A used lubricating oil comprising lube oil additives, including zinc dithiophosphate is subjected to reclaiming. Zinc dithiophosphate is thermally decomposed at a temperature of 400.degree. F. (204.degree. C.) to 1000.degree. F. (538.degree. C.) for a residence time of 10 to 120 minutes. The resulting oil is subjected to vacuum distillation. A zinc-free (i.e. ash free by ASTM D-482) distillate oil is useful as marine diesel fuel. About 5 to 25 vol % is recovered as a metal containing bottoms product, useful as asphalt extender. The process is carried out in the absence of chemical demetallizing.
Disclosed is an apparatus and a process for reclaiming fuel oil from waste oil. The apparatus comprises a thermal cracking unit for cracking the high boiling hydrocarbon material into lighter, lower boiling, material so as to separate hydrocarbon vapor products from viscous materials; a condenser/heat exchanger for condensing the hydrocarbon vapor products to the liquid state; a fuel stabilization unit for chemically treating the condensates so as to give a oil product and solid sediment; and a polishing unit for forming a high quality fuel oil by physically removing solid contaminants. According to the present invention, high quality fuel oil can be obtained together with an environmentally innocuous solid ash cake, through a simple and efficient process.
The Corona Inception Voltage of insulating oils is increased by repetitive cycles of prestressing the oil with a voltage greater than the corona inception voltage, and either simultaneously or serially removing byproducts of corona by evacuation and heating the oil.
The present invention relates to Performance Grade asphalt and a method for producing the same. The process includes adding a performance grade modifier and aggregates to an asphalt cement. The performance grade modifier reduces the high temperature limit and the low temperature limit of the performance grade asphalt in a ratio of about 1:1. A vacuum distilled component of recycled used lubricating oil is used as the performance grade modifier. The recycled used lubricating oil is added to the base oil and aggregate in sufficient quantities to achieve the selected operating temperature range.
A method of reclaiming used motor oil for further use is disclosed comprising (a) admixing used impurity laden motor oil with an effective amount of acetone as a flocculating agent and an effective amount of a second ketone as a wetting agent thereby forming an oil impurity flocculent mixture; (b) subjecting said mixture to a force such that a heavy phase and a light phase are formed, wherein said light phase is comprised of lean motor oil, acetone, and a second ketone, and wherein said heavy phase is comprised of flocculated impurities, any remaining acetone, and any remaining second ketone; and (c) separating said light phase containing said lean motor oil from said heavy phase containing said flocculated impurities. Preferably the second ketone is diisopropyl ketone, though other second ketones are also functional.
Waste lubricating oil, vegetable oil and animal fat are reprocessed into commercially usable diesel fuel and naphtha by thermocracking. A thermocracker unit is fired with sludge removed from the principal pool of oil or fat undergoing vaporization. The vapors are separated from liquids in a primary distillation tower with precisely controlled heating. Resultant vapors are partially condensed. Resultant liquids flow downward through a secondary distillation tower into a reboiler which is heated by a flue gas bypass with an auxiliary burner. Vapors leaving the secondary distillation tower are partially condensed and resultant fluids are passed to a light ends flash tank. Gases from the flash tank fuel the auxiliary burner. Liquids are collected and stored for selling as naphtha. Hot liquids are withdrawn from the reboiler and are immediately cooled to atmospheric conditions. Liquids within specification are stored in a diesel storage tank for further use and sale. Off-specification products are stored in a reflux storage tank and are pumped and heated and sprayed downward in the primary distillation tower for washing the tower and for reprocessing in the thermocracking unit. Some light ends are mixed with sludge in a storage tank. The mixture is pumped as sludge fuel to the burner in a fire tube in the thermocracking unit.