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Claims  |
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What is claimed is:
1. A microwave plasma generating device, comprising:
a plasma chamber for generating plasma;
a reaction chamber having a specimen stage on which a specimen is treated
with the plasma;
gas supply means for supplying gas to the plasma generating chamber;
means for generating a microwave electric field in the plasma and reaction
chambers;
means comprising axially spaced apart and concentric electromagnet coils
for generating a magnetic field in the plasma and reaction chambers, the
microwave electric field and magnetic field having perpendicularly
crossing components of the magnetic field and electric field,
respectively, the magnetic field having a strength which decreases in an
axial direction from the plasma chamber towards the reaction chamber and
having constant strength magnetic flux density lines lying in planes which
are substantially parallel to each other and perpendicular to the axial
direction, the magnetic field producing a flat ECR condition wherein an
ECR layer extends perpendicular to the axial direction over at least 50%
of the width of the plasma chamber.
2. The microwave plasma generating device of claim 1, wherein the magnetic
field generating means comprises a plurality of axially spaced apart
electromagnets having coils concentric with each other, each of the
electromagnets having a substantially equal number of coil turns, the
electromagnets located closer to a center of the device having a larger
diameter than the electromagnets located further from the center of the
device.
3. The microwave plasma generating device of claim 1, wherein the magnetic
field generating means includes a first electromagnet extending completely
around an end of the plasma chamber located furthest from the reaction
chamber, a second electromagnet extending completely around the plasma
chamber and located between the first electromagnet and the specimen
stage, and a third electromagnet located such that the specimen stage is
between the third electromagnet and the plasma chamber.
4. The microwave plasma generating device of claim 2, wherein the magnetic
field generating means includes more than three electromagnets, the
diameters of the electromagnets becoming progressively smaller towards
opposite axial ends of the device.
5. The microwave plasma generating device of claim 3, wherein all of the
electromagnets are located outside of the plasma chamber and the reaction
chamber.
6. The microwave plasma generating device of claim 1, wherein the magnetic
field generating means includes a plurality of electromagnets having coils
concentric with each other and means for supplying each of the
electromagnets with an adjustable amount of current independent of the
other electromagnets.
7. The microwave plasma generating device of claim 1, wherein the magnetic
field generating means includes first and second electromagnets having the
same diameter, the first and second electromagnets having coils concentric
with each other and of identical gage wire, the first and second
electromagnets being spaced apart along the axial direction, the first
electromagnet having a higher number of coil turns than the second
electromagnet and the first electromagnet being further from the specimen
stage than the second electromagnet.
8. The microwave plasma generating device of claim 1, wherein the magnetic
field generating means includes first and second electromagnets having
coils concentric with each other having the same diameter, the first and
second electromagnets having coils of identical gage wire, the first and
second electromagnets being spaced apart along the axial direction, the
first and second electromagnets having the same number of coil turns, the
first electromagnet being further from the specimen stage than the second
electromagnet, the magnetic field generating means including a first
direct current power supply electrically connected to the first
electromagnet and a second direct current power supply electrically
connected to the second electromagnet, and the first power supply
supplying an amount of electrical current to the first electromagnet which
is greater than an amount of electrical current supplied by the second
power supply to the second electromagnet.
9. The microwave plasma generating device of claim 1, wherein the magnetic
field generating means includes first and second electromagnets having
coils concentric with each other and of identical gage wire, the first and
second electromagnets being spaced apart in the axial direction with the
first electromagnet being further from the specimen stage than the second
electromagnet, the first and second electromagnets having the same number
of coil turns, the magnetic field generating means including direct
current power supply electrically connected to the first and second
electromagnets, the power supply means supplying the first and second
electromagnets with the same amount of electrical current, and the second
electromagnet having a diameter which is greater than a diameter of the
first electromagnet.
10. A method of forming a flat ECR layer in a microwave plasma generating
device, the device including a plasma generating chamber into which gas is
introduced for generating plasma therein, a microwave introducing system
for supplying microwave energy into the plasma generating chamber, a
specimen chamber communicated with the plasma generating chamber, a
substrate holder in the specimen chamber for supporting a specimen to be
treated by plasma generated in the plasma generating chamber, and at least
first and second electromagnets, the first electromagnet being located
further from the substrate holder than the second electromagnet, the first
and second electromagnets being spaced apart in an axial direction, the
first electromagnet having coils which are concentric with coils of the
second electromagnet for generating a magnetic field in the plasma and
specimen chambers, the method comprising the steps of:
introducing gas into the plasma generating chamber;
introducing microwave energy into the plasma generating chamber and
generating plasma in the plasma generating chamber; and
supplying a first amount of direct current to the first electromagnet and
supplying a second amount of direct current to the second electromagnet so
as to form constant strength magnetic field flux density lines lying in
planes which are substantially parallel to each other and perpendicular to
the axial direction and a flat ECR layer in the plasma wherein the ECR
layer extends perpendicular to the axial direction over at least 50% of
the width of the plasma chamber.
11. The method of claim 10, wherein the first and second electromagnets are
supplied with different amounts of current.
12. The method of claim 10, wherein the first and second electromagnets are
supplied with the same amounts of current.
13. The method of claim 10, wherein the first and second electromagnets
have the same diameter, the first and second electromagnets have coils
concentric with each other and of identical gage wire, the first
electromagnet has a higher number of coil turns than the second
electromagnet and the same amount of current is supplied to the first and
second electromagnets.
14. The method of claim 10, wherein the first and second electromagnets
have the same diameter, the first and second electromagnets have coils
concentric with each other and of identical gage wire, the first
electromagnets have the same number of coil turns, and the amount of
electrical current supplied to the first electromagnet is greater than the
amount of electrical current supplied to the second electromagnet.
15. The method of claim 10, wherein the first and second electromagnets
have coils concentric with each other and of identical gage wire, the
first and second electromagnets have the same number of coil turns, the
second electromagnet has a diameter which is greater than a diameter of
the first electromagnet, and the first and second electromagnets are
supplied with the same amount of electrical current.
16. The method of claim 10, wherein the first and second electromagnets
have the same diameter, the first and second electromagnets have coils
concentric with each other and of identical gage wire, the first
electromagnet has a higher number of coil turns than the second
electromagnet and the amount of current supplied to the first
electromagnet is less than the amount of current supplied to the second
electromagnet.
17. The method of claim 10, wherein the first and second electromagnets
have the same diameter, the first and second electromagnets have coils
concentric with each other and of identical gage wire, the first
electromagnet has a higher number of coil turns than the second
electromagnet and the amount of current supplied to the first
electromagnet is greater than the amount of current supplied to the second
electromagnet.
18. The method of claim 10, wherein the first and second electromagnets
have coils concentric with each other and of identical gage wire, the
first and second electromagnets have the same number of coil turns, the
second electromagnet has a diameter which is greater than a diameter of
the first electromagnet, and the amount of current supplied to the first
electromagnet is less than the amount of current supplied to the second
electromagnet.
19. The method of claim 10, wherein the first and second electromagnets
have coils concentric with each other and of identical gage wire, the
first and second electromagnets have the same number of coil turns, and
the second electromagnet has a diameter which is greater than a diameter
of the first electromagnet, and the amount of current supplied to the
first electromagnet is greater than the amount of current supplied to the
second electromagnet.
20. The method of claim 10, wherein the flat ECR layer extends
perpendicularly with respect to the axial direction and covers at least
75% of the width of the plasma generating chamber.
21. The method of claim 10, wherein the flat ECR layer extends
perpendicularly with respect to the axial direction and covers at least
85% of the width of the plasma generating chamber. |
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Claims |
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Description |
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BACKGROUND OF INVENTION
1. Field of Invention
The present invention relates to the use of a microwave plasma processing
device in the etching and film growth processes. More particularly, the
invention is used in the process of manufacturing semiconductor devices.
The plasma is generated by microwaves with electron cyclotron resonance
("ECR") excitation.
2. Description of Related Art
Several advantages are realized by devices in which plasma is generated by
electron cyclotron resonance excitation. For example, a highly active
plasma can be generated at low gas pressures, ion energies can be selected
from a wide range of magnitudes, large ionic currents can be realized, and
excellent directionality and homogeneity of ionic currents can be
achieved.
FIG. 1 is a cross section of a conventional microwave plasma apparatus
which is used for etching and which operates on the principle of electron
cyclotron resonance excitation initiated by microwaves. FIG. 2 shows the
constant strength flux density lines exemplary of the magnetic field of
the conventional apparatus shown FIG. 1.
As shown in FIG. 1, plasma generating chamber 11 is comprised of
cylindrical outer wall 11b which has coolant circuit 11a, upper wall 11c
and lower wall 11d. Microwave feeding hole 12 is located at the center of
upper wall 11c. Microwave feeding hole 12 is sealed with microwave feeding
window 13 and is connected to a lower end of wave guide 14 at feeding
window 13. The upper part of wave guide 14 is connected with a microwave
generator (not shown). A generated microwave is introduced through wave
guide 14 and feeding window 13 into plasma generating chamber 11. Gas
feeding pipe 15 is connected with upper wall 11c. Electro-magnetic
exciting coil 18 is coaxially placed around both plasma generating chamber
11 and the lower end of wave guide 14.
At lower wall 11d of plasma generating chamber 11, there is plasma
extraction window 16. Located below plasma extraction window 16 is
reaction chamber 17 which is connected with plasma generating chamber 11.
Sample holder stage 19 for holding wafer S or some other sample, with an
electro-static chuck or other conventional means for holding the sample in
place, is positioned in reaction chamber 17 facing plasma extraction
window 16. Pumping hole 20 at the lower wall of reaction chamber 17, is
connected with an evacuation system (not shown).
The following describes the operation of an etching process with the
above-mentioned conventional microwave plasma apparatus. First, plasma
generating chamber 11 and reaction chamber 17 are evacuated. Following
evacuation, gas is fed into plasma generating chamber 11 through gas
feeding pipe 15. Electro-magnetic coil 18 creates a magnetic field within
the apparatus. After formation of the magnetic field, a microwave is
introduced into plasma generating chamber 11 through wave guide 14 and
microwave feeding window 13. Plasma is then formed as a result of the
resonance excitation initiated in the gas inside plasma generating chamber
11 which acts as a microwave resonant cavity. The plasma generated is
transported and brought into contact with sample surface S in reaction
chamber 17 by the force of the diverging magnetic field wherein the
magnetic flux density of the magnetic field is decreasing in a direction
toward reaction chamber 17 thereby ensuring that the surface of the sample
S is etched by the plasma.
Constant strength magnetic flux density lines 21 of the apparatus shown in
FIG. 1 are convex, as shown in FIG. 2, with respect to microwave feeding
window 13 in plasma generating chamber 11 and concave with respect to
sample S in reaction chamber 17. At the midpoint of a line drawn from
feeding window 13 to sample S, constant strength magnetic flux density
lines 21 approach complete flatness. The region along axis A where
constant strength magnetic flux density lines 21 are flat is small and the
gradient of the magnetic field is steep. With the resulting magnetic field
configuration, the ratio of the microwave power absorption efficiency to
the amount of plasma is low. Absorption is large at the center of the
device causing the plasma density distribution and the stability to be
poor.
The conventional apparatus shown in FIGS. 1 and 2 provides an 875 G region
which is thin in axial direction A since the device generates a non-flat
ECR condition. Constant strength magnetic flux density line 22 represents
the 875 G region. In this case, a very small area of the ECR layer is flat
with respect to a plane perpendicular to axial direction A. As mentioned
above, this provides high microwave absorption only at the center of
plasma generating chamber 11 with the result that plasma density
distribution and stability is poor. Hereafter, such an arrangement is
referred to as the "non-flat ECR condition."
U.S. Pat. No. 4,911,814 ("the '814 patent") discloses a thin film forming
apparatus and ion source utilizing sputtering with microwave plasma. In
particular, the '814 patent discloses a sputtering type ion source
utilizing ECR plasma. Several embodiments of the apparatus disclosed in
the '814 patent include two vertically spaced-apart electromagnets above
and below an entry hole in a side of a plasma chamber through which
microwave energy is introduced. The electromagnets are arranged such that
a magnetic field sufficient to cause ECR is produced and the magnetic flux
passes between two targets in the plasma generating chamber. The currents
passing through the electromagnets can be 20A each or the current passing
through the electromagnet closest to the reaction chamber can be 20A
whereas the current passing through the other electromagnet can be 10A.
The '814 patent does not disclose the shape of the ECR layer nor is there
any suggestion of supplying a lower amount of current to the electromagnet
located closest to the reaction chamber.
Other ECR type plasma treating apparatuses are disclosed in U.S. Pat. Nos.
4,401,054; 4,438,368; 4,806,829; 4,859,908; 4,947,085; 4,973,883; and
4,990,229.
There is a need in the art for a microwave plasma generating device which
provides a strong, uniform and stable plasma. Applicants have developed an
apparatus which produces an improved magnetic field distribution resulting
in enhanced microwave power efficiency in the plasma and improved
uniformity with respect to plasma density, absorption distribution
uniformity.
SUMMARY OF THE INVENTION
The invention provides a microwave plasma generating device which includes
a plasma chamber for generating plasma, a reaction chamber having a
specimen stage on which a specimen is treated with the plasma, gas supply
means for supplying gas to the plasma generating chamber, means for
generating a microwave electric field in the plasma and reaction chambers,
and means for generating a magnetic field in the plasma and reaction
chambers. The microwave electric field and magnetic field have
perpendicularly crossing components of the magnetic field and electric
field. The magnetic field also has a strength which decreases in an axial
direction from the plasma chamber towards the reaction chamber and has
constant strength magnetic flux density lines lying in planes which are
substantially parallel to each other and perpendicular to the axial
direction, the magnetic field producing a flat ECR condition. The
microwave generating means preferably supplies microwave energy at 2.45
GHz and the magnetic field has an 875 G region which is thick in the axial
direction compared to the 875 G region generated by a non-flat ECR
condition.
According to one aspect of the invention, the magnetic field generating
means can comprise a plurality of axially spaced apart electromagnets,
each of the electromagnets having a substantially equal number of coil
turns, the electromagnets located closer to a center of the device having
a larger diameter than the electromagnets located further from the center
of the device. The magnetic field generating means can include more than
three electromagnets, the diameters of the electromagnets becoming
progressively smaller towards opposite axial ends of the device.
According to another aspect of the invention, the magnetic field generating
means can include a first electromagnet around an axial end of the plasma
chamber located furthest from the reaction chamber, a second electromagnet
around the plasma chamber and located between the first electromagnet and
the specimen stage, and a third electromagnet located such that the
specimen stage is between the third electromagnet and the plasma chamber.
All of the electromagnets can be located outside of the plasma chamber and
the reaction chamber. However, one or more electromagnets could be
provided within the reaction chamber. Each of the electromagnets can be
supplied with an adjustable amount of current independent of the other
electromagnets. However, some or all of the electromagnets can be
connected in series to a common direct current source.
According to one feature of the invention, the magnetic field generating
means can include first and second electromagnets having the same
diameter, the first and second electromagnets having coils of identical
gage, the first and second electromagnets being spaced apart along the
axial direction, the first electromagnet having a higher number of coil
turns than the second electromagnet and the first electromagnet being
further from the specimen stage than the second electromagnet.
According to another feature of the invention, the magnetic field
generating means can include first and second electromagnets having the
same diameter, the first and second electromagnets having coils of
identical gage wire, the first and second electromagnets being spaced
apart along the axial direction, the first and second electromagnets
having the same number of coil turns, the first electromagnet being
further from the specimen stage than the second electromagnet, the
magnetic field generating means including a first direct current power
supply electrically connected to the first electromagnet and a second
direct current power supply electrically connected to the second
electromagnet, and the first power supply supplying an amount of
electrical current to the first electromagnet which is greater than an
amount of electrical current supplied by the second power supply to the
second electromagnet.
According to a still further feature of the invention, the magnetic field
generating means can include first and second electromagnets having coils
of identical gage wire, the first and second electromagnets being spaced
apart in the axial direction with the first electromagnet being further
from the specimen stage than the second electromagnet, the first and
second electromagnets having the same number of coil turns, the magnetic
field generating means including direct current power supply means
electrically connected to the first and second electromagnets, the power
supply means supplying the first and second electromagnets with the same
amount of electrical current, and the second electromagnet having a
diameter which is greater than a diameter of the first electromagnet.
The invention also provides a method of forming a flat ECR layer in a
microwave plasma generating device. The device includes a plasma
generating chamber into which gas is introduced for generating plasma
therein, a microwave introducing system for supplying microwave energy
into the plasma generating chamber, a specimen chamber communicated with
the plasma generating chamber, a substrate holder in the specimen chamber
for supporting a specimen to be treated by plasma generated in the plasma
generating chamber, and at least first and second electromagnets. The
first electromagnet is located further from the substrate holder than the
second electromagnet, the first and second electromagnets being spaced
apart in an axial direction. The method includes the steps of introducing
gas into the plasma generating chamber, introducing microwave energy into
the plasma generating chamber and generating plasma in the plasma
generating chamber, and supplying a first amount of direct current to the
first electromagnet and supplying a second amount of direct current to the
second electromagnet so as to form a flat ECR layer in the plasma. The
microwave energy can be introduced at 2.45 GHz so as to provide the ECR
resonance conditions with the magnetic field which has an 875 G region
which is thick in the axial direction compared to the 875 G region
generated by a non-flat ECR condition.
According to one aspect of the method, the first and second electromagnets
can be supplied with different amounts of current. Alternatively, the
first and second electromagnets can be supplied with the same amounts of
current. For instance, the first and second electromagnets can have the
same diameter, and have coils of identical gage wire, the first
electromagnet having a higher number of coil turns than the second
electromagnet, in which case the same amount of current is supplied to the
first and second electromagnets. In this case, however, the amount of
current supplied to the first electromagnet can be greater or less than
the amount of current supplied to the second electromagnet provided the
number of coil turns of the first electromagnet is sufficient to create
the flat ECR condition. Alternatively, the first and second
electromagnetics can have the same diameter and have coils of identical
gage wire, with the first and second electromagnetics having the same
number of coil turns, in which case the amount of electrical current
supplied to the first electromagnet is greater than the amount of
electrical current supplied to the second electromagnet. Another
possibility is where the first and second electromagnets have coils of
identical gage wire and have the same number of coil turns, with the
second electromagnet having a diameter which is greater than a diameter of
the first electromagnet, in which case the first and second electromagnets
are supplied with the same amount of electrical current. In this case,
however, the amount of current supplied to the first electromagnet can be
greater or less than the amount of current supplied to the second
electromagnet provided the diameter of the second electromagnet is
selected so as to create the flat ECR condition. In each case, a flat ECR
condition can be produced with the flat ECR layer extending over at least
50%, preferably at least 75% and even over 85% of the width of the plasma
chamber.
BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 shows a cross section of a conventional plasma generating device;
FIG. 2 shows the magnetic field strength lines within the FIG. 1
conventional apparatus;
FIG. 3 shows a cross section of a plasma generating device according to the
present invention;
FIG. 4 shows magnetic field strength lines within the FIG. 3 apparatus;
FIG. 5 shows magnetic field strength lines within a modified plasma
generating device according to the invention;
FIG. 6 shows another embodiment of an apparatus in accordance with the
invention;
FIG. 7a shows a conventional main coil electromagnet arrangement which
produces a non-flat ECR condition;
FIG. 7b shows a main coil electromagnet arrangement for producing a flat
ECR condition in accordance with the invention; and
FIGS. 8-14 show simulations of magnetic field amplitude lines in accordance
with the invention.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
Applicants have discovered several ways to overcome deficiencies of prior
art microwave plasma devices by providing a method and apparatus which
produces a flat ECR condition. In particular, the magnetic field
distribution can be changed by adjusting the ampere-turn number
distribution of the solenoid coils of the electromagnets, employing a
number of solenoid coils of different diameters and/or adjusting currents
of the electromagnets.
The above techniques can be used to make an expanded region where the
constant strength magnetic flux density lines are flat and parallel to
each other. As a result, the field strength of the constructed magnetic
field distribution can be changed without altering the distribution
pattern by changing the currents of every coil linearly, i.e. in the same
proportion. A magnetic field with a strength distribution generated
according to the aforementioned methods has parallel constant strength
magnetic flux density lines and small gradients of the magnetic field in
an axial direction (the direction in which the plasma moves from the
plasma generating chamber to the reaction chamber).
In accordance with the invention, an electron cyclotron resonance (ECR)
plasma generating device is provided in which a microwave of 2.45 GHz and
a magnetic field strength of 875 G can generate plasma perpendicular to
the microwave electric field such that the microwave power is uniformly
absorbed and a uniform density plasma can be generated. In particular, a
flat ECR condition is produced wherein the ECR layer extends perpendicular
to the axial direction over at least 50%, preferably 75% and more
preferably over 85% or more of the plasma generating chamber. Also, the
ECR plasma layer (located along the 875 G constant strength magnetic flux
density line) can be generated at any position between the inside of the
plasma chamber and the sample while maintaining the ECR generating
condition constant. As a result, the ion current density and the generated
plasma density, each of which are dependent on the plasma generating
distance, can be optimized around the sample. Optimization results in a
uniform and stable plasma generated across the sample surface.
FIG. 3 shows a cross section of a microwave plasma processing device
according to the present invention. The device includes plasma generating
chamber 1, wave guide 2, reaction chamber 3 with sample stage 7 for
holding sample S to be etched or provided with a film and three
electromagnets C1, C2 and C3. C1 is located around the upper part of
reaction chamber 1. C2 surrounds plasma chamber 1. C3 is located below
sample stage 7. Each coil is covered with iron to create a magnetic energy
saving magnetic circuit.
Plasma generating chamber 1 has double peripheral walls, which form hollow
chamber 1a furnished with cooling water and is configured in such a manner
that plasma generating chamber 1 can act as a cavity resonator for
microwaves. Microwave feeding hole 1c is located in the center of the
upper wall, and plasma extraction outlet 1d is located at the center of
the lower wall opposite microwave feeding hole 1c. Microwave window 1b
seals the lower end of wave guide 2 to microwave feeding hole 1c while
sample stage 7 in reaction chamber 3 is axially aligned so as to face
plasma extraction outlet 1d.
The upper end of wave guide 2 is connected to a microwave generator (not
shown) which generates microwaves to be introduced into plasma generating
chamber 1. Electromagnets C1, C2 and C3 are connected to respective direct
current sources 8a, 8b and 8c and form a magnetic field when a direct
current is passed through the coils of electromagnets C1, C2 and C3.
Plasma is generated as a result of introducing gas through line 1g and
introducing microwaves through window lb into plasma generating chamber 1
and energizing electromagnets C1, C2 and C3. The apparatus is maintained
at subatmospheric pressure by evacuation port 3a located beneath sample
holder 7 or at another location such as one side of reaction chamber 3.
FIG. 4 is representative of the magnetic field distribution which can be
produced in the apparatus of FIG. 3. In FIG. 4, however, electromagnet C2'
has a greater diameter than electromagnet C2 in FIG. 3 and electromagnet
C3' is located inside reaction chamber 3 whereas electromagnet C3 in FIG.
3 is located outside of reaction chamber 3.
The magnetic field strength distribution within the apparatus can be
adjusted by changing the ampere-turn number distribution of the coils of
electromagnets C1, C2 and C3. For example, the ratio of the ampere-turn
number from C1 to C2 to C3 can be 30:35:10. Lines 9 shown in FIG. 4
represent the constant strength magnetic flux density lines
(.vertline.B.vertline.=constant). The microwave electric field is assumed
to be horizontal. The magnetic field component perpendicular to the
electric field is Bz where Bz is in the Z-direction along axis A.
The magnetic field strength .vertline.B.vertline. and
.vertline.Bz.vertline. are substantially equal except in the region far
from the central axis. In this embodiment, the ion current density
obtained is 18 mA/cm.sup.2 with a uniformity of .+-.3% in a 200 mm
diameter area at the specimen position with a microwave power of 1 kW and
an argon gas pressure of 1 mTorr.
FIG. 5 shows the magnetic field arrangement with another preferred
embodiment of the present invention. Parts having the same function as
parts shown in FIG. 3 are identified with the same numerals. The coils D1
to D10 of this apparatus are in the form of a cocoon shape. Reaction
chamber 3 and the plasma chamber 1 are within the cocoon. Magnetic field
strength lines 9 are of equimagnetic field strength. With this embodiment,
a nearly flat magnetic field strength surface can be created with the same
currents and numbers of turns for each coil D1 to D10. The magnetic field
strength distribution can be varied by changing the magnitude of coil
current applied to coils D1 to D10 without affecting the shape of the
magnetic field distribution. For instance, the coils D1 to D10 can be
electrically connected in series and the ECR layer can be moved from the
position represented by line 10' to the line represented by line 10" by
increasing the amount of current applied to electromagnets D1 to D10.
In another embodiment, the energizing coils of the plasma generating device
are equal in diameter and arranged in a stack of two or more coils. For
instance, the stack could include six coils as shown in FIG. 6. A
decreasing current in a direction of movement of plasma generated in the
device can be achieved by reducing the number of turns of at least one
downstream coil. For instance, the ratio of turns in an upstream coil to a
downstream coil can be any amount such as 6:1, 3:2, 2:1.5, 2:1, etc. With
the arrangement shown in FIG. 6, the ratio of turns of coils
E1a:E1b:E1c:E1d:E1e:E1f can be selected such that one of the downstream
electromagnets located closer to reaction chamber 3 has a lower number of
coils than an upstream electromagnet further from reaction chamber 3.
Coil E2 can include a stack of sub-coils E2a, E2b and E2c. The diameter of
coil E2 can exceed the diameter of coils E1a to E1f. Likewise, coil E3 can
include a stack of sub-coils E3a, E3b and E3c having diameters
intermediate those of coil E1 and coil E2c.
As shown in FIG. 6, plasma formation chamber 1 is located below coil Elf.
In particular, rectangular or circular wave guide 2 is connected to larger
circular wave guide 2a by tapered adaptor 2b. Microwave introducing window
1b seals plasma formation chamber 1 from a lower end of larger wave guide
2a. Reaction zone 3 is not separated from plasma formation chamber by a
plasma aperture ring but rather, reaction zone 3 is within the same area
the plasma is formed. Sample loader 7a is located on one side of plasma
formation/reaction chamber 1,3 at a location immediately below coil E2.
Side evacuation port 3a' is located on another side of plasma
formation/reaction chamber 1,3 at a location below coil E2. Vertically
movable cylinder 7b is used to raise and lower substrate holder 7'.
FIG. 7a shows a conventional main coil arrangement for a plasma generating
device wherein the coils are connected in series, each coil has the same
number of turns and the same current, e.g., 20A, is passed therethrough.
FIG. 7b shows a main coil arrangement in accordance with the invention
wherein eight coils having the same number of turns of the same gage wire
are connected to separate power supplies such that the coils receive
different amounts of current, e.g., 30A, 30A, 20A, 20A, 13A, 13A, 5A, 5A,
respectively. Line 10 in FIG. 7a represents the non-flat ECR condition of
the prior art apparatus whereas line 10 in FIG. 7b shows the flat ECR
condition obtainable with the apparatus of the invention. In this case,
main coil F includes subcoils F1a, F1b, F1c, F1d, F1e, F1f, F1g and F1h
surrounding the plasma formation chamber.
FIGS. 8-14 show simulated magnetic field amplitude lines (.vertline.B
.vertline. lines) for cases where the magnetic field produced by each of
the electromagnets is adjusted in accordance with the invention. The
simulations apply to the apparatus shown in FIGS. 3, 4, 5, 6 and 7b. For
instance, in FIG. 8, the coil or coils in main coil E1, the coil or coils
in intermediate coil E2 and the coil or coils in lower coil E3 have the
same current and ratio of turns in all coils, i.e., 30A in each
electromagnet E1, E2 and E3. In this case, coil E2 has a larger diameter
than main coil E1 and the magnetic field produced by coil E2 is effective
in producing a flat ECR condition, as shown in FIG. 8. FIG. 9 shows
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