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Process for preparing retort-stable, extruded, shaped food pieces    
United States Patent5456933   
Link to this pagehttp://www.wikipatents.com/5456933.html
Inventor(s)Lee; Patrick S. (26 E. Cunningham Dr., Palatine, IL 60067)
AbstractA process for preparing a cohesive, retort-stable, shaped food piece. The process comprises: (a) preparing a premixture comprising, by weight, (1) from about 15% to about 65% by weight protein, (2) from about 15% to about 65% by weight starch, (3) from 0% to about 9% by weight fat, (4) from 0% to about 0.7% by weight added sulfur, and (5) from 0% to about 2% by weight dicalcium phosphate; (b) combining the premixture with water to form a secondary mixture, wherein the ratio of premixture to water is in the range of from about 1.6:1 to about 4:1; (c) mixing the secondary mixture for a period of time sufficient to obtain a substantially uniformly mixed dough and under conditions such that the temperature of the secondary mixture and uniformly mixed dough in the mixing operation are maintained in the range of from about 15.degree. C. to about 45.degree. C.; and (d) extruding the uniformly mixed dough into a desired shaped piece. The extrusion is carried out in conjunction with low specific mechanical energy and high pressure conditions, and under conditions such that the temperature of the uniformly mixed dough in the extrusion operation is in the range of from about 40.degree. C. to about 100.degree. C. The present invention further relates to a piece prepared by the above-described process.
   














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Inventor     Lee; Patrick S. (26 E. Cunningham Dr., Palatine, IL 60067)
Owner/Assignee    
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Publication Date     October 10, 1995
Application Number     08/168,009
PAIR File History     Application Data   Transaction History
Image File Wrapper   Patent Term   Fees
Litigation
Filing Date     December 15, 1993
US Classification     426/549 426/74 426/516 426/623 426/635 426/805
Int'l Classification     A21D 010/00
Examiner     Hunter; Jeanette
Assistant Examiner     Tran; Lien
Attorney/Law Firm    
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Priority Data    
USPTO Field of Search     426/2 426/549 426/805 426/74 426/623 426/635 426/516
Patent Tags     preparing retort-stable, extruded, shaped food pieces
   
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 U.S. References
 
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3900573



[0 after 0 votes]
5141755
Weisman
426/42
Aug,1992

[0 after 0 votes]
5000943
Scaglione
424/57
Mar,1991

[0 after 0 votes]
5000973
Scaglione
426/549
Mar,1991

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4743458
Gellman
426/549
May,1988

[0 after 0 votes]
4495205
Brander
426/104
Jan,1985

[0 after 0 votes]
4418086
Marino
426/302
Nov,1983

[0 after 0 votes]
4310558
Nahm, Jr.
426/98
Jan,1982

[0 after 0 votes]
4238515
Shemer
426/104
Dec,1980

[0 after 0 votes]
4235935
Bone
426/249
Nov,1980

[0 after 0 votes]
4211797
Cante
426/2
Jul,1980

[0 after 0 votes]
4128051
Hildebolt
99/348
Dec,1978

[0 after 0 votes]
4039691
Hildebolt
426/511
Aug,1977

[0 after 0 votes]
4029823
Bone
426/249
Jun,1977

[0 after 0 votes]
3968268
Sair
426/580
Jul,1976

[0 after 0 votes]
3965268
Stocker
426/331
Jun,1976

[0 after 0 votes]
3959511
Balaz
426/549
May,1976

[0 after 0 votes]
4997671
Spanier
426/646
Dec,1969

[0 after 0 votes]
4990356
Hamilton
426/623
Dec,1969

[0 after 0 votes]
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 Technical Review Submit all comments and votes
 Claims Submit all comments and votes
 


What is claimed is:

1. A process for preparing a cohesive, retort-stable, shaped food piece, which process comprises:

(a) preparing a premixture comprising

(1) from about 15% to about 65% by weight protein,

(2) from about 15% to about 65% by weight starch,

(3) from 0% to about 9% by weight fat,

(4) from 0% to about 0.7% by weight added sulfur,

(5) from 0% to about 2% by weight dicalcium phosphate, wherein the weight percentage of the premixture components are expressed as a percentage of the premixture;

(b) combining the premixture with water to form a secondary mixture, wherein the ratio of premixture to water is in the range of from about 1.6:1 to about 4:1;

(c) mixing the secondary mixture for a period of time sufficient to obtain a substantially uniformly mixed dough and under conditions such that the temperature of the secondary mixture and uniformly mixed dough in the mixing operation are maintained in the range of from about 15.degree. C. to about 45.degree. C.; and

(d) extruding the uniformly mixed dough into a desired shaped piece, wherein the extrusion is carried out at a specific mechanical energy in the range of from about 6 watt.multidot.hr./kg. to about 70 watt.multidot.hr./kg. and under a pressure of at least about 400 psig., and under conditions such that the temperature of the uniformly mixed dough in the extrusion operation is in the range of from about 40.degree. C. to about 100.degree. C., and wherein said shaped piece is cohesive and maintains its shape when retorted.

2. A process according to claim 1 wherein the fat is in the form of choice white grease, the sulfur is in the form of methionine, and wherein the premixture comprises from about 15% to about 35% by weight protein, from about 25% to about 60% by weight starch, from about 1% to about 8% by weight choice white grease, from about 0.1% to about 1% by weight methionine, and from about 0.1% to about 1% by weight dicalcium phosphate.

3. A process according to claim 2 wherein the premixture comprises from about 20% to about 40% by weight of a wheat gluten protein source and from about 30% to 75% by weight of a corn flour starch source.

4. A process according to claim 2 wherein the ratio of premixture to water is in the range of from about 1.65:1 to about 2.5:1.

5. A process according to claim 4 wherein the secondary mixture is mixed in a paddle mixer for a period of time in the range of from about 3 minutes to about 8 minutes.

6. A process according to claim 5 wherein the premixture further comprises from about 1% to about 30% by weight meat and bone meal.

7. A process according to claim 6 wherein the extruder is operated at a pressure of at least about 500 psig.

8. A process according to claim 7 wherein the specific mechanical energy of the extruder is in the range of from about 6 watt.multidot.hr./kg. to about 50 watt.multidot.hr./kg., wherein the extruder is operated at a speed in the range of from about 45 to about 60 RPM, and wherein the temperature of the dough exiting the extruder is in the range of from about 45.degree. C. to about 90.degree. C.

9. A process for preparing a retort-stable, shaped food piece, which process comprises:

(a) preparing a premixture comprising

(1) from about 25% to about 35% by weight wheat gluten,

(2) from about 35% to about 65% by weight corn flour,

(3) from about 3% to about 6% by weight choice white grease,

(4) from about 0.2% to about 0.5% by weight methionine,

(5) from about 0.1% to about 1% by weight dicalcium phosphate;

(b) combining the premixture with water to form a secondary mixture, wherein the ratio of premixture to water is in the range of from about 1.65:1 to about 1.85:1;

(c) mixing the secondary mixture in a ribbon mixer for a period of time in the range of from about 4 to about 6 minutes, thereby obtaining a substantially uniformly mixed dough, wherein said mixing is carried out under conditions such that the temperature of the secondary mixture and uniformly mixed dough in the mixing operation are maintained in the range of from about 20.degree. C. to about 25.degree. C.; and

(d) extruding the uniformly mixed dough into a desired shaped piece, wherein the extruder is operated at a speed in the range of from about 50 to 60 RPM, the dough exit temperature is in the range of from about 60.degree. C. to about 80.degree. C., the exit pressure is at least 600 psig, and the specific mechanical energy provided by the extruder is in the range of from about 6 watt.multidot.hr./kg. to about 35 watt.multidot.hr./kg.

10. A cohesive, retort-stable, shaped food piece prepared by the process comprising:

(a) preparing a premixture comprising

(1) from about 15% to about 65% by weight protein,

(2) from about 15% to about 65% by weight starch,

(3) from 0% to about 9% by weight fat,

(4) from 0% to about 0.7% by weight added sulfur,

(5) from 0% to about 2% by weight dicalcium phosphate, wherein the weight percentage of the premixture components are expressed as a percentage of the premixture;

(b) combining the premixture with water to form a secondary mixture, wherein the ratio of premixture to water is in the range of from about 1.6:1 to about 4:1;

(c) mixing the secondary mixture for a period of time sufficient to obtain a substantially uniformly mixed dough and under conditions such that the temperature of the secondary mixture and uniformly mixed dough in the mixing operation are maintained in the range of from about 15.degree. C. to about 45.degree. C.;

(d) extruding the uniformly mixed dough into a desired shaped piece, wherein the extrusion is carried out at a specific mechanical energy in the range of from about 6 watt.multidot.hr./kg. to about 70 watt.multidot.hr./kg. and under a pressure of at least about 400 psig., and under conditions such that the temperature of the uniformly mixed dough in the extrusion operation is in the range of from about 40.degree. C. to about 100.degree. C., and wherein said shaped piece is cohesive and maintains its shape when retorted.

11. A retort-stable, shaped food piece prepared by the method comprising:

(a) preparing a premixture comprising

(1) from about 25% to about 35% by weight wheat gluten,

(2) from about 35% to about 65% by weight corn flour,

(3) from about 3% to about 6% by weight choice white grease,

(4) from about 0.2% to about 0.5% by weight methionine,

(5) from about 0.1% to about 1% by weight dicalcium phosphate;

(b) combining the premixture with water to form a secondary mixture, wherein the ratio of premixture to water is in the range of from about 1.65:1 to about 1.85:1;

(c) mixing the secondary mixture in a ribbon mixer for a period of time in the range of from about 4 to about 6 minutes, thereby obtaining a substantially uniformly mixed dough, wherein said mixing is carried out under conditions such that the temperature of the secondary mixture and uniformly mixed dough in the mixing operation are maintained in the range of from about 20.degree. C. to about 25.degree. C.; and

(d) extruding the uniformly mixed dough into a desired shaped piece, wherein the extruder is operated at a speed in the range of from about 50 to 60 RPM, the dough exit temperature is in the range of from about 60.degree. C. to about 80.degree. C., the exit pressure is at least 600 psig, and the specific mechanical energy provided by the extruder is in the range of from about 6 watt.multidot.hr./kg. to about 35 watt.multidot.hr./kg.
 Description Submit all comments and votes
 


FIELD OF INVENTION

The present invention relates to a process for preparing a retort-stable, extruded, shaped food piece which is cohesive and maintains its shape when retorted. The present invention further relates to the retort-stable, extruded, shaped food piece prepared by the process of the present invention.

BACKGROUND OF INVENTION

Pet owners typically have a great deal of affection for their pets. Many, in fact, consider their pets to be members of their families, and treat them accordingly by indulging them to a great degree. One of the ways owners indulge their pets is by the food they purchase for them. In this context, many owners derive pleasure from feeding their pets foods which contain shaped food pieces which the owner identifies with the particular type of pet. An example of this would be a bone-shaped food piece in a dog food.

Of course, these shaped food pieces must also contribute to satisfying the nutritional requirements for the particular pet. To accomplish this, the shaped pieces are preferably prepared from proteinaceous and farinaceous material. The term proteinaceous material refers to glutens such as wheat gluten, corn gluten, rice gluten, and other types of cereal grain glutens known to those skilled in the art; proteinaceous material obtained from other sources such as defatted oil seed protein material; dried eggs; whole corn; wheat germ meal; dehulled soy meal; meat and bone meal; and other known proteinaceous sources. The term farinaceous material refers to cereal flours such as wheat flour, corn flour, rice flour, oat flour, and other types of cereal flours known to those skilled in the art; ground hard wheat; ground whole corn; and other types of ground cereal-based grain material.

One problem in preparing such extruded, shaped pieces is that many pet foods have to undergo the extreme processing conditions of a retort sterilization procedure. For certain shaped proteinaceous materials, such as meat analogs, this is not a concern. These meat analogs retain their analog properties even when subjected to a retort operation. However, these meat analogs are structurally different than the shaped pieces of the present invention in that they are typically prepared from texturized vegetable protein (TVP) and may have a striated texture. By "striated texture" it is meant that the shaped piece tends to have a texture analogous to muscle striations. This striated texture allows the shaped piece to be easily torn apart along the striations, and as such the piece does not have to maintain a distinct and definite shape when subjected to a retort operation.

The extruded shaped pieces of the present invention do not have such a striated texture, however, but instead are, for the most part, cohesive. Until now, extruded shaped pieces having a cohesive texture like those of the present invention could not withstand the extreme conditions of a retort operation, but would typically dissolve when retorted. This would be undesirable since the shaped piece would not maintain its original shape and form, but would be unrecognizable.

Thus, shaped food pieces having the cohesive consistency of the shaped pieces of the present invention are useful only when they are retort-stable, i.e., do not dissolve upon hydration and/or retorting, but maintain their desired shape. The present invention provides such a piece, as well as a process for its preparation.

BACKGROUND ART

There are numerous processes known in the art for producing shaped, extruded, edible proteinaceous products.

U.S. Pat. No. 3,968,268, issued Jul. 6, 1976 to Sair et al., discloses a process for producing hydratable, translucent to glassy, proteinaceous products, and the resulting products themselves. In the claimed process a water-moistened, edible proteinaceous material having at least about 40% by weight protein, on a dry weight basis, and an effective amount of water, within the range of about 10 to 50%, is subjected to working under effective mechanical pressure with added heat sufficient to convert it to a hot, moist, plastic extrudable mass. This hot, plastic mass is extruded through and from a length of a temperature controlled, elongated die under non-puffing conditions. The extruded product is unpuffed, substantially homogeneous, translucent to glassy, and characterized by having texture and retaining its structural integrity under retorting conditions. This product is alleged to be pleasing in the mouth and have protein cell bodies with the pleasing feel, firmness, structure, texture, coarseness, or bite characteristics found in uncooked or cooked food products.

Sair et al. also teach that in their process the proteinaceous material must be heated to a sufficiently high temperature to retain retort stability. Specifically, they teach that extruded proteinaceous materials which are extruded at temperatures of 180.degree. F., 210.degree. F., and 230.degree. F., completely disintegrate when subjected to retorting. This is contrary to what has been found in the present invention, where the products are shaped and formed at low dough temperatures and maintain their shape when retorted.

U.S. Pat. No. 3,965,268, issued Jun. 22, 1976 to Stocker et al., refers to an expanded protein product comprising a sulfur-containing organic compound. Stocker et al. claim a method of preparing an expanded edible protein product having an open, cellular structure, the method comprising forming an admixture of proteinaceous material having a protein content of at least about 30% by weight, from about 0.05% to about 2.0% by weight of said proteinaceous material of a sulfur-containing organic compound selected from the group consisting of cysteine hydrochloride, D,L-methionine, sodium lignosulfonate, thiamine mononitrate, calcium thioglycollate, and mixtures thereof, and water in an amount sufficient to result in a moisture content of 15% to about 50% by weight of said admixture; heating the mix to a temperature above about 220.degree. F.; mechanically working the heated mix at a pressure substantially above atmospheric pressure; and expanding the mix by suddenly releasing the pressure. The expanded product has a crisp, crunchy texture which lends itself to use in a large number of foodstuffs, for example snack items.

As can be seen, the product of the process taught by Stocker et al. has a different texture than the shaped edible piece of the present invention. Furthermore, the process taught by Stocker et al. includes a heating step which is not required in the process of the present invention.

As already stated herein, it is also known to make a striated, texturized shaped meat analog. This technology uses a vegetable protein, or extract, along with a sulfur-containing compound, typically a sulfur-containing amino acid or pure sulfur itself, to make the striated, texturized piece. An extrusion process operated under high shear and temperature conditions is typically used to manufacture this meat analog. The high shear and temperature conditions facilitate the cross-linking of the vegetable proteins.

The resulting extruded meat analog is typically very porous, and upon hydration expands to several times its dry weight and size. The hydrated meat analog is also porous and is spongy to the touch and chew. After retorting, the hydrated and retorted meat analog is spongy and soft. The meat analog is easily torn apart following retorting, due to its striated structure.

As can be seen, there is nothing in the art which teaches the shaped piece prepared by the process of the present invention. It is therefore an object of the present invention to provide a process for preparing such a shaped food piece which is cohesive and maintains a definite and distinct shape and integrity when hydrated and/or retorted.

It is another object of the present invention to provide an edible, shaped food piece which is cohesive and maintains a definite and distinct shape and integrity when hydrated and/or retorted.

These objects are accomplished by the invention described herein.

Unless otherwise specified, the weight percentages provided herein for the components of the premixture are on a wet basis.

SUMMARY OF THE INVENTION

The present invention relates to a process for preparing a cohesive, retort-stable, shaped food piece, said process comprising:

(a) preparing a premixture comprising

(1) from about 15% to about 65% by weight protein,

(2) from about 15% to about 65% by weight starch,

(3) from 0% to about 9% by weight fat,

(4) from 0% to about 0.7% by weight added sulfur,

(5) from 0% to about 2% by weight dicalcium phosphate, wherein the weight percentage of the premixture components are expressed as a percentage of the premixture;

(b) combining the premixture with water to form a secondary mixture, wherein the ratio of premixture to water is in the range of from about 1.6:1 to about 4:1;

(c) mixing the secondary mixture for a period of time sufficient to obtain a substantially uniformly mixed dough and under conditions such that the temperature of the secondary mixture and uniformly mixed dough in the mixing operation are maintained in the range of from about 15.degree. C. to about 45 .degree. C.; and

(d) extruding the uniformly mixed dough into a desired shaped piece, wherein the extrusion is carried out in conjunction with low specific mechanical energy and high pressure conditions, and under conditions such that the temperature of the uniformly mixed dough in the extrusion operation is in the range of from about 40.degree. C. to about 100.degree. C., and wherein said shaped piece is cohesive and maintains its shape when retorted.

The present invention further relates to a piece prepared by the above-described process.

DETAILED DESCRIPTION OF THE INVENTION

The present invention comprises a process for preparing a retort-stable, shaped food piece. The piece maintains its shape when hydrated and retorted, e.g., if the piece is originally formed in a bone shape, the hydrated piece will maintain the bone shape and the retorted piece will maintain the bone shape.

In the process of the present invention a premixture is initially prepared. The premixture comprises from about 15% to about 65%, preferably from about 15% to about 35%, more preferably from about 20% to about 30% by weight protein; from about 15% to about 65%, preferably from about 25% to about 60%, more preferably from about 30% to about 55% by weight starch; from 0% to about 9%, preferably from about 1% to about 8%, more preferably from about 3% to about 6% by weight fat; from 0% to about 0.7%, preferably from about 0.01% to about 0.5%, more preferably from about 0.1% to about 0.2% by weight added sulfur; and from 0% to about 2%, preferably from about 0.1% to about 1% dicalcium phosphate.

The protein present in the premixture of the present invention may be derived from any source known to those skilled in the art, and is preferably derived from wheat gluten. It is believed that other protein sources, such as corn gluten, may work in the present invention as well. Examples of other protein sources believed to be useful in the present invention include, but are not limited to, those protein sources listed in Table I below. Table I also includes an approximate description of the amount of protein, starch (also stated as "carbohydrate"), fat, and moisture each protein source can contribute to the premixture. These protein sources may also be combined with each other in the premixture.

TABLE I ______________________________________ Sources of Protein and Starch that may be used in premixrure: MOISTUR PROT FAT CORBOH INGREDIENT % % % % ______________________________________ CRACKD PEARLED 11.194 12.584 1.724 70.987 BARLEY CORN FLOUR 9.438 7.339 2.111 79.202 CORN GERM MEAL 10.631 12.077 0.919 60.732 CORN STARCH 9.850 2.517 0.195 87.125 CORN YELLOW 14.201 8.692 3.600 69.807 CORN 14.500 8.110 3.600 70.290 OAT FLOUR 8.650 15.300 6.100 66.876 FEEDING OATMEAL 7.507 14.427 7.700 66.416 CORN GLUTEN 10.841 61.694 5.272 19.619 MEAL BREWERS RICE 11.559 9.027 0.610 76.704 RICE HULLS 9.162 3.405 8.600 22.966 CORN 12.431 8.727 4.730 70.642 GROUND SOYBEAN 9.962 13.476 1.200 36.817 HULLS SOYBEAN MEAL 11.652 45.290 2.575 30.626 DEHULL SOY MEAL 10.954 48.818 2.820 28.339 SOY FLOUR 5.251 53.650 2.551 34.328 SOY FLOUR 5.505 53.357 1.397 29.583 SOY PROTEIN 6.534 66.261 0.568 17.908 CONC. SOYBEAN GRITS - 7.945 52.901 1.100 28.647 50% SOY FLOUR 5.799 52.693 2.469 30.186 TEX SYBN FL 7.850 50.000 1.000 31.950 TVP 8.980 51.400 1.680 29.080 WHEAT 12.168 11.394 1.600 72.506 WHEAT FEED FL 12.684 14.349 2.420 68.010 WHEAT FEED FL 11.677 11.823 1.865 72.623 WHEAT FEED FL 5.881 13.709 2.757 75.756 WHEAT BRAN 13.802 17.473 3.274 49.159 WHEAT GERM 12.786 27.136 7.669 44.935 MEAL WHEAT MIDDLINGS 12.576 16.337 3.591 54.452 WHEAT 10.195 13.856 2.960 68.526 PELLETED WHEAT 12.042 15.975 3.591 55.348 MIDDS WHEAT FEED FL 10.990 15.030 3.390 67.733 WHEAT FEED FL 11.984 17.306 3.390 64.716 WHEAT GLUTEN 9.100 78.990 0.818 9.819 ______________________________________

Wheat gluten is the preferred source of protein in the premixture of the present invention. This is because wheat gluten has a relatively high protein concentration (79%) and is therefore a good protein source.

Wheat gluten is a concentrated natural protein in the form of a light tan powder having a bland taste and aroma. Wheat gluten is known to consist mainly of gliadin (prolamine) and glutenin (glutelin), which are the principle cereal proteins, together with other components of the endosperm cell. Wheat gluten is separated from wheat flour by a washing method known to those skilled in the art.

The precise amount of any particular protein source used to prepare the premixture of the present invention will be that amount necessary to provide a protein content in the premixture in the range of from about 15% to about 65% by weight, and will be dependent upon the particular protein source utilized and the protein content of the particular source. The preferred wheat gluten, which has a protein content of 79% by weight, will comprise from about 20% to about 80%, preferably from about 20% to about 40%, more preferably from about 25% to about 35% by weight of the premixture.

The gluten protein source may be provided to the premixture in the form of isolated gluten added to the premixture, gluten inherent in the starch source present in the premixture, and mixtures thereof.

The starch source used in the present invention may be derived from any starch source known to those skilled in the art, including, but not limited to, cereal flours obtained from known grains; ground hard wheat; ground whole corn; and other types of ground cereal-based grain material. Examples of flours useful in the present invention include, but are not limited to, wheat flour, corn flour, oat flour, along with other types of cereal flours known to those skilled in the art, and mixtures thereof, with corn flour being preferred.

As with the protein source, the precise amount of any particular starch source used in preparing the premixture of the present invention will be that amount necessary to provide a total starch content in the premixture in the range of from about 15% to about 65% by weight, and is dependent upon the particular type of starch source being utilized and the starch content of the starch source. For example, the preferred corn flour has a starch content of about 79% by weight. When this preferred corn flour is used, the premixture comprises from about 20% to about 80%, preferably from about 30% to about 75%, more preferably from about 35% to about 65% by weight corn flour.

The exact amounts of any particular protein and/or starch source required to prepare the premixture of the present invention can be calculated by using the approximate concentrations of protein and starch contained in the specific type of ingredient, as stated in Table I, and determining the amount of ingredient needed to achieve a total premixture concentration in the above specified ranges.

The fat which may be added to the premixture of the present invention may be obtained from any fat source known to those skilled in the art. Examples of fat sources useful in the present invention include, but are not limited to, choice white grease, beef tallow, soy oil, corn oil, vegetable oil, and mixtures thereof, with choice white grease being the preferred fat source.

The amount of a particular fat source that must be used in the premixture is that amount necessary to provide a total fat content in the premixture in the range of from 0% to about 9%, preferably from about 1% to about 8%, more preferably from about 3% to about 6% by weight. Of course, the required amount of a particular fat source necessary to achieve this will vary for differing fat sources. However, this is something one skilled in the art can determine. When the preferred choice white grease is used as the fat source, the premixture comprises from 0% to about 9%, preferably from about 1% to about 8%, more preferably from about 3% to about 6% by weight choice white grease.

When fat is included in the premixture of the present invention it facilities the process of the present invention by lubricating the material flow through the extrusion operation, thereby lowering shear and energy transfer to the product.

The sulfur which may be added to the premixture of the present invention may be in the form of pure sulfur or either as an organic or inorganic sulfur-containing compound. This sulfur is considered "added sulfur" and is added to the premixture separately from the other premixture ingredients and in a manner sufficient to contribute the specified amount of sulfur to the premixture. Sulfur may also be present in the other premixture ingredients (e.g., gluten, flour, etc.), but any such amounts are typically not significant and are not considered when determining the amount of sulfur added to the premixture.

Any type of sulfur-containing compound useful in the preparation of edible foodstuffs may be used in preparing the premixture of the present invention. Examples of useful sulfur-containing organic compounds include, but are not limited to, sulfur-containing amino acids, lower alkyl mercaptans, lower alkyl sulfides, lower alkyl disulfides, thioacids, and other compounds, for example thiamine, may be employed. Among these, compounds such as cysteine, cystine, methionine, thiodipropionic acid, thioglycollin, thiamine, lignosulfonic acid, and their salts are preferred, with methionine being most preferred.

The amount of a particular sulfur source that must be used in the premixture is that amount sufficient to provide a total added sulfur content in the premixture in the range of from 0% to about 0.7%, preferably from about 0.01% to about 0.5%, more preferably from about 0.1% to about 0.2% by weight of the premixture. Of course, the required amount of a particular sulfur source necessary to achieve this will vary for differing sulfur sources, although falling within the broad range specified above, and will be appreciated by one skilled in the art. When the preferred methionine is used as the sulfur source, it comprises from 0% to about 2%, preferably from about 0.1% to about 1%, more preferably from 0.2% to 0.5% by weight of the premixture.

The dicalcium phosphate, when added to the premixture of the present invention, comprises from 0% to about 2%, preferably from about 0.1% to about 1% by weight of the premixture.

Other optional ingredients which may be added to the premixture of the present invention include, but are not limited to, meat and bone meal, edible fiber sources, nutritional supplements, coloring agents, and flavoring agents.

When such optional ingredients are added to the premixture, the levels at which they are added will vary depending upon the particular optional ingredient. When meat and bone meal is included in the premixture it typically comprises from 0% to about 50%, preferably from 1% to about 30%, more preferably from about 2% to about 15% by weight of the premixture.

When adding the fat, sulfur, dicalcium phosphate, and other optional ingredients, care must be taken to avoid adding amounts of such ingredients which may disrupt the formation of a gluten matrix. If such disruption occurs, then retort stability may be adversely affected.

Coloring agents and flavoring agents are added to the premixture at levels necessary to impart the desired flavor and color to the final product, which will be dependent upon the preferences of the particular formulator. Such coloring and flavoring agents are typically added to the premixture at levels of less than 1% by weight.

The premixture is next combined with water to form a secondary mixture. The ratio of the premixture to water i