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High density plasma deposition and etching apparatus    

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United States Patent5429070   
Link to this pagehttp://www.wikipatents.com/5429070.html
Inventor(s)Campbell; Gregor A. (Glendale, CA); Conn; Robert W. (Los Angeles, CA); Katz; Dan (Beverly Hills, CA); Parker; N. William (Fairfield, CA); de Chambrier; Alexis (Glendale, CA)
AbstractPlasma deposition or etching apparatus is provided which comprises a plasma source located above and in axial relationship to a substrate process chamber. The plasma source may include a sapphire or alumina source tube for use with plasmas containing fluorine. Surrounding the plasma source are an inner magnetic coil and an outer magnetic coil arranged in the same plane perpendicular to the axis of the plasma source and the substrate process chamber. Preferably a first current is provided through the inner coil and a second current in a direction opposite to the direction of the first current is provided through the outer coil. The inner and outer coils are wrapped with a thin sheet of conducting material to shield the coils from RF signal generated by the plasma source. The result is to advantageously shape the magnetic field in the process chamber to achieve extremely uniform processing, particularly when a unique diamond shaped pattern of gas feed lines is used wherein the diamond is arranged to be approximately tangent at four places to the outer circumference of the workpiece being processed in the apparatus.
   














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Drawing from US Patent 5429070
High density plasma deposition and etching apparatus - US Patent 5429070 Drawing
High density plasma deposition and etching apparatus
Inventor     Campbell; Gregor A. (Glendale, CA); Conn; Robert W. (Los Angeles, CA); Katz; Dan (Beverly Hills, CA); Parker; N. William (Fairfield, CA); de Chambrier; Alexis (Glendale, CA)
Owner/Assignee     Plasma & Materials Technologies, Inc. (Chatsworth, CA)
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Publication Date     July 4, 1995
Application Number     07/979,574
PAIR File History     Application Data   Transaction History
Image File Wrapper   Patent Term   Fees
Litigation
Filing Date     November 20, 1992
US Classification     118/723R 118/719 118/723AN 118/723MP 156/345.49 204/298.37 204/298.38
Int'l Classification     C23C 016/50 H01L 021/00
Examiner     Breneman; R. Bruce
Assistant Examiner     Baskin; Jonathan D.
Attorney/Law Firm     Friel, MacPherson; Alan H. Skjerven, Morrill, MacPherson, Franklin & Millers; David T. ,
Address
Parent Case     CROSS-REFERENCE TO RELATED APPLICATION This application is a continuation-in-part of U.S. patent application Ser. No. 07/964,149 filed Oct. 19, 1992 which is a continuation-in-part of U.S. patent application Ser. No. 07/887,278 filed May 21, 1992, now abandoned, which is a continuation of U.S. patent application No. 07/650,788 filed Feb. 4, 1991 and issued Jun. 16, 1992 as U.S. Pat. No. 5,122,251, which is a continuation-in-part of U.S. patent application Ser. No. 07/365,533, filed Jun. 13, 1989 and issued Feb. 5, 1991 as U.S. Pat. No. 4,990,229, all of which are hereby incorporated by reference.
Priority Data    
USPTO Field of Search     118/723 MP 118/723 MW 118/723 ME 118/723 MR 118/723 MA 118/723 AN 118/723 E 118/723 ER 118/723 IR 118/723 R 156/345 204/298.37 204/298.38
Patent Tags     high density plasma deposition etching
   
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ReferenceRelevancyCommentsReferenceRelevancyComments
5122251
Campbell
204/298.06
Jun,1992

[0 after 0 votes]
5089441
Moslehi

Feb,1992

[0 after 0 votes]
4990229
Campbell
204/298.06
Feb,1991

[0 after 0 votes]
4963242
Sato
204/298.31
Oct,1990

[0 after 0 votes]
4433228
Nishimatsu
219/686
Feb,1984

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What is claimed is:

1. Structure for use in generating a high density plasma for use in the processing of a substrate, said structure comprising:

a plasma generation chamber;

an inner magnet and an outer magnet surrounding said plasma generation chamber, said inner magnet having a smaller diameter than the diameter of said outer magnet such that said outer magnet is located around said inner magnet and in the same plane as said inner magnet, thereby to produce a magnetic field for use with said plasma generation chamber; and

means for shielding each of said inner and outer magnets such that radio frequency energy is not absorbed by said inner and outer magnets.

2. Structure as in claim 1, wherein:

the substrate comprises polysilicon, metal or metal compound; and

the plasma generation chamber is made of quartz.

3. Structure as in claim 1, wherein:

the plasma comprises gases containing fluorine; and

the plasma generation chamber is made of alumina.

4. Structure as in claim 1, wherein:

the plasma comprises gases containing fluorine; and

the plasma generation chamber is made of sapphire.

5. Structure as in claim 1, further comprising a process chamber for holding a substrate to be operated upon by the plasma, wherein:

said plasma generation chamber is located above said process chamber such that said inner magnet and outer magnet are located around said plasma generation chamber above said process chamber; and

a surface of said substrate to be operated upon by the plasma is located between 100 and 200 millimeters from an upper surface of said process chamber.

6. Structure as in claim 5, further comprising a magnetic bucket surrounding the process chamber.

7. Structure as in claim 6, wherein the magnetic bucket includes between 18 and 28 magnets inclusive.

8. Structure as in claim 7, wherein the magnetic bucket includes 24 magnets.

9. Structure as in claim 1, wherein said means for shielding comprises a sheet of conductive material wrapped around each of said inner and outer magnets.

10. Structure as in claim 9, wherein said sheet of conductive material is aluminum tape.

11. Structure for use in generating a high density plasma for use in the processing of a substrate, said structure comprising:

a plasma generation chamber;

a magnet surrounding said plasma generation chamber, thereby to produce a magnetic field for use with said plasma generation chamber; and

means for shielding said magnet such that radio frequency energy is not absorbed by said magnet.

12. Structure as in claim 11, wherein said means for shielding comprises a sheet of conductive material wrapped around said magnet.

13. Structure as in claim 12, wherein said sheet of conductive material is aluminum tape.
 Description Submit all comments and votes
 


BACKGROUND OF THE INVENTION

1. Field of the Invention

The present invention relates to a plasma deposition or etching method and various apparatus for depositing a thin film onto a substrate or for removal (etching) of a film from a substrate. The present invention includes the use of a new and significantly better high density plasma deposition and etching apparatus, a significantly improved magnetic means for the plasma source region and operation with a specified range of processes and gases. Applications of the present invention include the removal by etching of a layer from a surface, the removal by sputtering of a layer from a surface, or the deposition of a layer onto a surface.

2. Related Art

Etching

Plasma etching involves using chemically active atoms or energetic ions to remove material from a substrate. It is a key technology in the fabrication of semiconductor integrated circuits. However, before the advent of microwave plasmas utilizing electron cyclotron resonance (ECR), it was becoming difficult for conventional plasma etching techniques to satisfy the requirements dictated by the increase in device packing density. Specifically, the requirement for fine pattern etching without undercutting (anisotropic etching) and the requirements for low damage and high selectivity could hardly be satisfied at the same time.

Deposition

Plasma Enhanced Chemical Vapor Deposition (PECVD) is a widely used technique to deposit materials on substrates in a host of applications. In normal Chemical Vapor Deposition (CVD) the chemical reaction is driven by the temperature of the substrate and for most reactions this temperature is high (>800.degree. C.). The high substrate temperature needed precludes use of this method in a number of applications particularly in microelectronics, displays and optical coatings. The role of the plasma is to dissociate and activate the chemical gas so that the substrate temperature can be reduced. The rate of dissociation, activation and ionization is proportional to the density of the plasma. It is therefore of importance to make the plasma as dense as possible.

Sputtering

Sputtering is also a widely used method for depositing materials onto substrates for a wide variety of applications such as the production of hard or decorative coatings and the coating of glass. In general, a plasma is produced at the sputter target material and the sputter target is biased to a negative voltage of around 700 V. Plasma ions (generally argon) impact the surface and sputter the material which then transports as neutral atoms to a substrate. Reactive gases can be introduced to chemically react with the sputtered atoms at the host substrate in a process called reactive sputter deposition. Rate is often important and it is therefore important to make the plasma as dense as possible. Ionization of reactive gases is also important and is helped by having plasma in the vicinity of the substrate material. Sputtering is also done by ions accelerated in an ion or plasma gun and then made to bombard the sputter target. In this case, a bias voltage on the target is not necessary. For sputtering insulating materials, RF voltage bias can be applied to the sputter target.

Existing Methods

There are presently two widely used methods for plasma deposition and etching, the parallel plate reactor and the ECR plasma deposition system. There are also methods based on the use of RF to produce plasma including ordinary induction techniques and techniques based on whistler waves.

Parallel Plate Reactor (Diode)

The RF diode has been widely used for both deposition and etching. It is described in detail in the book by Chapman ("Glow Discharge Processes" John Wiley & Sons 1980). It uses RF at 13.56 MHz capacitively coupled to one electrode while the other electrode is grounded. The pressure in the system is typically 1 mtorr to 1 torr and the plasma density is typically 10.sup.10 electrons per cm.sup.3. The rate at which both deposition or etching occurs is dependent on the density of the plasma and the density (pressure) of the reactive gas used to etch, or, in CVD processes, to deposit.

In etching, the high pressure needed to sustain the discharge causes collisions between the ions and the background gas. This causes the paths of the etching ions or atoms to be randomized or non-directional, leading to undercutting of the mask. This is referred to as an isotropic etch. It is desirable to have the etch atoms or ions be directional so that straight anisotropic etches can be achieved. At the high pressure used in RF diode discharges, it is necessary for the ions to have high energy (up to 1 KeV) to achieve an anisotropic etch. However, the high energy of the ions can cause damage to the substrate, film materials or photoresist.

The plasma is sustained by secondary electrons that are emitted by ions impacting the cathode. These electrons are accelerated by the voltage drop across the sheath which is typically 400-1000 V. These fast electrons can bombard the substrate causing it to have a high voltage sheath drop. This high voltage can accelerate the ions leading to damage of the substrate or film material. The presence of high energy electrons leading to high voltage sheath drops is undesirable.

Electron Cyclotron Resonance Plasmas

The advent of using microwaves at 2.45 GHz and a magnetic field of 875 Gauss to utilize electron cyclotron resonance allowed the generation of high density plasmas at low pressure. The advantages of this technique for plasma etching are described by Suzuki in U.S. Pat. No. 4,101,411 and in an article entitled "Microwave Plasma Etching" published in Vacuum, Vol. 34, No. 10/11, 1984. Due to a low gas pressure (0.04-0.4 Pa) and high plasma density (1.7-7.times.10.sup.11 electrons/cm.sup.3) anisotropic etch with high etch rates is achievable.

Suzuki, in U.S. Pat. No. 4,101,411, describes a plasma etching apparatus using ECR. Matsuo, in U.S. Pat. No. 4,401,054 describes a plasma deposition apparatus utilizing ECR. In U.S. Pat. No. 4,876,983 there is described a plasma etching apparatus to improve uniformity and have the specimen close to the source chamber.

While this technique is desirable over the parallel plate reactor in many respects, it has several limitations. The magnetic field needed is very high (1-2 kGauss) which means that heavy, power consuming electromagnets must be used. The maximum density is limited by either cut-off in certain configurations or by refraction in other configurations to the value of 1.times.10.sup.12 electrons/cm.sup.3 in the source. The expense of the power supply and necessary hardware to generate and transmit the microwaves is high. The uniformity (or width of the plasma profile) is not very good.

RF Helicon Whistler Wave Plasmas

The first use of helicon type whistler waves to generate dense plasmas was described in 1970 by Boswell in the journal, Physics Letters, Vol. 33A, pp 457-458 (1970) which showed an antenna configuration used by Ovchinnikov. This type of antenna excites an m=1 mode. The frequency of excitation was 8 MHz. The density profile of the 10 cm plasma was found to be quite peaked, particularly at the higher magnetic field strengths needed for high densities. In Boswell, U.S. Pat. No. 4,810,935, two mathematical relationships are required to be satisfied. These equations are in fact overly restrictive and not applicable to the approach outlined by Campbell, Conn and Shoji in U.S. Pat. Nos. 4,990,229 and 5,122,251.

In these publications the mechanism for efficient coupling of the RF energy to the plasma could not be explained. Chen, in an Australian National University report, explained the mechanism as Landau damping.

Chen, in a paper presented in August 1988 and published in the journal, Plasma Physics and Controlled Fusion, Vol. 33, 1991, describes a system using whistler waves to generate dense plasmas for use in advanced accelerators. The type of antenna used in this arrangement was similar to that used by Boswell in that it excited the m=1 mode and was a type known as the Nagoya Type III antenna. This type of antenna is explained in a paper by Watari (1978). The frequency of excitation was 30 MHz.

Campbell, Conn and Shoji, in U.S. Pat. No. 4,990,229 and Pat. No. 5,122,251 describe new and highly efficient antenna means designed to excite the m=0 and the m=1 modes, and to control the wave number of the excited wave. This is important in obtaining the maximum plasma density, in generating the broadest spatial plasma density profile in the source and process chamber regions, and in providing control over the electron temperature in the plasma.

Efficiency of plasma production by low frequency whistler waves depends on the coupling of RF energy into the plasma. As discussed by Campbell et al. in U.S. Pat. No. 4,990,229, an important mechanism for damping of the RF energy is Landau damping. The phase velocity of the whistler wave is given by .omega./k.sub.z, where k.sub.z is given by the dispersion relation and depends on the plasma density and vacuum magnetic field strength. Ideally, the phase velocity of the wave should be near the maximum of the ionization potential of the gas we wish to ionize. From the dispersion relation for the m=0 mode, the higher the value of k.sub.z, the higher the density. However, the phase velocity of the wave is .omega./k.sub.z and so increasing k.sub.z decreases the energy of the electrons that are accelerated by the wave. If the k.sub.z is too high then the energy of the electrons may fall below the ionization potential.

Also, Campbell, Conn and Shoji in the above-mentioned patents use a magnetic bucket means in conjunction with the plasma generator to provide a uniform plasma density over large circular or rectangular areas. They use one or multiple plasma generators in conjunction with cylindrical or rectangular magnetic buckets to provide a uniform density over a large area for the coating or etching of substrates such as are needed for IC or flat panel display processing. They use expansion of the magnetic field to allow deposition or etching over a large area.

Other RF Induction Sources

Other existing methods use RF circuit resonances to generate plasma. These methods are less efficient than those using low frequency whistler waves, and do not generate high density plasmas. Ogle, in U.S. Pat. No. 4,948,458 describes an RF means to produce planar plasma in a low pressure process gas using an external planar spiral coil (or series of concentric rings) and connected to a second loop which is positioned to allow for effective coupling of the circuit and for loading of the circuit at the frequency of operation. Steinberg et al., in U.S. Pat. No. 4,368,092, describes a plasma generating system employing a helical inductive resonator for producing the plasma external to an etching chamber. The plasma is non-uniform and passes through a tube before utilization. U.S. Pat. No. 4,421,898, describes an inductively-coupled plasma generating apparatus, where a transformer having a magnetic core induces electron circulation in an insulating tube carrying a process gas. Gas ionization is non-uniform, and exposure to the wafer occurs downstream. U.S. Pat. No. 4,626,312, describes a conventional parallel plate plasma etcher where the wafer is situated on a lower electrode and a plasma is generated by applying radiofrequency energy across the lower electrode and a parallel upper electrode. U.S. Pat. Nos. 4,668,338 and 4,668,365, describe magnetically-enhanced plasma processes for reactive ion etching and chemical vapor deposition, respectively. Flamm et al. in U.S. Pat. No. 4,918,031 describes an L-C circuit referred to as a helical resonator which consists of an inner helically shaped copper coil surrounding a quartz tube and attached at one end to a cylindrical copper shield. The opposite end of the inner coil is unterminated. No external magnetic field is employed in these approaches and all generate plasmas at low pressure in the 1-10 mtorr range but at moderate density in the quartz source tube or just below a planar spiral coil and without a high degree of spatial uniformity. No externally generated magnetic field is employed in these RF plasma generators.

SUMMARY OF THE INVENTION

The present invention utilizes low frequency RF whistler waves to generate plasmas of high density for use in plasma etching, deposition, and sputtering equipment. Plasma is generated in a source tube which is typically made of quartz or a fluorine-resistant material such as alumina or sapphire. In conjunction with the source tube into which a gas is injected and along the central axis of which a magnetic field is established, a single loop antenna is disposed in a plane transverse to the central axis. The angle of the antenna plane is 90.degree. if it is desired to excite only M=0 mode, or at less than 90.degree. if it is desired to excite components in both M=0 and M=1 mode. The gas is a noble or reactive gas at a pressure of 0.1 mtorr to 200 mtorr. The magnetic field strength is in the range of 10 to 1000 gauss and the antenna is driven with RF energy of 100 W to 5 KW at a frequency range of 2 MHz to 50 MHz. With the antenna placed along the tube source at a sufficient distance along the axis from the gas injection end, the other end defining an open egress zone leading to a process chamber, the single loop antenna surprisingly provides highly efficient wave coupling to establish a high density and high current plasma.

In accordance with other features of the invention, the plasma generated by this plasma source is supplied to a process chamber including a magnetic bucket system for holding the plasma away from the process chamber walls. The arrangement provides, in combination, a uniform plasma density over a large circular area, so that a large substrate may be etched or otherwise processed. Another feature is that a magnetic cusp zone may be established, at the material surface being processed, to homogenize and make more uniform the plasma at that location. An aspect of this is that the magnetic cusp position relative to the substrate may be time modulated to enhance uniformity and reduce sensitivity to substrate location.

Further, the magnetic field may be expanded to allow deposition or etching over a large area and current flows may be equalized by serial driving of antennas in systems having more than one antenna. Other features reside in configurations which employ one or more multiple geometrical areas for coating or etching of square or rectangular substrates, or a linear juxtaposition for coating or etching large substrates.

The invention provides a module with a highly efficient magnetic means of transporting plasma from a plasma generator means to a substrate located on a cooled substrate holder located in a substrate process chamber and in which the processing of the substrate is highly uniform and the substrate process module is compact. The invention shields the magnet means from RF signals generated by the antenna and thereby prevents false signals from being received by a control system which drives the magnet means. The shielding may be a thin sheet of conducting material wrapped around the magnet means.

The invention provides a gas distribution means in the top of the process chamber as an integral part of the process chamber structure in order to attain highly efficient plasma operation and highly uniform processing of the substrate while permitting the process module to be reduced in height.

The invention attains highly efficient plasma operation in a compact substrate process module which can attain excellent characteristics for the etching of IC wafers as represented by high etch rate, high uniformity, high selectivity, high anisotropy, and low damage.

The invention achieves high density and highly uniform plasma operation at low pressure from 0.3 mtorr to 5 mtorr for etching an IC substrate and from 1 mtorr to 30 mtorr for deposition of films on to substrates.

The invention provides a substrate processing system capable of operating with a wide variety of gases and combinations of gases, including highly reactive and corrosive gases.

The invention provides such a substrate processing system capable of etching or depositing films listed in Table 1 and Table 2 using gases fed into the plasma generator region, into the process chamber region, or into both regions.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a schematic diagram depicting the principle of operation and RF current flow in an antenna constructed according to the invention as shown in U.S. Pat. No. 4,990,229.

FIGS. 2A, 2B and 2C are schematic views of antennas constructed according to the principles of the invention.

FIG. 3 is a schematic diagram depicting the principle of operation and RF current flow in a plasma source constructed according to the invention as shown in U.S. Pat. No. 5,122,251.

FIGS. 4A and 4B illustrate in schematic form two basic configurations of a plasma deposition or etching apparatus accordance with this invention.

FIG. 5A is a schematic diagram of a second example of a system in accordance with the present invention in which the plasma source region is connected to a magnetic bucket region where uniformity requirements are important.

FIG. 5B is a plan view of the arrangement of FIG. 5A, taken along the line 3A--3A in FIG. 5A.

FIG. 6A is a perspective view of a third example of a system in the present invention for deposition or etching over a large rectangular area where uniformity is important.

FIG. 6B is a plan view of the arrangement of FIG. 6A, taken along the line 4A--4A in FIG. 6A.

FIG. 7A is a schematic diagram of yet another example of a system in accordance with the present invention in which a bottom magnet is added behind the plane of the substrate holder to provide a magnetic cusp field, the plane of the cusp being approximately the same as the plane of the substrate holder.

FIG. 7B is a plan view of the arrangement of FIG. 7A, taken along the line 5A--5A in FIG. 7A.

FIG. 8 is a schematic diagram of an example of a system in accordance with the invention for sputter deposition.

FIG. 9 is a graph depicting the plasma current density at the substrate location according to the example of FIG. 5A using the plasma source depicted in FIG. 3 as a function of magnetic field in the source region.

FIG. 10 is a graph of the same data as in FIG. 9 but graphed on a linear scale for magnetic field to show the plasma current density at the substrate location where the magnetic field is low, varying from zero to 160 gauss.

FIG. 11 is a graph depicting the total plasma current (or total flux) at the substrate location according to the invention as depicted in FIG. 5A using the plasma source as depicted in FIG. 3 as a function of RF power to the source at a gas pressure of 2 mtorr.

FIG. 12 is a graph depicting the plasma current density at the substrate location according to the invention as depicted in FIG. 5A using the antenna as depicted in FIG. 3 as a function of the gas pressure.

FIG. 13 is a graph depicting the plasma current density at the substrate location according to the invention as depicted in FIG. 5A and the plasma source of FIG. 3 as a function of position to show the excellent uniformity over a substantial width.

FIGS. 14A to 14C are diagrams showing the arrangement of the electromagnetic system in the plasma generator region according to the present invention to make efficient the transport of plasma from the plasma generator tube to the substrate process chamber which includes a magnetic bucket and where uniformity and high plasma flux to the substrate are required.

FIG. 15A is a plot of the magnetic field lines obtained using one electromagnet surrounding the plasma source tube.

FIG. 15B is a plot of the magnetic field lines obtained using two electromagnets surrounding the source tube and where the outer magnet coil carries a current in the opposite direction from the inner magnet coil and has a coil current that is 40% as large in magnitude as that of the inner coil.

FIG. 16A is a schematic diagram of the configuration of a plasma etching or deposition apparatus.

FIG. 16B is a plan view of the substrate process chamber section of the arrangement of FIG. 16A taken along the line 7A--7A in FIG. 16A.

FIG. 17A is a plan view of the substrate process chamber showing the gas feed lines, the nozzle holes for gas injection into the chamber, the water cooling lines and the grooves for the ceramic permanent magnets.

FIG. 17B is a detail showing the entrance to the gas feed line at the top of the substrate process chamber shown in FIG. 17A.

FIG. 17C shows in larger size the gas feed structure of FIG. 17A.

FIG. 18 is a cross sectional SEM image obtained for the etching of poly-Si in pure Cl.sub.2 using the MORI plasma source etching system. In this case, the SEM shows structure with 100% overetch. One sees highly anisotropic profiles, no notching, and less than 50 .ANG. oxide loss.

FIG. 19 shows the aluminum etch rate, the oxide etch rate, and the PR etch rate (left ordinate) and selectivity to photoresist etching and to oxide etching (right ordinate) as a function of RF wafer bias power applied at 13.56 MHz. The gas mixture is 85% Cl.sub.2 -15% BCl.sub.3, the MORI source power is 1 KW, and the substrate is located in the process chamber 20 cm below the end of the source tube.

FIG. 20 is a cross sectional SEM image obtained for sub micron etching of W on a TiW adhesion layer on thermal oxide in pure SF.sub.6 using the MORI plasma source etching system. The anisotropy is excellent, there is no CD loss, and there are no residues.

DETAILED DESCRIPTION OF THE INVENTION

FIGS. 1A, 2B, and 2C illustrate schematically the RF current flow in two antennas constructed according to the invention disclosed in U.S. Pat. No. 4,990,229 issued Feb. 5, 1991. For a more detailed description of the operation of these antennas, U.S. Pat. No. 4,990,229 is incorporated herein by reference in its entirety.

A simplified view of principal elements and relationships in a device in accordance with the invention is provided by the representation of FIG. 3, wherein high density plasma 9 is to be generated within a source tube 10 of generally cylindrical form about a central (here vertical) axis. At one (here upper) end an injector 11 feeds gas to be ionized into the interior volume of the source tube, where the gas is excited by an external loop antenna 12 that encompasses an intermediate region of the source tube 10. The antenna loop 12 comprises in this example a not fully circular element lying in a plane that is at 90.degree. or less in either sense relative to the central axis. The direction of propagation of the plasma is here downward toward an exit aperture 13. The antenna loop 12 has its opposite ends coupled to the outer conductor 14 and center conductor 15 of a coaxial driver line 16 which is energized through a matching box 18 by an RF energy source 19. A pair of variable vacuum capacitors 20, 21 in the matching box 18 are adjustable to tune the circuit so that the antenna loading plus the reactive load of the matching box 18 is approximately 50 ohms to minimize the reflected power.

The antenna tuning and wave spectrum are adjusted to match the conditions in the plasma field, and also in relation to an interior axial magnetic field 8 generated by at least one magnetic field coil (not shown) about the source tube 10. The matching condition is predicted by theory to be dictated by the dispersion relation:

[.omega./.omega..sub.c -.omega..sub.p.sup.2 /C.sup.2 K.sub.z.sup.2 ].sup.2 =1+(3.83/k.sub.z a).sup.2

To effect wave coupling and establish a high plasma current density, measured in mA/cm.sup.2, the antenna loop 12 is driven at 13.56 MHz and with RF energy of the order of 2.0 KW (in the range of 100 W to 5 KW) by the RF energy source 19. The magnetic field established by the magnetic field coil is in the range of 10 to 1000 gauss, for different useful applications. The gas is argon and maintained at a pressure of about 1 mtorr in this example. However, in addition to a noble gas such as argon, reactive gases such as SF.sub.6, chlorine, oxygen, and mixtures with oxygen have been used with comparably useful results. A pressure range of 0.1 mtorr to 200 mtorr can be used if other variables are properly taken into account. With a 5 KW power supply less than the maximum available power can be used, to a substantially lower level of several hundred watts, depending on the application. Although the 13.56 MHz frequency is available from many industrial sources, the range of 2 MHz to 50 MHz can be usefully employed.

In FIG. 3, the antenna loop 12 is shown at 90.degree. to the longitudinal axis of the source tube 10. This orientation generates the M=0 mode, while reducing the angle from 90.degree. in either sense introduces components of the M=1 mode as well as components of the M=0 mode. Angles of less than 90.degree. to the longitudinal axis require correspondingly longer antenna loops 12, so there is a practical limit of about 45.degree. to the angle which can be used. Most orientations are preferred to be in the range of 60.degree. to 90.degree.. It should be noted that the loop 12 is disposed within a flat plane that is directly perpendicular or tilted to the longitudinal axis. In the prior art constructions with double loops and other configurations it has usually been postulated that the looped portions must describe a helical path in order to establish a helical wave property, but this is disproven by the results given below as to the efficacy of the present invention. It is important, however, that the antenna loop 12 be sufficiently spaced apart from the closed (gas entry) end of the source tube 10 for the necessary interactions to occur between the plasma and the RF energy, and for the dispersion relation to be satisfied so that proper excitation can be realized and high density can be achieved. Too long a length, however, can also preclude establishment of the proper wave numbers. In practice source tubes 10 of 1" to 4" in diameter and 8" to 9" in length have been used, with the antenna loop being about one-third or more of the distance from the closed end.

This arrangement establishes low frequency whistler waves, but the mechanism of the wave energy-plasma interaction is not fully understood. Simple analysis in accordance with the dispersion relation is not feasible. The presence of the plasma load in the RF field appears to give rise under proper conditions to selective interactions in which the gas density and dielectric characteristics determine the wave numbers that exist. In a sense, therefore, the plasma itself appears to predetermine the wavelengths for interaction, and thus the value of k.sub.z, out of the spectrum of radiation from the antenna that excites the plasma.

The physics of whistler wave propagation in plasmas has been studied in other contexts. In a cylindrical geometry, these waves are generally referred to as helicon waves. The classical helicon wave was first investigated by Lehame and Thonemann and is governed by the following equations:

.gradient..times.E=.delta.B/.delta.t, .gradient..times.B=.mu..sub.o i, .gradient.. B=0E=i.times.B.sub.o /en.sub.o, E.sub.z =.eta.J.sub.z

where E is the electric field, B is the magnetic field, i is the current density, B.sub.o is the vacuum magnetic field, e is the charge on an electron, n.sub.o is the density of the plasma and .eta. is the resistivity of the plasma.

Following the derivation of Chen one can easily find perturbations of the form B exp(i(m.theta.+k.sub.z Z-.omega.t)), and in the limit as .eta. tends to 0, the above equations lead to:

.gradient..sup.2 B+.alpha..sup.2 B=0 where .alpha.=(.omega./k) (.mu..sub.o en.sub.o /B)

where i=(.alpha./.mu..sub.o) B

and .omega. is the angular frequency of the wave, .mu..sub.o is the permittivity, k is the wave number, 2.pi./.lambda., where .lambda. is the wavelength. These equations can be solved in cylindrical coordinates to yield the dispersion relation:

m.alpha.J.sub.m (T a)+TkaJ.sub.m ' (T a)=0

where, J.sub.m is a Bessel function of the first kind, J.sub.m ' is a derivative of J.sub.m with respect to its argument, a is the plasma radius and T is a transverse wave number defined by

T.sup.2 =.alpha..sup.2 -k.sup.2

It is important to remember that m is the mode number that describes the .theta. dependence of perturbations of the form B exp(i(m.theta.+k.sub.z -.omega.)).

The two lowest modes satisfy

J.sub.1 (T a)=0 (m=0)

J.sub.1 (T a)=T k a/2 .alpha.(J.sub.2 -J.sub.0) (m=1)

This leads to the simple relation

[(.omega./.omega..sub.c)-(.omega..sub.p.sup.2 /C.sup.2 k.sub.z.sup.2)].sup.2 =1+(3.83/k.sub.z a).sup.2

where

.omega..sub.c =cyclotron angular frequency

.omega..sub.p =plasma frequency

for the m=0 mode. The above derivation is important to understand the excitation of the desired mode by the antenna.

Another important mechanism to understand is the damping of the wave by the plasma. In the papers by Boswell, wave damping by electron collisions could not explain the experimentally observed results. Chen, however, determined that Landau damping was responsible for the large damping observed experimentally. Landau damping is a collisionless damping of waves in a plasma due to particles in the plasma that have a velocity nearly equal to the phase velocity of the wave. These particles travel with the wave, do not see a rapidly fluctuating electric field and so can effectively exchange energy with the wave. In a plasma there are electrons both faster and slower than the wave. In a Maxwellian distribution, however, there are more slow electrons than fast ones and so there are more particles taking energy from the wave than vice versa.

The damping rate due to Landau damping has been calculated by Chen for helicon waves and can be expressed as:

Damping Rate=Jm(k.sub.z)/Re(k.sub.z) 2.pi.c.sup.2 (3.8/a).sup.2 .xi..sup.3 e-.xi..sup.2

where .xi.=.omega./k.sub.z V.sub.th

and V.sub.th is the thermal velocity of the plasma electrons. It is of interest to demonstrate how sensitive the damping rate is to the value of k because it is such a steep function of .xi.. Take for example a plasma with a density of 10.sup.12 electrons/cm.sup.3, an electron temperature of 3 eV and a driving frequency of 8 MHz. The collisional damping rate would be 0.065 and the Landau damping rate would be 0.6 for k.sub.z =0.25 cm.sup.-1 and 0.0005 for k.sub.z =0.125 cm.sup.-1. It is clear that Landau damping is the important damping mechanism and that it is very dependent on the wave number k.sub.z.

There are a number of factors important in devising an antenna structure which excites whistler waves for generation of plasmas, including a) frequency of excitation, b) wave mode and c) efficiency of coupling RF power to plasma. The frequency of the waves should be such that it satisfies .OMEGA..sub.c <.omega.<.omega..sub.c where .OMEGA..sub.c is the ion cyclotron frequency, eB.sub.o /M.sub.i and .omega..sub.c is the electron cyclotron frequency eB.sub.o /M. These waves are low frequency waves that operate far below the electron cyclotron frequency.

The mode structure of the wave electric and magnetic fields should be understood so that the antenna arrangement can efficiently couple the RF power into wave excitation. As discussed above, the two lowest modes are the m=0 and m=1 modes. The mode structure of the wave electric field for an m=0 mode has radial and circumferential electric field vectors, spatially disposed at different transverse planes along the direction of wave travel, z. Within a wavelength of wave travel, the electric field varies between purely radial and purely azimuthal. The azimuthal electric field varies between being anticlockwise at one plane and being clockwise one-half wavelength away. With this understanding, it is found that the wave can be efficiently excited in this mode with an antenna that has a single loop located in a plane perpendicular to the magnetic field generating a spectrum of wave numbers such that a portion of the spectrum generated includes 2.pi./k.sub.z, where k.sub.z is given by the stated dispersion relation. The mode structure of the wave electric field for an m=1 mode imparts a natural helical pitch to the electric and magnetic field vectors as the wave propagates along the z direction. The electric field vector rotates in a righthanded sense, i.e., it rotates clockwise as it travels along B.sub.o which is in the z direction. This mode can be excited with the present invention if the single loop is canted at an angle to the magnetic field such that the wave spectrum generated contains a significant portion around 2.pi./k.sub.z, where k.sub.z is given from the dispersion relations.

The efficiency of plasma production depends on the coupling of RF energy into the plasma. As discussed above, the important mechanism for damping of the RF energy is believed to be Landau damping. The phase velocity of the whistler wave is given by .omega./k.sub.z, where k.sub.z is given by the dispersion relation and depends on the plasma density and magnetic field strength without plasma. Ideally, the phase velocity of the wave should be near the maximum of the ionization potential of the gas we wish to ionize. From the above dispersion relation for the m=0 mode:

n=.alpha.B.sub.o k.sub.z (T.sub.2 +k.sub.z.sup.2).sup.1/2

where .alpha.=B.sub.o k.sub.z.sup.2 for T<k.sub.z.

In other words, the higher the value of k.sub.z, the higher the density. However, the phase velocity of the wave is .omega./k.sub.z and so increasing k.sub.z decreases the energy of the electrons that are accelerated by the wave. If the k.sub.z is too high, then the energy of the electrons may fall below the ionization potential. It is therefore important to control k.sub.z in order to be able to increase the density and control the electron temperature.

The present invention uses low frequency whistler waves to generate plasmas with high density exceeding 10.sup.13 per cm.sup.3. The first use of whistler waves to generate dense plasmas was de