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Claims  |
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We claim:
1. A drinking straw for filtering an aqueous solution containing impurities
and delivering the filtered solution to a person's mouth, comprising:
a tube having a first end and a second end with a first passageway
therethrough, wherein the tube is sufficiently sized so that the second
end contacts the aqueous solution and the first end is receivable in the
person's mouth;
filter medium disposed in the first passageway capable of permitting the
passage of the solution through the first passageway while reducing the
amount of impurities in the aqueous solution that passes through the tube;
and
at least two plugs positioned in the first passageway such that the filter
medium is retained in a selected area of the first passageway between the
plugs, wherein the plugs are capable of permitting the passage of the
aqueous solution through the plugs but will not permit the passage of the
filter medium through the plugs,
the plugs being fixed in the passageway in a friction fit relation by the
plugs having been inserted into the passageway in a resilient but
compressed condition and on release expanding into said friction fit
relation,
wherein the plugs have increased resiliency at temperatures above room
temperature, each plug being inserted into the passageway while the plug
is at a temperature when it has increased resiliency,
the plugs being substantially uncompressible at room temperature, and
the tube being deformed outwardly locally about each plug on the plug
expanding.
2. The drinking straw of claim 1 wherein the plugs comprise an open cell
thermoplastic material having sufficiently small pores therethrough to
prevent suspended solids from passing therethrough.
3. A drinking straw as claimed in claim 2 wherein
three plugs are provided at spaced locations,
a first filter media being provided between the two plugs closest the first
end, and a second filter media being provided between the two plugs
closest the second end,
the first filter media comprising activated carbon,
the second filter media comprising a metal having a redox potential
relative to the redox potential of chlorine in the aqueous solution so as
to establish spontaneous oxidation and reduction reactions between the
metal and said chlorine.
4. A straw as claimed in claim 3 wherein said metal is in the form of a
batting of fine wire.
5. A straw as claimed in claim 4 wherein said metal comprises an alloy of
copper and zinc.
6. A straw as claimed in claim 5 further including active AlO.sub.2 for
removal of fluorine ions from the aqueous solution, said AlO.sub.2
retained within the plug closest the second end by impregnating the plug
with up to 5% by volume AlO.sub.2 during manufacture of the plug.
7. A straw as claimed in claim 5 wherein said tube comprises ABS plastic.
8. The drinking straw of claim 1 wherein the plugs comprise sintered, open
cell polyolefin material.
9. The drinking straw of claim 1 wherein the plugs comprise sintered
polyethylene having a pore size in the range of 50 to 200 microns.
10. A drinking straw for filtering an aqueous solution containing
impurities, comprising
a thin hollow tube having a first end receivable in a person's mouth and a
second end, and having a passageway within said tube between the first end
and the second end,
at least three plugs positioned within the passageway at spaced locations,
a first filter media disposed between the two plugs nearest the first end,
and a second filter media disposed between the two plugs closest the
second end,
the first filter media comprising activated carbon,
the second filter media comprising an alloy of copper and zinc having a
redox potential relative to the redox potential of chlorine to remove
chlorine impurities from the aqueous solution,
the alloy being in the form of a batting of fine wire presenting a large
surface area of the alloy into contact with the aqueous solution,
said plugs comprising a sintered, open cell polyolefin fixed in the
passageway in a friction fit realtion by the plugs having been inserted
into the passageway in a resilient but compressed condition and on release
expanded into said friction fit relation,
wherein the plugs have increased resiliency at temperatures above room
temperature, each plug being inserted into the passageway while the plug
is at a temperature when it has increased resiliency,
the plugs being substantially uncompressible at room temperature, and
the tube being deformed outwardly locally about each plug on the plug
expanding. |
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Claims  |
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Description  |
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FIELD OF THE INVENTION
The present invention relates to filtering systems for aqueous solutions
and more particularly to filtering systems contained within a drinking
straw.
BACKGROUND OF THE INVENTION
Portable filtering systems such as U.S. Pat. No. 4,298,475 to Gartner are
known which provide an elongate tube through which water is to be drawn in
the manner of a straw. Such filtering systems suffer a number of
disadvantages. Firstly, they typically require very strong suction to draw
water through them with the result that they are only really suitable for
emergency use and cannot conveniently be used to drink fluids. Secondly,
the tubes are of a relatively complex structure and are difficult to
manufacture.
SUMMARY OF THE INVENTION
Accordingly, to at least partially overcome the disadvantages of the prior
art, the present invention provides a drinking straw with a simplified
construction in which plugs to retain filter media in the straw are
retained in force fit relation within the tube.
The present invention comprises a drinking straw for filtering an aqueous
solution containing impurities and delivering the filtered solution to a
person's mouth. The drinking straw comprises a tube having a first end and
a second end with a first passageway therethrough. The tube is
sufficiently sized so that the second end of the tube contacts the aqueous
solution and the first end is receivable in the person's mouth.
A sufficient amount of a filter medium is disposed in the first passageway.
The filter medium is capable of permitting the passage of the solution
through the first passageway while reducing the amount of impurities
including bacteria in the solution that passes through the tube.
At least two plugs are positioned in the first passageway such that the
filter medium is retained in a selected area of the first passageway
between the plugs. The plugs are capable of permitting the passage of the
aqueous solution through the plugs but will not permit the passage of the
filter medium through the plugs.
The present invention also comprises a method for reducing impurities in an
aqueous solution containing impurities consumed by a person. The second
end of the above described drinking straw is placed in the solution and
the first end is sucked to draw the solution through the tube and into the
person's mouth.
BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 is an elevational view of a first embodiment of the apparatus of the
present invention.
FIG. 2 is a cross sectional view of the apparatus shown in FIG. 1, taken
along lines 2--2.
FIG. 3 is a cross sectional view of the apparatus shown in FIG. 1, taken
along lines 3--3.
FIG. 4 is a bottom end view of the apparatus shown in FIG. 1.
FIG. 5 is a top plan view of the apparatus shown in FIG. 1.
FIG. 6 is an elevational view of a second embodiment of the present
invention;
FIG. 7 is a cross-sectional view of the apparatus of FIG. 6 along line
7--7;
FIG. 8 is a cross-sectional view of the apparatus of FIG. 6 along line
8--8; and
FIG. 9 is a cross-sectional view of the apparatus of FIG. 6 along line
9--9.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS
Referring to the drawings in detail, and particularly FIGS. 1 and 2, the
drinking straw of the first embodiment of the present generally designated
by the numeral 10, comprises a tube 12 having an outer periphery 13, a
first end 14 and a second end 16 with a first passageway 18 therethrough
defining an interior wall 19; two plugs 20 and 22 positioned in the first
passageway 18; and a filter medium 24 disposed between plugs 20 and 22.
The tube 12 may be of any length or configuration suitable for the purpose
of the present invention as stated herein. Generally, a linear tube of
about seven inches from the first end 14 to the second end 16 is
sufficient. Another embodiment of the present invention (not shown),
angles about the upper third of the tube about twenty to forty degrees in
order to facilitate drinking from the straw when the straw is positioned
in a glass or other container.
The tube 12 may be of any diameter suited for the purpose of the present
invention. Preferably the tube 12 has a consistent diameter from the first
end 14 to the second end 16. The second end 16 contacts the solution which
is preferably in a container such as a glass or aluminum can. Therefore it
is preferable that the second end 16 of the tube 12 is capable of fitting
into a container such as the ring-top opening of an aluminum can.
Preferably, the tube 12 has a consistent diameter of about 10 mm.
The tube 12 has the first passageway 18 from the first end 14 of the tube
12 to the second end 16 of the tube 12, whereby a solution received by the
second end 16 of the tube may pass through the first passageway 18 to the
first end 14 of the tube 12 and into the user's mouth. The first
passageway 18 may be of any diameter which will permit a sufficient amount
of filter medium 24 (as described hereafter) to be positioned in the first
passageway 18 and permit the flow of the solution from the second end 16
of the tube 12 to the first end 14 of the tube 12 while in operation. In a
preferred embodiment, a first passageway 18 diameter of about 6 mm in a 10
mm tube has been found to be sufficient.
The tube 12 may be constructed from any suitable material which can be
exposed to an aqueous solution and be safe for human consumption. The tube
12 is preferably constructed from a durable material capable of retaining
and not substantially interacting with the filter medium as defined
hereafter. Acceptable materials for constructing the tube 12 are glass,
acrylic, polycarbonate, polyethylene, polypropylene, nylon, ABS, PCV and
styrene.
A preferred embodiment of the present invention is a seven inch, linear,
clear acrylic tube with a 10 mm diameter having a first passageway
diameter of about 6 mm.
Straw 10 includes a mouthpiece 26 having a first end 28 and a second end 30
with a second passageway 32 therethrough. The second end 30 of the
mouthpiece 26 is sized to telescope over and frictionally fit on the first
end 14 of the tube 12 as shown in FIG. 2. The first end 28 of the
mouthpiece 26 preferably tapers inward to more comfortably fit in the
user's mouth. As shown in FIG. the tapering of the mouthpiece 26 begins at
a taper point 34. The distance between the second end 30 of the mouthpiece
26 and the taper point 34 is sufficient for the mouthpiece 26 to
frictionally fit over and be supported by the first end 14 of the tube 12.
The mouthpiece 26 may be permanently attached to the tube 12 or fit snugly
enough to remain thereon unless manually removed. Alternatively, the
mouthpiece 26 may be formed as a part of the tube 12.
The second passageway 32 is sized sufficiently to receive the solution from
the first passageway 18 of the tube 12 without significantly impeding the
flow thereof. Preferably the diameter of the second end 30 of the
mouthpiece 26 is only slightly larger than the diameter of the tube 12
with the first end 28 of the mouthpiece 26 tapering slightly inward
therefrom.
The mouthpiece is constructed from a material which is durable and safely
compatible with aqueous solutions for human consumption, and preferably
slightly flexible in order to fit more snugly over the tube 12 and be more
comfortable in the mouth. In the first preferred embodiment, the distance
from the first end 28 of the mouthpiece 26 to the second end 30 of the
mouthpiece 26 is about 3.75 cm, with a distance from the second end 30 to
the taper point 34 of 1 cm.; the diameter of the second end 30 is 12 mm;
the diameter of the second passageway 32 of the second end 30 is 10 mm;
and the diameter of the second passageway 32 of the first end 28 is 5 mm
at its longest point.
As shown in FIGS. 2 and 3, the present invention also includes the first
plug 20 and the second plug 22. Plugs 20 and 22 respectively have an upper
surface 36 and 38, a lower surface 40 and 42, and an outer periphery 44
and 46.
The plugs 20 and 22 function to keep the filter medium 24, as defined
hereafter, in a selected area of the first passageway 18 of the tube 12
but permit the passage of the solution therethrough. The plugs 20 and 22
may be constructed from any material or be of any size which performs the
intended function as previously described and is safely compatible with an
aqueous solution for human consumption. The first embodiment preferably
utilizes an open cell foam material, such as polyester, having a porosity
of about 80 to about 100 pores per inch.
The plugs may be secured in the first passageway 18 in any manner.
Preferably the plugs 20 and 22 are, constructed from compressible material
and are forced into the first passageway 18 and lodged therein. When the
compression pressure is released the plugs 20 and 22 decompress, becoming
lodged in the first passageway 18, thereby retaining the filter medium 24
therebetween. In a preferred embodiment using the polyester previously
described, the diameter of the plugs 20 and 22 are slightly larger than
the diameter of the first passageway 18, and are 5-10 mm from the upper
surfaces 36 and 38 to the lower surfaces 42 and 44 respectively.
Preferably the plugs 20 and 22 are positioned in the first passageway 18
respectively near the first end 14 of the tube 12 and the second end 16 of
the tube 12 as shown in the drawings. This leaves a maximum selected area
for the filter medium to interact with the solution.
The filter medium 24 is disposed in the first passageway 18 between the
plugs 20 and 22. The filter medium 24 is capable of permitting the passage
of the solution through the first passageway 18 while reducing the amount
of impurities in the solution. The filter medium 24 is preferably capable
of reducing the amount of certain bacteria such as E. Coli and
Pseudomonas. The filter medium 24 is also preferably capable of reducing
the amount of other impurities such as chlorine, organic chemicals, iron
and algae. The filter medium 24 is also preferably bacteriostatic.
There are several factors which will affect the amount of reduction of
certain impurities in the solution, some of which are the quantity and
rate of the solution passing though the filter medium, the quantity of the
filter medium, the surface area of the filter medium, the particulate size
of the filter medium, and type of impurities in the solution. Preferably
the filter medium 24 reduces the amount of organic chemicals from about 10
percent to about 50 percent, reduces the amount of chlorine in the
solution from about 10 percent to about 75 percent, and reduces the
bacteria in the solution from about 10% to about 100%.
In a preferred embodiment, the filter medium 24 comprises zinc and copper
such as the filter medium KDF.TM. from ORC/KDF Technologies in
Constantine, Mich., as described in their promotional literature entitled
"The KDF Media" which has been submitted herewith in the Information
Disclosure Statement, of patent application Ser. No. 07/402,910, and is
hereby incorporated by reference. Although any of the KDF media as
manufactured as of the date of the filing of this application will work in
the present invention, a preferred embodiment of the present invention
utilizes KDF-55D. The first embodiment is preferably used on chlorinated
water since unchlorinated water may have an excessive amount of bacteria
that cannot be substantially eliminated with the use of the present
invention.
KDF filter media is described in U.S. Pat. No. 4,642,192 in the name of
Heskett, the disclosure of which is incorporated by reference. The filter
media comprises a metal having favourable redox potentials relative to the
5 redox potentials of impurities in the aqueous solution, notably
chlorine, so as to establish conditions for spontaneous oxidation and
reduction reactions between the impurities and the metal, thus removing
the impurities. The metal is preferably chosen from aluminum, zinc, iron,
steel and copper as well as mixtures and alloys thereof. Preferably, the
metal is an alloy of copper and zinc.
KDF.TM. is in the form of particulates of copper and zinc which range in
mesh size from -10 to 100 based on U.S. Standard Screen sizes. The metal
particulates exist as irregularly sized and shaped granules. KDF reduces
the amount of bacteria, algae, chlorine, iron, and hydrogen sulfide in
aqueous solutions.
The speed and degree of removal of the impurities is dependent, in part,
upon the contact time of the aqueous solution with the filter medium.
Increasing the contact surface of the filter medium will enhance the speed
and degree of removal of impurities. It is therefore preferable that the
maximum mesh size of the KDF or other zinc and copper filter medium is
about 60, and more preferably 40 (U.S. Standard Screen).
A sufficient amount of the filtering medium 24 is disposed in the first
passageway 18 which is an amount sufficient to reduce at least a portion
of the impurities in the solution as defined herein. In a preferred
embodiment, about 3 inches of KDF-55D having a maximum mesh size of 40 in
a straw having a 1/4 inch first passageway diameter has been found to be
sufficient for this purpose.
In operation, the straw 10 of FIG. 1 is shaken before use to loosen the
filter medium 24 and to insure maximum filtering capability. The second
end 16 of the tube 12 is placed in an aqueous solution (any solution
comprising water or water and at least one additive such as tea). The
aqueous solution is drawn into the straw by sucking on the first end 14 of
the tube 12 or the first end 28 of the mouthpiece 26. Preferably the
aqueous solution is allowed to sit in the first passageway 18 for about
one minute to activate the filtering medium 24. Preferably the aqueous
solution is only drawn into the second end 16 of the tube 12 each time.
Reference is now made to FIG. 6 which shows a second embodiment comprising
a drinking straw generally shown as 50 received in a transparent travel
case indicated 51. Case 51 comprises a thin-walled cylindrical tube having
a closed end 53 and a removable cover 54. The combination of the drinking
straw 50 and the case 52 is useful to keep the straw 50 clean when not in
use. For use, straw 50 is removed from case 52.
Straw 50 comprises an elongate tube 56 with three plugs 58 securely
received therein at spaced locations to retain, in between the plugs,
firstly, between plugs 58a and 58b, a carbon filter medium 60, and,
secondly, between plugs 58b and 58c, a second filter medium 62.
Filter medium 62 is preferably a KDF (trade mark) type medium as discussed
above. In the second embodiment, medium 62 is, however, preferably in the
form of fine metal strands formed into a batting. Such strands may be spun
or woven from the zinc and copper alloy. The strands preferably have a
small diameter in the range of that of strands used in steel wool. The
diameter of the strands is not critical. Preferred diameters are in the
range of 0.001 to 0.003 inch. Use of the filter medium 62 in the form of a
metal strand has the advantage of increasing the surface area of metal in
contact with the fluid yet decreasing the suction required to draw fluid
through the tube compared to granular material. Further, with the use of
the medium 62 as a strand, any tendency of the granular material to
develop channels, which reduces liquid contact with the granular material,
is avoided.
Filter medium 60 comprises granular, activated carbon to deodorize and
absorb impurities, especially organic matter including nitrates.
Preferably, the carbon is acid washed to remove acid soluable ash from the
carbon. One preferred carbon is sold by Barnebey Sutcliffe Corp. under the
trade name Activated Carbon Type SK and is preferably used in granular
size 20.times.50 US Screen ASTM D-2862.
Tube 56 is a thin-walled cylindrical tube of plastic material, preferably
ABS plastic, having a wall thickness in the range of about 0.10 to 0.010
inches, more preferably about 0.025 inches. ABS is strong and thus permits
a thin yet relatively rigid wall. Provision of a thin wall is useful so as
to maximize the diameter of the internal passageway 64 through the tube
yet keeping the outside diameter of the tube sufficiently small to
approximate that of a normal straw and permit use with sport and hospital
type water bottles and other containers having small openings for straws.
Providing the tube to be of a thin-walled material is advantageous to
maximize the passage size which reduces the suction pressure necessary to
efficiently draw water through the straw. The ABS should be food grade as,
for example, U.S. FDA approved.
ABS plastic also has the advantage of being electroplatable so the tube can
be provided with a thin, electroplated decorative metal layer over the
exterior of the tube.
Plugs 58 in the second embodiment comprise a micro filter through which
small particles cannot pass. The plugs are of an open-celled thermoplastic
material selected to have pore openings sufficiently small to physically
filter suspended particles. Preferably, the plugs comprise polyolefin
plastics such as polyethylene and polypropylene which are sintered so as
to provide an open cell pore structure preferably with a pore size in the
range of 50 to 200 microns.
The plugs 58 of the material are preferably made of a plastic selected so
as to have relatively low resiliency at normal room temperatures but
resilient and compressible at temperatures above room temperature. With
such plugs, the plugs may be compressed when at an elevated temperature,
for example, at about 100.degree. F. and then inserted into the tube and
released while still hot. The hot plugs expand outwardly into a forced-fit
relation in the tube. On cooling, the plug is effectively locked in place
in the tube. The plug should be carefully sized having a regard to the
extent to which they will expand and the strength and size of the tube.
Preferably, when a thin-walled ABS tube is used, the plug will be sized so
as to marginally expand the tube wall radially outwardly as shown at 66 in
FIGS. 7 and 8 and thus ensure the cooled plug is locked in place in the
tube. The plugs can thus provide a stable, relatively rigid filter secured
in place in the tube.
Plugs have been formed and inserted by a process of using a thin-walled
circular die to stamp a circular disc from a 1/8 inch thick sheet of the
plastic material while the material is hot. The die is formed so as to
compress the plug as the die stamps the plug from the sheet material. The
compressed circular plug is retained in a compressed state hot within the
die. The circular die has thin walls and its outer diameter is marginally
less than the inside diameter of the tube. The die with the heated plug
inside it is inserted into the tube to a desired distance from an end of
the tube and then a plunger is used to push the compressed, hot plug
axially out of the die whereby the hot plug expands into frictional
engagement with the tube at a desired location. Of course, alternatively,
plugs of desired thickness and size could be preformed, later heated and
then inserted into the tube in a compressed heated state.
The second embodiment filters out suspended particles via means of each of
the three plugs 58. Filter medium 62 filters out chlorine, lead, mercury,
aluminum, arsenic, cadmium, chromium, barium, hydrogen, sulphine and other
impurities such as algae, fungus, scale and sediment.
To filter out fluoride, the second embodiment may have bone ash or bone
meal added to the carbon filter medium. Alternately, to filter out
fluoride, a layer of AlO.sub.2 may be provided below the bottom plug 58c.
For example, a fourth plug may be provided and the AlO.sub.2 could be
disposed as a powder between the third and the fourth plug below the
filtered medium 62. Any AlO.sub.2 which may pass through the plug 58c
would be filtered out by the filter medium 62. Rather than provide a
fourth plug, a preferred method of incorporating granular material or
powder in the tube in small amounts is to incorporate the granular
material or powder into the bottom plug 58c at the time it is being
formed. Up to about 10% preferably 5% by volume of the plastic plug can
comprise a granular and/or powdered material which is ingrained within the
opened cell during its formation and is substantially trapped therein
against removal. Thus, a sprinkling of AlO.sub.2 powder may be provided in
the bottom plug 58c captured in the plug and thus serve the function of
additionally removing fluoride from any fluid.
The straw of the second embodiment is particularly adapted to filter out
chlorine and metals from treated water such as available from taps in
cities in North America. However, the straw is useful to treat almost any
water which contains chlorine, such as untreated water to which chlorine
tablets have been added for treatment.
While the invention has been described with reference to a preferred
embodiment, the invention is not so limited. Many modifications and
variations will now occur to persons skilled in the art. For definition of
the invention, reference is made to the appended claims.
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Description  |
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