A method of preventing polymer scale deposition in a polymerization vessel in polymerization of a particular monomer having an ethylenic double bond having a high dissolving power against the conventional scale preventive coatings, wherein said polymerization is carried out in a polymerization vessel of which the inner wall has been previously coated with a first coating liquid comprising: (A) a water-soluble anionic dye, and (B) a metal salt, to form a first coating, and the first coating thus formed has been then coated with a second coating liquid comprising: (C) an alkaline earth metal compound, and at least one member selected from the group consisting of: (D) a water-soluble anionic dye and (E) an inorganic colloid, to form a second coating. Polymer scale deposition can be effectively prevented.
A non-toxic chemical composition inhibits corrosion in metal substrates. The composition contains a Phosphorus compound, comprising an acid and a metal selected from the group consisting of an alkali, alkaline earth, or transition metal. The composition also contains a Boron compound comprising an acid and a metal selected from the group consisting of an alkali, alkaline earth, or transition metal. A process of making the chemical composition comprises the steps of filling a mixer with 30-60% by weight of hot water and adding 10-20% by weight of barium carbonate or strontium carbonate, 10-20% by weight of phosphoric acid (75%), 5-15% by weight of lime, and 10-20% by weight of Boric acid; mixing the said contents for 10-15 minutes to create a wet slurry; pouring said wet slurry into an attrition mill for 15-60 minutes; drying said wet slurry and milling said wet slurry to an average particle size of 1.0-2.0 microns to form a dry pigment; pushing said dry pigment through a 325 mesh sieve.
A polymer scale preventive agent for use in the polymerization of a monomer containing an ethylenic double bond is provided. The agent includes (A) a condensation reaction product obtained by reacting an aldehyde compound and a hydroxynaphthalene-based compound in the presence of a reducing agent, and (B) a polymer compound containing a nitrogen atom. This agent is capable of forming a coating with satisfactory scale prevention properties on inner wall surfaces of a polymerization vessel with a single-stage application, enabling the production process time to be shortened and the productivity and quality of polymeric products improved.
Provided is a polymer scale deposition-preventive agent. It includes (A) a condensation reaction product of an aldehyde compound and a hydroxynaphthalene compound and (B) a soluble methoxyl group-substituted cellulose ether. The agent is formed into a film having an adequate polymer scale deposition-preventive property in a single-step application. The time for the application process is shortened to improve productivity. Polymer scales can be prevented from adhering to the inner wall surfaces of the polymerization vessel even if a plenty number of batches for polymerization are repeated.
Method for inhibiting scale deposits in an aqueous system. The method may include at least one of adding and forming anti-scalant in the aqueous system such that an amount of anti-scalant in the aqueous system is up to about 1000 ppm, wherein the anti-scalant comprises at least one of polyvalent metal silicate and polyvalent metal carbonate, wherein the aqueous system has a pH of at least about 9, and wherein a mean particle size of the anti-scalant is less than about 3 microns. The method may also include at least one of adding and forming anti-scalant in the aqueous system such that an amount of anti-scalant in the aqueous system is up to about 1000 ppm, wherein the anti-scalant comprises at least one of polyvalent metal silicate and polyvalent metal carbonate, and wherein the aqueous system has a pH of at least about 9; and adding dispersant to the aqueous system. The method may involve forming anti-scalant in the aqueous system such that an amount of anti-scalant in the aqueous system is up to about 1000 ppm, wherein the anti-scalant comprises at least one of polyvalent metal silicate and polyvalent metal carbonate, and wherein a mean particle size of the anti-scalant is less than about 3 microns. The method may further include at least one of adding and forming anti-scalant in the aqueous system, wherein the anti-scalant comprises at least one of polyvalent metal silicate and polyvalent metal carbonate; and adding at least one protein to the aqueous system. Compositions therefor.
Method for inhibiting scale deposits in an aqueous system. The method may include adding anti-scalant to the aqueous system such that an amount of anti-scalant in the aqueous system is up to about 500 ppm, wherein the anti-scalant comprises at least one of polyvalent metal silicate and polyvalent metal carbonate, and wherein the aqueous system has a pH of at least about 9. The method may include adding anti-scalant to the aqueous system such that an amount of anti-scalant in the aqueous system is up to about 500 ppm, wherein the anti-scalant comprises at least one of polyvalent metal silicate and polyvalent metal carbonate, in the presence of up to about 0.4 ppm of cationic polymer. The method may include adding anti-scalant to the aqueous system at at least one of before a pulping digester and at a pulping digester, such that an amount of anti-scalant in the aqueous system is up to about 500 ppm, wherein the anti-scalant comprises at least one of polyvalent metal silicate and polyvalent metal carbonate. The method may involve adding a nucleation promoter/initiator to the aqueous system to inhibit formation of scale deposits, such that an amount of the nucleation promoter/initiator in the aqueous system is up to about 500 ppm. The method may involve adding first cations to the aqueous system and removing second cations which are distinct from the first cations from the aqueous system, to inhibit the second cations from forming scale deposits, wherein the aqueous system is at a temperature of about 70.degree. C. to 500.degree. C. Inorganic compositions therefor.