distance, they do not communicate with each other and self-discharge is eliminated. This condition corresponds to a highest density of excited electrons on the order of about 10.sup.20 per cubic centimeter. Each time an infrared signal is applied to the charged electron trapping film, emission of orange light occurs. Of course, with each photon emitted, the number of electrons remaining in traps in the trapping level T is reduced. Depending on the sensitivity of the detector which, in this case is at 620 nanometers, many readings can be made before the traps are depleted. For the examples given herein, complete erasure of a bit storage spot 1 micrometer in diameter requires approximately 1 picojoule of infrared energy. Of course, depletion can be avoided, if necessary, by periodic refreshing of the stored data.

As briefly described above, the ability of electron trapping materials to "store" energy received in the form of light and to later release that energy upon interrogation by another light beam, comprises the means of digital switching used by the storage media of the present invention. Data points on the storage media surface that have electrons trapped in the elevated state can be interpreted as "on" or a binary one, while those with no electrons in the elevated state are interpreted as "off" or binary zero. Conversely, changed data points can be interpreted as "zeros" and unchanged data points as "ones". It is also possible to "charge" the entire disk with visible light and to write data using the infrared read beam. In that case, the ones or zeros would be stored on the disk at points which have been discharged and vice-versa. Also, only a single infrared beam would be necessary to both read and write data.

Since at each such spot there are sufficient electrons that can switch energy states, the present invention optically determines whether a spot is a binary zero or one without altering the "switch" setting. That is accomplished by interrogating the spot with an infrared beam of low intensity in order to release a small fraction of the elevated energy electrons, enough to determine whether or not the spot is a binary one or binary zero. However, as a practical matter, not enough of the elevated energy electrons are released to significantly deplete the inventory of energized electrons stored at that spot. Utilizing the particular electron trapping thin film materials discussed herein for media storage, switching or write/erase speeds of 5 nanoseconds or less are achieved.

It is also possible to coat multiple layers of differently doped electron trapping materials, one on top of the other. Since each layer produces a different wavelength of output emission, it is possible to separate the read beam signals on that basis. Binary codes can additionally be used to distinguish between layers.

In addition, the read, write and erase laser power requirements for the present invention are low. It is sufficient for the write energy to be a fraction of 1 picojoule per cubic micron, for example, about 0.5 picojoule per cubic micron. The read energy is at femtojoules, for example, about 10 femtojoules per cubic micron. The erase energy is about 1 picojoule per cubic micron. In watts, the write laser power is preferably about 0.1 mW, the read laser power about 0.5 mW and the erase laser power is preferably about 2.0 mW.

FIG. 6 is a side view of an optical disk showing the disk substrate 12 upon which the electron trapping layer 16 is deposited. The disk substrate 12 is preferably made from an optical alumina material. However, it could also be made from other materials such as optical glass, which can be readily coated with a thin film material and withstand the temperatures necessary to fuse the crystalline structure of the thin film material. The first material deposited onto the disk substrate 12 is an interlayer material 14 with a thickness of about several hundred Angstroms. The purpose of this interlayer 14 is to define a crystalline surface structure for the electron trapping layer. It also provides a chemical barrier to prevent any leaching of the substrate material into the electron trapping layer 16. Any suitable material, such as CaO, MoO.sub.3 or ZnS may be used, however ZnS is preferred. Any suitable deposition process may be utilized.

The second layer deposited on the disk 10, on top of the interlayer 14, is the electron trapping layer 16. The thickness of the electron trapping material 16 is preferably about 5 microns. The deposition processes described in the pending U.S. patent applications referenced and