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Plasma treatment apparatus    
United States Patent5487785   
Link to this pagehttp://www.wikipatents.com/5487785.html
Inventor(s)Horiike; Yasuhiro (Hiroshima, JP); Fukasawa; Takayuki (Yamanashi, JP)
AbstractA semiconductor wafer plasma treatment apparatus comprising a processing vessel whose interior is maintained at a predetermined degree of vacuum; a plasma generation means which is arranged on an upper surface of the processing vessel and generates radio-frequency waves into the interior thereof, to cause the generation of a plasma in the process gas within the processing vessel; and a holder for holding a semiconductor wafer that is to be subjected to a predetermined treatment by the plasma generated from the process gas by the action of the plasma generation means, a supply means which supplies process gas into the processing vessel comprises first gas supply pipes that are arranged at positions equidistant in the peripheral direction around the processing vessel and a second gas supply pipe that is arranged at the center of an upper surface of the processing vessel, and gas exhaust means from exhaust gases from the processing vessel is arranged at positions equidistant in the peripheral direction around the processing vessel. This configuration counters any drop in the plasma density at the central portion of the processing vessel to obtain a uniformly high-density plasma, making it possible to subject large-diameter semiconductor wafers to uniform, rapid treatment.
   














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Drawing from US Patent 5487785
Plasma treatment apparatus - US Patent 5487785 Drawing
Plasma treatment apparatus
Inventor     Horiike; Yasuhiro (Hiroshima, JP); Fukasawa; Takayuki (Yamanashi, JP)
Owner/Assignee     Tokyo Electron Kabushiki Kaisha (Tokyo, JP)
Patent assignment
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Publication Date     January 30, 1996
Application Number     08/233,591
PAIR File History     Application Data   Transaction History
Image File Wrapper   Patent Term   Fees
Litigation
Filing Date     March 25, 1994
US Classification     118/723E 118/723MP 118/723MR 204/298.07 204/298.16 204/298.37
Int'l Classification     C23C 016/00
Examiner     Breneman; R. Bruce
Assistant Examiner     Chang; Joni Y.
Attorney/Law Firm     Beveridge, DeGrandi, Weilacher & Young
Address
Parent Case    
Priority Data     Mar 26, 1993[JP]5-092303 Mar 26, 1993[JP]5-092304
USPTO Field of Search     118/723 E 118/723 ER 118/723 MW 118/723 MA 118/723 MR 118/723 MP 118/345 204/298.16 204/298.17 204/298.18 204/298.19 204/298.2 204/298.21 204/298.22 204/298.37 204/298.07
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ReferenceRelevancyCommentsReferenceRelevancyComments
5254171
Hayakawa
118/723MR
Oct,1993

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5173641
Imahashi
315/111.41
Dec,1992

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5134965
Tokuda
118/723MW
Aug,1992

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5122251
Campbell
204/298.06
Jun,1992

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5000113
Wang
118/723E
Mar,1991

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What is claimed is:

1. A plasma treatment apparatus comprising:

a processing vessel capable of being maintained at a degree of vacuum;

gas supply means for supplying a process gas into said processing vessel;

gas exhaust means for exhausting gases from within said processing vessel after treatment is completed;

plasma generation means provided in said processing vessel to generate radio-frequency waves within said processing vessel to cause generation of a plasma in said process gas; and

holder means provided in said processing vessel to hold an object to be subjected to treatment by said plasma, said object having a surface to be treated;

said gas supply means comprising;

a plurality of first gas supply means arranged equidistantly around a periphery of said processing vessel, said first gas supply means being provided to direct the process gas toward a center of said processing vessel and over said surface of the object; and

second gas supply means arranged at a center of an upper portion of said processing vessel to supply the process gas toward a central portion of the processing vessel and over said surface of the object;

said gas exhaust means comprising a plurality of gas exhaust structres arranged equidistantly around said periphery of said process vessel.

2. A plasma treatment apparatus comprising:

a processing vessel capable of being maintained at a degree of vacuum;

gas supply means for supplying a process gas into said processing vessel, said gas supply means including a plurality of first gas supply means arranged equidistantly around a periphery of said processing vessel, and second gas supply means arranged at a center of aun upper portion of said processing vessel;

gas exhaust means for exhausting gases from within said processing vessel after treatment is completed, said gas exhaust means including a plurality of gas exhaust structures arranged equidistantly around said periphery of said processinmg vessel;

plasma generation means provided in said processing vessel to generate radio-frequency waves within said processing vessel to cause generation of a plasma in said process gas, said plasma generation means comprising a one-turn loop antenna having an outer diameter greater than that of an object to be treated; and

holder means provided in said processing vessel to hold said object to be subjected to treatment by said plasma.

3. A plasma treatment apparatus in accordance with claim 1, wherein said first gas supply means is positioned higher than said gas exhaust structures and is positioned between two neighboring gas exhaust structures with respect to the perimeter of said processing vessel.

4. A plasma treatment apparatus in accordance with claim 1, further comprising a capacitor for maintaining a bias potential of said holder means, said capacitor having a capacitance at least 10 times that of an ion sheath formed in the vicinity of said holder means.

5. A plasma treatment apparatus in accordance with claim 4, wherein the capacitance of said capacitor is at least 50 times that of said ion sheath.

6. A plasma treatment apparatus in accordance with claim 4, wherein the capacitance of said capacitor is at least 50 times that of said ion sheath.

7. A plasma treatment apparatus comprising:

a processing vessel capable of being maintaind at a degree of vacuum;

gas supply means for supplying a process gas into said processing vessel;

gas exhaust means for exhausting gases from within said processing vessel after treatment is completed;

application means provided in an upper portion of said processing vessel;

helical wave plasma generation means provided surrounding said application means and causing generation of a helical wave plasma; and

second plasma generation means provided above said application means, to generate radio-frequency waves and direct them toward an interior of said application means and thus increase the density of said plasma.

8. A plasma treatment apparatus in accordance with claim 7, wherein said second plasma generation means comprises a loop antenna, a radio-frequency power source, and matching means inserted between said loop antenna and said radio-frequency power source.

9. A plasma treatment apparatus in accordance with claim 7, wherein said gas supply means comprises a plurality of first gas supply means arranged equidistantly around a periphery of said processing vessel and second gas supply means arranged at a center of an upper surface of said processing vessel, and wherein

said gas exhaust means comprises a plurality of gas exhaust structures arranged equidistantly around periphery of said processing vessel.

10. A plasma treatment apparatus comprising:

a processing vessel capable of being maintained at a degree of vacuum;

gas supply means for supplying a process gas into said processing vessel;

gas exhaust means for exhausting gases from within said processing vessel after treatment is completed;

holder means for holding an object to be treated in said processing vessel; and

helical plasma generation means provided in a side portion of said processing vessel, to cause a helical wave plasma to be generated within said process gas in a flat-plate-shaped region interposed within a gap proximal to an object that is held on said holder means;

said helical plasma generation means comprising:

electromagnetic wave generation mean for generating electromagnetic waves parallel to said object on said holder means; and

rectangular magnetic field shaping means for shaping a rectangular magnetic field in a same direction as electromagnetic waves from said electromagnetic wave generation means to cause generation of said helical wave plasma from said electrogmagnetic waves.

11. A plasma treatment apparatus in accordance with claim 10, wherein said helical plasma generation means comprises a pair of means arranged symmetrically on sides of said facing toward said processing vessel.

12. A plasma treatment apparatus in accordance with claim 10, wherein said gas supply means comprises a plurality of scattered gas supply holes in a gas supply head, said gas supply head being positioned above said holder means for supplying said process gas in a direction toward said holder means.

13. A plasma treatment apparatus in accordance with claim 10, further comprising a magnetic path provided around the periphery of said holder means for reducing the magnetic field in the vicinity of said object.

14. A plasma treatment apparatus in accordance with claim 10, wherein said gas supply means comprises a plurality of first gas supply means arranged equidistantly around a periphery of said processing vessel, and second gas supply means provided at a center of an upper portion of said processing vessel, and wherein said gas exhaust means comprises a plurality of gas exhaust structure arranged around a periphery of said processing vessel.

15. A plasma treatment apparatus comprising:

a processing vessel capable of being maintained at a degree of vacuum;

gas supply means for supplying a process gas into said processing vessel;

gas exhaust means exhausting gases from within said processing vessel after treatment is completed;

plasma generation means provided in said processing vessel to generate radio-frequency waves within said processing vessel to cause generation of a plasma; and holding means provided in said processing vessel to hold an object to be subjected to treatment by said plasma, said object having a surface to be treated;

said gas supply means comprising:

a plurality of first gas supply means arranged equidistantly around said processing vessel to supply the process gas toward a central portion within the processing vessel and over said surface of the object; and

second gas supply means arranged at an upper portion of said processing vessel to supply the process gas downward toward a central portion of the processing vessel and over said surface of the objecgt;

said gas exhaust means comprising a pluraity of gas exhaust structures arranged equidxistantly in the peripheral direction around said processing vessel.

16. A plasma treatment apparatus comprising:

a processing vessel capable of being maintained at a degree of vacuum;

gas supply means for supplying a process gas into said processing vessel;

gas exhaust means for exhausting gases from within said processing vessel after treatment is completed;

plasma generation means provided in said processing vessel to generate radio-frequency waves within said processing vessel to cause generation of a plasma, said plasma generation means comprising a one-turn loop antenna having an outer diameter greater than that of an object to be treated; and

holding means provided in said processing vessel to hold said object to be subjected to treatment by said plasma;

said gas supply means comprising:

a plurailty of first gas supply means arranged equidistantly aroun said processing vessel to supply the process gas toward a central portion within the processing vesse; and

second gas supply means arranged at an upper portion of said processing vessel to supply the process gas downward toward a central portion of the processing vessel;

said gas exhaust means comprising a plurality of gas exhaust structures arranged equidistantly in the peripheral direction around said processing vessel.

17. A plasma treatment apparatus in accordance with claim 15, wherein said first gas supply means is positioned higher than said gas exhaust structures and is positioned between two neighboring gas exhaust structures with respect to the perimeter of said processing vessel.

18. A plasma treatment apparatus in accordance with claim 15, further comprising a capacitor for maintianing a bias potential of said holding means, said capacitor having a capacitance at least 10 times that of an ion sheath formed in the vicinity of said holding means.

19. A plasma treatment apparatus in accordance with claim 15, wherein the capacitance of said capacitance is at least 50 times that of said ion sheath.

20. A plasma treatment apparatus in accordance with claim 15, wherein the capacitance of said capacitor is at least 100 times that of said ion sheath.
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BACKGROUND OF THE INVENTION

1. Field of the Invention

The present invention relates to a plasma processing or treatment apparatus for an object such as a semiconductor wafer.

2. Related Art

A plasma processing or treatment apparatus is configured such that a plasma is generated by vacuum-charging the interior of a processing vessel in which exists a processing gas, and that plasma is used to implement a predetermined treatment on an object such as a semiconductor wafer. In the prior art, such plasma treatment apparatuses are widely used throughout the semiconductor fabrication process, in steps such as in sputtering, ashing, CVD, and etching.

In a typical plasma treatment apparatus, a pair of horizontal, flat electrodes that face each other act as the plasma generation source. In this type of apparatus, the relationship of the electrode configuration means that a comparatively high gas pressure of, for example, several hundreds of mmTorr is used, and thus problems can occur such as ions within the plasma impacting against the electrodes and causing sputtering of the electrodes, which will lead to impurities being generated from the electrodes. For that reason, this type of apparatus is difficult to adapt to cope with recent ultra-fine processing techniques at a half-micron and greater. That is why various plasma treatment apparatuses are currently being developed to generate high-density plasmas under hard vacuum conditions. Examples of these plasma treatment apparatuses include a magnetron style that uses orthogonal electromagnetic fields, a radio-frequency inductively coupled style that uses radio-frequency electromagnetic energy, and, most recently, an apparatus that uses helicon, or helical waves generated from electromagnetic waves propagated parallel to a magnetic field.

A radio-frequency inductively coupled type of plasma treatment apparatus is provided with: a processing vessel that has a gas supply portion for supplying a processing gas and a gas exhaust portion for exhausting the gas after the treatment, and which maintains a predetermined degree of vacuum therein; a plasma generation means arranged on an upper surface of the processing vessel; and a holder device that holds a semiconductor wafer on which a predetermined treatment is to be performed in a plasma produced by the plasma generation means. The processing vessel is provided with a main body formed from an electrically conductive material such as stainless steel, with an upper portion formed from an insulating material that is transparent to radio-frequency waves, such as quartz, mounted on an upper end of the main body. Each of the above mentioned gas supply portion and gas exhaust portion is attached to the peripheral surface of the main body. The plasma generation means is provided with, for example, a one-turn antenna and a radio-frequency power source connected to this antenna by a matching circuit, with the configuration being such that radio-frequency electric power from the radio-frequency power source is supplied to the antenna through the matching circuit, radio-frequency waves are generated within the processing vessel from the antenna, and the process gas is activated by this electromagnetic energy to cause the generation of a plasma. The holder device is configured such that another radio-frequency power source is connected thereto with a blocking capacitor therebetween, radio-frequency electric power is supplied from this radio-frequency power source, and a self-bias potential is maintained with respect to the plasma's potential, via the blocking capacitor. When the above mentioned plasma treatment apparatus is used to physically etch a semiconductor wafer using argon, the pressure of the argon within the processing vessel is first adjusted to 10 mmTorr, with the semiconductor wafer held on the holder device. Next, when predetermined electric power from the radio-frequency power source is supplied to the antenna via the matching circuit, radio-frequency waves are generated within the processing vessel from the antenna, this electromagnetic energy excites the argon to form a plasma, and thus a high-density plasma of, for example, the order of 10.sup.11 cm.sup.-3 is generated. At the same time, since 100-kHz radio-frequency electric power is supplied through the blocking capacitor from the radio-frequency power source in the holder device, an ion sheath is formed between the holder device and the plasma, and argon ions from the plasma impact against the semiconductor wafer to perform the predetermined etching.

The previously mentioned prior art helical wave plasma treatment apparatus is provided with: a processing vessel having a gas supply means for supplying a process gas and a gas exhaust means for exhausting gases after the treatment, and is maintained at a predetermined degree of vacuum; a helical wave plasma generation means that surrounds an application portion forming part of the processing vessel; and a holder device for holding a semiconductor wafer that is to be subjected to a predetermined treatment by the helical wave plasma generated from the process gas by the action of the helical wave plasma generation means. This application portion is formed of an insulating material that is transparent to electromagnetic waves, such as quartz, and the above described main body connected to a lower end aperture of the application portion is formed of an electrically conductive material such as stainless steel. The helical wave plasma generation means is also provided with an antenna surrounding the outer peripheral surface of the application portion and an electromagnetic coil also surrounding the application portion, but further out from the antenna. The configuration is such that electromagnetic waves from the antenna propagate parallel to the magnetic field shaped by the electromagnetic coil; the electromagnetic waves are subjected to the action of the magnetic field as they propagate through the plasma, and thus generate helical waves; and a high-density helicon wave plasma is generated by these helical waves.

When this helicon wave plasma treatment apparatus is being used to physically etch a semiconductor wafer using argon, argon is first supplied from the gas supply means into the processing vessel and its pressure is adjusted to 10 mmTorr, with the semiconductor wafer held on the holder device. In this state, radio-frequency electric power is applied to the antenna, the generation of electromagnetic waves proceeding from the antenna in the axial direction within the processing vessel causes electrons to absorb energy from these electromagnetic waves, these electrons collide with the argon gas, ionizable energy is imparted to the argon atoms, and this generates the high-density plasma. At the same time, a magnetic field is shaped parallel to the direction of progress of the electromagnetic waves within the processing vessel by the electromagnetic coil. Thus, low-frequency helical waves from the electromagnetic waves are propagated through the plasma by the action of this magnetic field, and, during this time, the electrons within the plasm are accelerated to increase the density of the plasma. At the same time, radio-frequency electric power is supplied via the blocking capacitor by the radio-frequency power source of the holder device, so that the holder device becomes self-biased as described above, and the potential difference with respect to the plasma's potential causes argon ions to impact against the semiconductor wafer so that the semiconductor wafer is etched thereby. Since this plasma treatment can be implemented by causing the generation of helical waves within even a comparatively weak magnetic field, it is possible to soften the effects of the magnetic field in comparison with electronic cyclotron resonance (ECR) plasma treatment that uses a strong magnetic field.

A high-density plasma of the order of 10.sup.11 cm.sup.-3 can be obtained with the above described prior art plasma treatment apparatus that uses inductively coupled radio-frequency waves, but if an attempt is made to increase the power supplied to the antenna to further increase the density of the plasma (for example, if the supplied power is increased to 600 W), the plasma density does become approximately uniform within a central portion within a radius of 50 mm from the center of the processing vessel, but as the power is increased further to 800 W and then 1 kW to increase the plasma density even further, as will be shown later in a graph, the plasma density in the central portion drops, there is an increasing tendency for the plasma density to increase with distance from the center in a certain direction, and thus it becomes more difficult to obtain an uniform high-density plasma as the plasma density increases, raising concern that it is becoming more difficult to implement uniform plasma treatment. This tendency becomes more and more obvious as the diameters of semiconductor wafers increase, and it is becoming a big problem concerning plasma treatment as diameters become increasingly larger in the future.

If the plasma densities obtained by plasma treatment apparatuses are up to the order of 10.sup.11 cm.sup.-3, a self-bias potential of several tens of volts to several hundred volts can be obtained by just the application of power of several tens of Watts to the holder device, but when it comes to the above described higher plasma densities of the order or 10.sup.11 cm.sup.-3 or higher, conventional radio-frequency bias circuitry cannot achieve a self-bias potential of about several tens of watts, even if power is supplied at several hundred watts, so that concern has been raised that it has become impossible to implement such plasma treatment.

Further, when a prior art helical wave plasma treatment apparatus is used, plasma treatment can be implemented even with an ECR plasma in a weak magnetic field. However, if, for example, the magnetic field is further weakened in order to lessen the effects of the magnetic field, etching rates gradually decrease with distance from the antenna, etching at the central portion of the semiconductor wafer is delayed the most, and thus a problem occurs in that it becomes difficult to implement uniform etching (plasma treatment) over the entire surface. In general, trends such as the recent increase in diameter of semiconductor wafers are becoming more obvious, and film thicknesses have also become even thinner. Therefore it is becoming impossible to use a prior art helicon wave plasma treatment apparatus to treat objects under weak magnetic field conditions.

If etching of a semiconductor wafer is done using a high-density plasma with a prior art helical wave plasma treatment apparatus, there is a problem in that only the peripheral parts of the semiconductor wafer that are outside a high-density region of the plasma are etched, virtually no etching occurs in the central portion within this region, and also there is a problem that the etching rate is not constant over all positions on of the semiconductor wafer.

SUMMARY OF THE INVENTION

The present invention was devised in order to solve the above described problems and has as its object the provision of a plasma treatment apparatus that creates a uniform high-density plasma wherein the plasma density does not drop at the central portion of the processing vessel, to enable uniform, rapid processing of a large-diameter object.

A further object of the present invention is to provide a plasma treatment apparatus that causes the generation of helical waves under weak magnetic field conditions, to create a uniform high-density plasma throughout and thus enable uniform, rapid processing of a large-diameter object.

A yet further object of the present invention is to provide a plasma treatment apparatus that can sufficiently ensure and maintain a self-bias potential at a low level of supplied power, even in a high-density plasma on the order of 10.sup.11 cm.sup.-3.

A still further object of the present invention is to provide a plasma treatment apparatus that can perform uniform, rapid treatment throughout, even for the treatment of a large-diameter object, by using a helical wave plasma.

To achieve the above objectives, the present invention provides a plasma treatment apparatus comprising: a processing vessel capable of being maintained at a predetermined degree of vacuum; gas supply means for supplying a process gas into the processing vessel; gas exhaust means for exhausting gases from within the processing vessel after treatment is completed; plasma generation means provided in the processing vessel, to generate radio-frequency waves within the processing vessel to cause generation of a plasma in the process gas; and holder means provided in the processing vessel to hold an object to be subjected to a predetermined treatment by the plasma. The gas supply means comprises: a plurality of first gas supply means arranged equidistantly in the peripheral direction around the processing vessel; and second gas supply means arranged at the center of an upper surface of the processing vessel. The gas exhaust means comprises a plurality of gas exhaust means arranged equidistantly in the peripheral direction around the processing vessel.

In this plasma treatment apparatus, the holder means is provided with a capacitor that maintains a bias potential, and this capacitor has a capacitance that is at least 10 times that of an ion sheath formed in the vicinity of the holder means.

The present invention also provides a plasma treatment apparatus comprising: a processing vessel capable of being maintained at a predetermined degree of vacuum; gas supply means for supplying a process gas into the processing vessel; gas exhaust means for exhausting gases from within the processing vessel after treatment is completed; an application portion provided in an upper portion of the processing vessel; helical wave plasma generation means provided surrounding the application portion and causing the generation of a helical wave plasma within the processing vessel; holder means provided within the processing vessel to hold an object to be subjected to a predetermined treatment by the helical wave plasma; and second plasma generation means provided above the application portion, to generate radio-frequency waves toward the interior of the application portion and thus increase the density of the plasma.

The present invention still further provides a plasma treatment apparatus comprising: a processing vessel capable of being maintained at a predetermined degree of vacuum; gas supply means for supplying a process gas into the processing vessel; gas exhaust means for exhausting gases from within the processing vessel after treatment is completed; holder means for holding an object in the treatment vessel; and helical plasma generation means provided in a side portion of the processing vessel in such a manner as to cause a helical wave plasma to be generated within the process gas, in a flat plate-shaped region interposed within a gap with respect to an object held on the holder means. The helical plasma generation means comprises: an electromagnetic wave generation means for generating electromagnetic waves parallel to the object on the holder means; and a rectangular magnetic field shaping means for shaping a rectangular magnetic field in the same direction as the electromagnetic waves from the electromagnetic wave generation means, to cause the generation of a helical wave plasma from the electromagnetic waves.

Preferred embodiments of the present invention will be described in more detail below, with reference to the accompanying drawings.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a plan view of a radio-frequency inductively coupled type of plasma treatment apparatus in accordance with one embodiment of the present invention;

FIG. 2 is a vertical section through the plasma treatment apparatus of FIG. 1;

FIG. 3 is a graph evaluating the effects on plasma density within the processing vessel of using different methods to supply the process gas from a first gas supply portion of the plasma treatment apparatus of FIG. 1;

FIG. 4 is a graph of the relationship between the electric power applied to the holder device of the plasma treatment apparatus of FIG. 1 and the self-bias potential;

FIG. 5 is a vertical section through a helical wave plasma treatment apparatus of another embodiment of the present invention;

FIG. 6 is a graph comparing etching rates of the plasma treatment apparatus of FIG. 5 and a prior art plasma treatment apparatus of the same type;

FIG. 7 is a sectional view of a central portion of a plasma treatment apparatus of a parallel flat-electrode configuration;

FIG. 8 is a partial cross-sectional view of an upper electrode shown in FIG. 7, with the right half in section;

FIG. 9 is a graph showing the relationship between position in the radial direction on a semiconductor wafer and electron density in the plasma at that position, when the power applied to the antenna of a prior art radio-frequency inductively coupled type of plasma treatment apparatus is varied;

FIG. 10 is a graph of the relationship between electric power applied to a holder device and self-bias potential, in a prior art plasma treatment apparatus;

FIG. 11 is a vertical sectional view through a helical wave plasma treatment apparatus in accordance with a third embodiment of the present invention; and

FIG. 12 is a graph of the relationship between distance from the center of the semiconductor wafer and etching rate during processing using the plasma treatment apparatus of FIG. 11.

DESCRIPTION OF THE PREFERRED EMBODIMENTS

An embodiment of a radio-frequency inductively coupled type of plasma treatment apparatus in accordance with the present invention is shown in FIGS. 1 and 2. As shown in the plan view of FIG. 1, this plasma treatment apparatus has a processing vessel 3, with first gas supply pipes 1A, 1B, 1C, and 1D for supplying a process gas G into the processing vessel 3 being provided in a radial fashion at constant peripheral spacing at a plurality of places (four in the example shown in these figures) around the outer periphery of the processing vessel 3. As can be seen from FIG. 2, the first gas supply pipes 1A to 1D are provided toward the upper end of the processing vessel 3. Gas exhaust structures, e.g. pipes 2 for exhausting gases from the interior of the processing vessel 3 are also provided at constant peripheral spacing at a plurality of places (four in the example shown in these figures) around the outer periphery of the processing vessel 3. As shown in FIG. 2, the gas exhaust pipes 2 are provided toward the lower end of the processing vessel 3, and the positions of the gas exhaust pipes 2 in the peripheral direction around the processing vessel 3 are such that each one is between neighboring first gas supply pipes 1A, 1B, 1C, and 1D, as shown in FIG. 1.

A plasma generation device 4 for generating radio-frequency within the processing vessel 3 to cause the generation of a high-density plasma in the process gas G is provided above the processing vessel 3. A known holder device 5 for holding on the upper surface thereof a semiconductor wafer W as an object to be treated is provided in the interior of the processing vessel 3. The holder device 5 is connected to a radio-frequency power source 7 with a blocking capacitor 6 therebetween, in such a manner that a radio-frequency voltage is applied to the holder device 5. A coolant supply pipe 8A that supplies a coolant into the interior of the holder device 5 to cool it in a known manner is connected to the holder device 5, and a coolant exhaust pipe 8B for exhausting the coolant after this cooling is also provided.

The plasma generation device 4 has a one-turn loop antenna 4A of a configuration such that it generates radio-frequency waves in the process gas G within the processing vessel 3 by the action of a matching circuit 9B and a radio-frequency power source 9C of known types that are connected to the antenna, and the electromagnetic energy of these radio-frequency waves turn the process gas G into a plasma to generate a high-density plasma of the order of 10.sup.11 cm.sup.-3. All of the first gas supply pipes 1A to 1D, gas exhaust pipes 2, processing vessel 3, and holder device 5 are formed of an electrically conductive material such as stainless steel, a central portion 3A of an upper surface of the processing vessel 3 at which the loop antenna 4A is arranged is formed of an insulating material such as quartz or alumina, and a peripheral portion 3B thereof is formed of the same electrically conductive material as the processing vessel 3.

In addition to the first gas supply pipes 1A to 1D, a second gas supply pipe 1E is arranged at a place in the center of the upper surface of the processing vessel 3 as another gas supply means, so that process gas G can be supplied uniformly within the processing vessel 3 by this second gas supply pipe 1E and the radially arranged first gas supply pipes 1A to 1D. The gas exhaust pipes 2 are arranged equidistantly along the periphery of the lower peripheral surface of the processing vessel 3, so that the product gases within the processing vessel 3 after the treatment can be exhausted through all these gas exhaust pipes 2 to the exterior without any unevenness.

The present inventors measured the distribution of electron density Ne generated within the processing vessel 3 when the process gas G was supplied from the gas supply pipes 1A to 1E by different methods. The results of these measurements are shown in FIG. 3. For example, a distribution curve A in this figure was obtained as the results of supplying process gas G by opening only the first gas supply pipe 1A, leaving all of the other first gas supply pipes 1B to 1D and the second gas supply pipe 1E closed, then measuring the electron density Ne in the diametric direction across the processing vessel 3 from the first gas supply pipe 1C to the first gas supply pipe 1A. It can be seen from curve A that the electron density Ne is at a maximum in the vicinity of the first gas supply pipe 1A and gradually decreases with distance from the first gas supply pipe 1A.

The first gas supply pipe 1B was then opened alone, process gas G was supplied with all of the other first gas supply pipes and the second gas supply pipe 1E being closed, and a distribution curve B was obtained as the results of measuring the electron density Ne in the diametric direction across the processing vessel 3 from the first gas supply pipe 1B to the first gas supply pipe 1D. It can be seen from curve B that the electron density Ne is at a maximum in the vicinity of the first gas supply pipe 1B and gradually decreases with distance from the first gas supply pipe 1B, in a similar manner to that described above.

The second gas supply pipe 1E alone was then closed, with all of the first gas supply pipes 1A to 1D being open, and a distribution curve C was obtained as the results of measuring the electron density Ne in the diametric direction across the processing vessel 3 from the first gas supply pipe 1B to the first gas supply pipe 1D. It can be seen from curve C that the electron density Ne is somewhat lower at the periphery than at the central portion of the processing vessel 3, so that a uniform electron density Ne can not be obtained by simply supplying the process gas G radially from positions that are equidistantly spaced around the processing vessel 3.

Next, the process gas G was supplied from all of the gas supply pipes 1A to 1E and a distribution curve D was obtained thereby, from which it can be seen that the electron density Ne within the processing vessel 3 can be made approximately uniform. From the above results, it is clear that supplying the process gas G uniformly from the periphery and upper surface of the processing vessel 3 enables a uniform electron density Ne within the processing vessel 3, which means that a uniform high-density plasma can be achieved. In contrast, if the supply of process gas G is unbalanced, as it is in the radio-frequency inductively-coupled plasma treatment apparatus of the prior art, even if various techniques are devoted to the plasma generation means, the electron density Ne will be lower at the central portion, and rise toward the left side as seen in FIG. 9, so it is clear that there is a limit to the uniformity of the electron density.

The present invention provides uniform supply of the process gas G from around the periphery of the processing vessel 3 by the first gas supply pipes 1A to 1D, and also provides a downward supply of the process gas G from the center of the top surface of the processing vessel 3 by the second gas supply pipe 1E. Therefore, the supply of process gas G from above can compensate in portions where the process gas G supplied from the first gas supply pipes 1A to 1D cannot scatter sufficiently, the concentration of the process gas G within the processing vessel 3 can be rapidly made even, this enables the achievement of a uniform high-density plasma within the processing vessel 3, and thus treatment can be performed over the entire surface of the semiconductor wafer both uniformly and rapidly. In accordance with this embodiment of the present invention, since a one-turn loop antenna 4A is used as the plasma generation device 4, the second gas supply pipe 1E can be mounted in the central portion thereof so that uniform plasma treatment can be implemented without any drop in the plasma density at the center, even with a semiconductor wafer W of a larger diameter as described above.

With the previously described radio-frequency inductively-coupled plasma treatment apparatus of the prior art, a high-density plasma of the order of 10.sup.11 cm.sup.-3 can be obtained, as shown in FIG. 9, but if an attempt is made to obtain an even denser plasma by increasing the power supplied to the antenna 14A (for example, by increasing the power supplied further to 600 W), the plasma density will still be substantially uniform in a central portion within a radius of 50 mm from the center of the processing vessel, as shown in FIG. 9. However, as the supplied power is increased further to 800 W or 1 kW, it can be seen from this graph that the plasma density at the central portion will drop as the plasma density increases, and also the plasma in the leftward portion will tend to increase in particular, so there is the problem that it becomes more difficult to obtain a uniform high-density plasma as the density increases, and thus it is difficult to implement uniform plasma treatment. This tendency becomes more obvious as the diameters of the semiconductor wafers increase, which is making it a big problem for plasma treatment of even larger diameters in the future.

If the plasma density obtained by the plasma treatment apparatus is up to the order of 10.sup.11 cm.sup.-3, the application of several tens of watts of electric power to the holder device 5 will achieve a self-bias potential -Vdc of several tens of volts to several hundred volts, but when the plasma density reaches the above described order of 10.sup.11 cm.sup.31 3, a prior art radio-frequency bias circuit would only be able to achieve a self-bias potential -Vdc of about several tens of volts, even if power of several hundred watts is supplied, and thus there is the problem that plasma treatment becomes impossible. The relationship between supplied power and self-bias potential -Vdc is shown graphically in FIG. 10, and this relationship between the two factors will be described below with reference to this figure. It can be seen from this figure that, if the plasma density is of the order of 10.sup.11 cm.sup.-3, it becomes increasingly difficult to achieve a self-bias potential at the holder device 5, even if the power supplied to the holder device 5 is increased, and when it exceeds 6.6.times.10.sup.11 cm.sup.-3, virtually no self-bias potential is created which is a problem in that treatment of the semiconductor wafer W cannot be done even if a high-density plasma could be obtained by some means. Note that the data shown in FIG. 10 refers to a self-bias potential -Vdc when different electric powers are supplied at 100 kHz when the capacitance of the blocking capacitor 6 is 3000 pF. This self-bias potential -Vdc was measured between the holder device 5 and the blocking capacitor 6.

To solve the above described problem, the capacitance of the blocking capacitor 6 is set to at least 10 times that of the ion sheath between the holder device 5 and the plasma, and is preferably set to at least 50 times that value, even more preferably to at least 100 times. A capacitance of less than 10 times that value raises concern in that it might not be possible to create the self-bias potential -Vdc necessary for plasma treatment, even with a large power for generating the high-density plasma of, for example, 10.sup.11 cm.sup.-3. The relationship between supplied power (at 100 kHz) and self-bias potential -Vdc when the plasma density is varied as a parameter between 1.8 and 6.6.times.10.sup.11 cm.sup.-3, using a 25 000-pF blocking capacitor 6 is shown in FIG. 4. It is clear from this figure that a sufficient self-bias potential -Vdc can be obtained at a low power of several tens of watts when the plasma density is 1.8.times.10.sup.11 cm.sup.-3. As a result of calculating the capacitance of the ion sheath, we have determined that capacitance to be 637 pF. Therefore, the capacitance 25,000 pF of the blocking capacitor 6 is approximately 40 times that of the ion sheath. The capacitance of an ion sheath can be calculated using the following equation for obtaining the thickness of an ion sheath when general-purpose flat-plate electrodes are used:

0.97=(yp-1/2).sup.3/2

where: yp=eVp/.kappa.Te and .eta.=d/.lambda.D, Vp is the electrode potential measured in the negative direction and based on the plasma potential, and .lambda.D=(E.kappa.Te/Ne e.sup.2).sup.1/2 is the length of the device. Note that the capacitance of a prior art blocking capacitor is usually about 3000 pF.

If, for example, the above equation is used to calculate the capacitance of an ion sheath in argon for an electrode area (equivalent to the area of the upper surface of the holder device 5) of 314 cm.sup.2 (for 8" wafers), a value of 3.85 nF is obtained. Note that the electron temperature Te is 3 eV. In this case, if the capacitance of the blocking capacitor 6 is set to 100 times that of the ion sheath, 385 nF, a sufficient self-bias potential can be ensured and maintained, even when the plasma density is of the order of 10.sup.11 cm.sup.-3.