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Process for reducing cure time in cycloaliphatic amine based epoxy resins
   
Document Number
US Patent 5414067
Issued Date
May 9, 1995
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Inventors
Vratsanos; Menas S. (Breinigsville, PA)
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Abstract
This invention relates to an improved method for curing polyepoxide resins at elevated temperature and particularly to a method for reducing the time required to effect cure of thermosetting resins at elevated temperature without sacrificing performance. In the basic process, an epoxide resin comprising a polyglycidyl ether of a polyhydric phenol is mixed with cycloaliphatic amine, e.g., di(4-aminocyclohexyl)methane, di(4-amino-3-methylcyclohexyl)methane, and isophoronediamine in an amount sufficient to effect cure of the polyepoxide resin at an initial temperature and then raised to a final cure temperature. The improvement for reducing the time necessary for cure comprises: effecting an initial and partial cure of the epoxy resin at a temperature between 60.degree. and 100.degree. C.; increasing the temperature of the epoxy resin at a point when the ratio of the slope of the equilibrium modulus to the initial slope of the equilibrium modulus in megapascals plotted as a function of time in minutes for the curing epoxy resin as determined by the equation: ##EQU1## is greater than about 20:1 to a final cure temperature between about 160.degree. and 200.degree. C.; and, then maintaining a final cure temperature until the slope of said equilibrium modulus falls below about 0.1:1. Cure is deemed complete when the slope of the curve falls below 0.1:1.
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Process for reducing cure time in cycloaliphatic amine based epoxy resins - US Patent 5414067 Drawing
Drawing from US Patent 5414067
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Number of Claims:
15
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Published
May 9, 1995
Application Number
08/248,786
Filed
May 25, 1994
US Classification
528/120   525/504 528/122 528/407
Int'l Classification
C08G   59/18   (20060101)   C08G   59/00   (20060101)   C08G   59/50   (20060101)  
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USPTO Field of Search
528/120   528/122   528/504   528/407  
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