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Semiconductor device having a thin film transistor and thin film diode    
United States Patent5589694   
Link to this pagehttp://www.wikipatents.com/5589694.html
Inventor(s)Takayama; Toru (Kanagawa, JP); Takemura; Yasuhiko (Atsugi, JP)
AbstractAmorphous silicon in impurity regions (source and drain regions or N-type or p-type regions) of TFT and TFD are crystallized and activated to lower electric resistance, by depositing film having a catalyst element such as nickel (Ni), iron (Fe), cobalt (Co) or platinum (Pt) on or beneath an amorphous silicon film, or introducing such a catalyst element into the amorphous silicon film by ion implantation and subsequently crystallizing the same by applying heat annealing at an appropriate temperature.
   














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Drawing from US Patent 5589694
Semiconductor device having a thin film transistor and thin film diode - US Patent 5589694 Drawing
Semiconductor device having a thin film transistor and thin film diode
Inventor     Takayama; Toru (Kanagawa, JP); Takemura; Yasuhiko (Atsugi, JP)
Owner/Assignee     Semiconductor Energy Laboratory Co., Ltd. (Kanagawa-ken, JP)
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Publication Date     December 31, 1996
Application Number     08/411,972
PAIR File History     Application Data   Transaction History
Image File Wrapper   Patent Term   Fees
Litigation
Filing Date     March 28, 1995
US Classification     257/67 257/69 257/350 257/354 257/359 257/E21.352 257/E21.413 257/E21.703
Int'l Classification     H01L 029/78
Examiner     Crane; Sara W.
Assistant Examiner     Williams; Alexander Oscar
Attorney/Law Firm     PC, Ferguson, Jr.; Gerald J. Sixbey, Friedman, Leedom & Ferguson, Costellia; Jeffrey L. ,
Address
Parent Case     This is a divisional application of Ser. No. 08/216,107, filed Mar. 21, 1994, now U.S. Pat. No. 5,501,989.
Priority Data     Mar 22, 1993[JP]5-86744 Mar 22, 1993[JP]5-86745 Mar 22, 1993[JP]5-86746 Mar 22, 1993[JP]5-86747
USPTO Field of Search     257/66 257/67 257/68 257/69 257/70 257/71 257/72 257/75 257/76 257/78 257/350 257/354 257/359
Patent Tags     semiconductor thin film transistor thin film diode
   
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5488000
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Jan,1996

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What is claimed is:

1. A semiconductor circuit having at least one thin film transistor and at least one thin film diode formed on a substrate, wherein

a semiconductor film that forms an active region (channel-forming region) of said thin film transistor comprises the same layer of a semiconductor film as that of an intrinsic region (I-layer) of said thin film diode, and

a concentration of a catalyst element for promoting crystallization of semiconductor contained in source and drain regions of said thin film transistor is higher by more than one digit than that in the active region of said thin film transistor.

2. A semiconductor circuit as defined in claim 1, wherein the concentration of the catalyst element in the source and the drain regions is 1.times.10.sup.17 cm.sup.-3 or higher and less than 1.times.10.sup.20 cm.sup.-3.

3. A semiconductor circuit as defined in claim 2, wherein the concentration of the catalyst element is defined by a minimum value obtained by secondary ion mass spectroscopy.

4. A semiconductor circuit as defined in claim 1, wherein the catalyst element is at least one of nickel, iron, cobalt and platinum.

5. A semiconductor circuit having at least one thin film transistor and at least one thin film diode formed on a substrate, wherein

source and drain regions of said thin film transistor, and an n-type region and a p-type region of said thin film diode substantially comprises crystalline semiconductor, and an active region (channel-forming region) of said thin film transistor and an intrinsic region (I-layer) of said thin film diode substantially comprise amorphous semiconductor.

6. A semiconductor circuit as defined in claim 5, wherein a semiconductor film that forms the active region of the thin film transistor comprises the same layer of a semiconductor film as that of the intrinsic region of said thin film diode.

7. A semiconductor circuit having at least one thin film transistor and at least one thin film diode formed on a substrate, wherein

a semiconductor film that forms an active region (channel-forming region) of said thin film transistor comprises the same layer of a semiconductor film as that of an n-type region, a p-type region and an intrinsic region (I-layer) of said thin film diode, and

a concentration of a catalyst element for promoting crystallization of semiconductor contained in a source region and a drain region of the thin film transistor is at 1.times.10.sup.17 cm.sup.-3 or higher and less than 2.times.10.sup.20 cm.sup.-3.

8. A semiconductor circuit as defined in claim 7, wherein the concentration of the catalyst element is defined by a minimum value obtained by secondary ion mass spectroscopy.

9. A semiconductor circuit as defined in claim 7, wherein the catalyst element is at least one of nickel, iron, cobalt and platinum.

10. A semiconductor circuit having at least one thin film transistor and at least one thin film diode formed on a substrate, wherein

a source region and a drain region of said thin film transistor substantially comprise crystalline semiconductor and an n-type region and a p-type region of said thin film diode substantially comprise amorphous semiconductor.

11. A semiconductor circuit as defined in claim 10, wherein a semiconductor film that forms an active region (channel-forming region) of the thin film transistor comprises the same layer of a semiconductor film as that of the n-type region, the p-type region and an intrinsic region (I-layer) of said thin film diode.

12. A semiconductor circuit having at least one thin film transistor and at least one thin film diode formed on a substrate, wherein

a semiconductor film that forms an active region (channel-forming region) of said thin film transistor comprises the same layer of a semiconductor film as that for an n-type region, a p-type region and an intrinsic region (I-layer) of said thin film diode, and

a concentration of a catalyst element for promoting crystallization of semiconductor contained in the active region of the thin film transistor is at 1.times.10.sup.17 cm.sup.-3 or higher and less than 2.times.10.sup.20 cm.sup.-3.

13. A semiconductor circuit as defined in claim 12, wherein the concentration of the catalyst element is defined by a minimum value obtained by secondary ion mass spectroscopy.

14. A semiconductor circuit as defined in claim 12, wherein the catalyst element is at least one of nickel, iron, cobalt and platinum.

15. A semiconductor circuit having at least one thin film transistor and at least one thin film diode formed on a substrate, wherein

an active region of said thin film transistor substantially comprises crystalline semiconductor and

an intrinsic region of said thin film diode substantially comprises amorphous semiconductor.

16. A semiconductor circuit as defined in claim 15, wherein a semiconductor film that forms the active region of the thin film transistor comprises the same layer of a semiconductor film as that of an n-type region, a p-type region and the intrinsic region of said thin film diode.

17. A semiconductor circuit having at least one thin film transistor and at least one thin film diode formed on a substrate, wherein

a semiconductor film that forms an active region (channel-forming region) of said thin film transistor is the same layer of a semiconductor film as that of an intrinsic region (I-layer) of said thin film diode, and

a concentration of a catalyst element for promoting crystallization of semiconductor contained in the active region of the thin film transistor and the intrinsic region of said thin film diode is at 1.times.10.sup.17 cm.sup.-3 or higher and less than 2.times.10.sup.20 cm.sup.-3.

18. A semiconductor circuit as defined in claim 17, wherein the concentration of the catalyst element is defined by a minimum value obtained by secondary ion mass spectroscopy.

19. A semiconductor circuit as defined in claim 17, wherein the catalyst element is at least one of nickel, iron, cobalt and platinum.

20. A semiconductor circuit as defined in claim 17, wherein an amorphous semiconductor film is disposed in an intimate contact with the intrinsic region of the thin film diode.

21. A semiconductor circuit as defined in claim 20, wherein an element for changing a wavelength dependence of photosensitivity is added to the amorphous semiconductor film.

22. A semiconductor circuit having at least one thin film transistor and at least one thin film diode formed on a substrate, wherein

a width (channel length) of an active region (channel-forming region) of said thin film transistor is shorter than a width of an intrinsic region of said thin film diode,

the active region of said thin film transistor substantially comprises crystalline semiconductor and

at least a portion of the intrinsic region of said thin film diode comprises amorphous semiconductor.

23. A semiconductor circuit as defined in claim 22, wherein a semiconductor film that forms the active region of the thin film transistor is the same layer of a semiconductor film as that of the intrinsic region (I-layer) of the thin film diode.

24. A semiconductor device having at least one thin film diode formed on a substrate, wherein

said thin film diode includes an amorphous semiconductor film at least a portion of which is crystallized by a catalyst element.

25. A semiconductor device as defined in claim 24, wherein an n-type region and a p-type region of the thin film diode are formed in an identical amorphous semiconductor film and have a planer structure.
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BACKGROUND OF THE INVENTION

1. Field of the Invention

The present invention relates to a semiconductor device/circuit having at least partially crystallized semiconductor layer and a manufacturing method thereof. The semiconductor device/circuit manufactured according to the present invention is formed on any of insulation substrates such as glass substrates and semiconductor substrates such as single crystal silicon substrates. In particular, the present invention relates to a semiconductor device/circuit having a thin film transistor (TFT) and/or a thin film diode (TFD) (for example, image sensor) manufactured by way of crystallization (activation) through heat annealing.

2. Description of the Prior Art

Thin film semiconductor devices such as TFT and TFD are classified into amorphous devices and crystalline devices depending on the crystalline structures of the semiconductor materials used. Amorphous silicon can be fabricated at a low temperature and shows excellent mass productivity. However, it is inferior to crystalline silicon in view of physical properties such as field effect mobility or conductivity. So it has been demanded for crystalline semiconductor devices in order to obtain hiEh speed characteristics. On the other hand, it has been known that amorphous semiconductors are usable, for example, to light sensors since they generally show large change in the photoconductivity. It has been proposed recently a circuit for driving a light sensor using an amorphous silicon diode or a thin film diode by a thin film transistor using crystalline silicon capable of high speed operation ( for example, integrated image sensor circuit).

FIGS. 1A-1E show an example for the steps of fabricating a circuit comprising a combination of an amorphous silicon diode and a crystalline silicon TFT in the prior art. An underlying insulation film 51 is formed on a glass substrate 50, over which an amorphous silicon film is formed and crystallized by applying long time annealing at a temperature higher than 600.degree. C. Then, it is patterned to obtain an island-like silicon region 52. Then, a gate insulation film 53 is formed and, further, gate electrodes 54N and 54P are formed (refer to FIG. 1A).

Then, an N-type impurity region 55N and a p-type impurity region 55P are formed by using known CMOS fabrication technique. In this impurity introduction step, an impurity element is introduced into a semiconductor layer with a gate electrode as a mask in a self-aligning manner. After the implantation of impurities, the impurities are activated by laser annealing, heat annealing or like other means (refer to FIG. 1B).

Then, a first interlayer insulator 58 is formed through which contact holes are formed, thereby forming electrode/wiring 57a, 57b, 57c for source and drain of TFT, and an electrode 57d for an amorphous silicon diode (FIG. 1C).

Then, p-, I- (intrinsic) and N-type amorphous silicon films 58P, 58I and 58N are successively laminated, which are then patterned to form a diode junction portion (FIG. 1D).

Finally, a second interlayer insulator 59 is formed through which contact holes are formed thereby forming an electrode 60 of the amorphous silicon diode to complete a circuit (FIG. 1E).

In the prior art method requiring such procedures, it is necessary to form silicon films 52, 58I and the interlayer insulators 56, 59 each by two layers, which requires film formation for long time and, in addition, the N-type layer 58N and the p-type layer 58P have to be formed. Therefore, it involves a problem that the throughput is reduced. Further, a plasma CVD or vacuum CVD process used for forming such films, takes much dead time for the maintenance of the apparatus and the presence of such additional step further reduces the throughput.

Furthermore, since crystallization of the silicon film used in the crystalline silicon TFT also requires a temperature higher than 600.degree. C. and needs a time as much as 24 hours or longer for crystallization, many facilities for crystallization apparatus are required in actual mass production, which results in enormous installation cost.

SUMMARY OF THE INVENTION

An object of the present invention is to provide a technique capable of overcoming the foregoing problems by simultaneously forming a semiconductor layer to form a TFT and a TFD using only a single interlayer insulator, as well as crystallizing the silicon film at a temperature lower than 800.degree. C. and in such a short period of time as causing no substantial problems.

Another object of the present invention is to provide a method capable of simplifying production processes and saving the number of film-forming steps.

A further object of the present invention is to improve crystallization and activation of amorphous silicon, in particular, in an impurity region of TFT and TFD (source, drain or n-type or p-type region), thereby lowering the resistivity.

A further object of the present invention is to lower the resistivity in an impurity region by annealing at a lower temperature and for a shorter period of time.

A further object of the present invention is to obtain crystalline silicon by low temperature and short time annealing and then using the same to TFT.

A further object of the present invention is to provide a semiconductor circuit in which source, drain of TFT and N-type and p-type regions of TFD are constituted with crystalline silicon, while an active region (channel forming region) of TFT and an I-layer of TFD is constituted with amorphous silicon, as well as a manufacturing method therefor.

A further object of the present invention is to provide a semiconductor circuit in which the source, drain regions of TFT are constituted with crystalline silicon, while an active region of TFT and TFD are constituted with amorphous silicon, as well as a manufacturing method thereof.

A further object of the present invention is to provide a semiconductor circuit, in which an active region of a TFT is constituted with crystalline silicon, while an intrinsic region of a TFD is constituted with amorphous silicon, as well as manufacturing method therefor.

A further object of the present invention is to provide a semiconductor device/circuit in which TFT and/or TFD are formed from one semiconductor film, as well as a manufacturing method thereof.

A further object of the present invention is to provide a method of manufacturing a semiconductor device/circuit capable of attaining a satisfactory light sensitivity.

A further object of the present invention is to provide a method of manufacturing a semiconductor device/circuit capable of crystallizing an active region not introduced with a catalyst element by laterally proceeding crystallization.

A further object of the present invention is to provide a method of manufacturing a semiconductor device/circuit capable of optionally fabricating a crystalline semiconductor region, and an amorphous semiconductor region.

A further object of the present invention is to provide a semiconductor device/circuit containing TFT of extremely high mobility.

The primary feature of the present invention is to add a catalytic element to a selected portion of a semiconductor film for reducing the crystallization temperature in the selected portion and to subject the semiconductor film to a heat annealing at such a temperature which is enough high to crystallize the impurity added portion but not enough high to crystallize the remaining portion of the semiconductor film, thereby, crystallizing only the selected portion of the semiconductor film.

According to the study of the present inventor, it has been found that one of most major problems of the amorphous silicon TFT is caused by that the conductivity of source, drain regions is remarkably low. It has been found that a satisfactory operation for driving a TFD is obtainable if the conductivity of the source, drain regions of a TFT is comparable with that of crystalline silicon. It has also been found that the problem in the amorphous silicon TFD is attributable to that the conductivity of the n-type and p-type regions is low.

The foregoing problems can be solved by proceeding crystallization and activation thereby lowering the resistivity of amorphous silicon, particularly, in impurity regions (source, drain regions or n-type and p-type regions), of TFT and/or TFD. As a result of the studies conducted by the present inventor, it has been found that crystallization can be promoted by adding a trace amount of a catalyst material to a silicon film in a substantially amorphous state thereby enabling to lower the crystallization temperature and shorten the crystallization time. In the present invention, the amorphous state and the substantially amorphous state include a so-called amorphous state and an extremely degraded crystalline state if it is present. As the catalyst element, nickel (Ni), iron (Fe), cobalt (Co) or platinum (Pt) is suitable. Actually, crystallization can be attained by forming a film, particles, cluster or the like containing such a catalyst in the form of elemental metal or a compound such as silicide in an intimate contact on or below an amorphous silicon film or introducing such a catalyst element into the amorphous silicon film by an ion implantation or like other method and, subsequently, applying heat annealing at an appropriate temperature, typically, at a temperature below 580.degree. C.

As a matter of fact, there is such a relation that the crystallization time is shorter as the annealing temperature is higher. Further, there is also a relation that the crystallization temperature is lower and the crystallization time is shorter as the concentration of the catalyst element is greater. According to the study of the present inventor, it has been found that at least one of the elements has to be present at a concentration of higher than 1.times.10.sup.17 cm.sup.-3, preferably 5.times.10.sup.18 cm.sup.-3. Also, depending upon the annealing temperature and period, the catalytic element diffuses by 10-20 .mu.m and the crystallization proceeds in a lateral direction.

On the other hand, since most of the catalyst materials described above is not preferred for an electrical characteristics of silicon, it is desirable that the concentration is as low as possible. According to the study of the present inventor, it is desired that the concentration of the catalyst material does not exceed 2.times.10.sup.20 cm.sup.-3, preferably, 1.times.10.sup.20 cm.sup.-3 in total in order to attain sufficient reliability and characteristic, particularly, when it is utilized as an active region. It has been found on the other hand that there is no substantial problem in the source or drain region if the catalyst is present relatively in a large amount. Particularly, it has been found that the concentration of the catalyst element contained in the active region (channel-forming region) of TFT is desirably smaller by more than one digit as that in the source, drain regions in the first feature of the present invention. In the same way, it is also desired in TFD that the concentration of the catalyst element contained in the intrinsic region (I-layer) is lower by more than one digit than that in the impurity region (n-type or p-type region).

Further, it should be noted that the amorphous state can be maintained without proceeding crystallization at all in such a region that the catalyst material is not present. For instance, crystallization of amorphous silicon not having such a catalyst material, usually starts at a temperature higher than 600.degree. C. but it does not proceed at all at a temperature lower than 580.degree. C. However, since hydrogen necessary for neutralizing dangling bonds in amorphous silicon is dissociated, in an atmosphere at a temperature higher than 300.degree. C., it is desirable that annealing is applied in a hydrogen atmosphere in order to attain a satisfactory light sensitivity.

Further, such a catalyst element has an effect of crystallizing a peripheral area by diffusion during annealing. For instance, when annealing is applied at 550.degree. C. for four hours, the catalyst element diffuses to the periphery as far as by 10-20 .mu.m to cause crystallization therein. Accordingly, if the width of the gate electrode of TFT is less than 20 .mu.m, preferably, less than 10 .mu.m, crystallization proceeds laterally, and an active region (channel-forming region) not introduced with the catalyst element can also be crystallized by introducing the catalyst element into the source, drain regions before or after introduction of the n-type or p-type impurities and then applying annealing. Further, in this method, the concentration of the catalyst element in the active region is generally low as compared with the concentration of the catalyst element in the source, drain regions. The lateral crystallization depends on the temperature and the time of annealing and the concentration of the catalyst element. Accordingly, the crystalline silicon region and the amorphous silicon region can be prepared optionally by optimizing them.

For instance, when two kinds of TFT gate electrodes having, respectively, 5 .mu.m and the 30 .mu.m width are provided, it is possible to prepare a crystalline silicon TFT from the 5 .mu.m width electrode, while an amorphous silicon TFT from the 30 .mu.m width electrode.

Taking notice on the effect of the catalyst element and by utilizing the same, the present inventor has succeeded in lowering the resistivity in the impurity region by low temperature and short time annealing thereby obtaining crystalline silicon and using it for TFT.

In the first feature of the present invention, only the impurity region is crystallized and activated by taking an advantageous feature of the crystallization due to the catalyst material while the active region of TFT and the intrinsic region of TFD are left as they are in the amorphous state, thereby improving the function of the device. The present inventor has made a further study and has found a method capable of simplifying the process, that is, saving the number of film-forming steps as other object described above. The outline of the method is shown below.

(1) Formation of an amorphous semiconductor (silicon) film

(2) Formation of an insulation film (gate insulation film)

(8) Formation of a TFT gate electrode and a mask material for a TFD

(4) Introduction of doping impurity (for example by ion implantation or ion doping method)

(4') Formation or catalyst element-containing material on a semiconductor (silicon) film

(5) Activation of doped impurity (possible at a temperature lower than 600.degree. C. and within 8 hours)

(6) Formation of an interlayer insulator

(7) Formation of source and drain electrodes of TFT, or alternatively.

(1) Formation of an amorphous semiconductor (silicon) film

(2) Formation of an insulation film (gate insulation film)

(3) Formation of a TFT gate electrode and a mask material for a TFD

(4) Introduction of doping impurity (for example, by ion implantation or ion doping method)

(4') Introduction of catalyst element (for example by ion implantation or ion doping method)

(5) Activation of doped impurity (possible at a temperature lower than 600.degree. C. and within 8 hours)

(6) Formation of an interlayer insulator

(7) Formation of source and drain electrodes of TFT.

In the second feature of the present invention, only the impurity region of TFT is crystallized and activated by taking an advantageous feature of the crystallization due to the catalyst material while TFD is left as it is in the amorphous state thereby improving the function of the device. The present inventor has made a further study and has found a method capable of simplifying the process, that is, saving the number of film-forming steps as other object described above. The outline of the method is shown below.

(1) Formation of an amorphous semiconductor (silicon) film

(2) Formation of an insulation film (gate insulation film)

(3) Formation of a TFT gate electrode and a mask material for a TFD

(4) Introduction of doping impurity (for example, by ion implantation or ion doping method)

(4') Formation of catalyst element-containing material on the semiconductor (silicon) film in the TFT region

(5) Activation of doped impurity (possible at a temperature lower than 600.degree. C. and within 8 hours)

(6) Formation of an interlayer insulator

(7) Formation of source and drain electrodes of TFT, or, alternatively,

(1) Formation of an amorphous semiconductor (silicon) film

(2) Formation of an insulation film (gate insulation film)

(3) Formation of a TFT gate electrode and a mask material for a TFD

(4) Introduction of doping impurity (for example, by ion implantation or ion doping method)

(4') Introduction of catalyst element into the semiconductor (silicon) film in the TFT region (for example, by ion implantation or ion doping method)

(5) Activation of doped impurity (possible at a temperature lower than 600.degree. C. and within 8 hours)

(6) Formation of an interlayer insulator

(7) Formation of source and drain electrodes of TFT.

In the third feature of the present invention, only the TFT is crystallized and activated by taking an advantageous feature of crystallization due to the catalyst material while TFD is left as it is in the amorphous state thereby improving the function of the device. The present inventor has made a further study and found a method capable of simplifying the process, that is, saving the number of film-forming steps as other object described above. The outline of the method is shown below.

(1) Formation of an amorphous semiconductor (silicon) film

(1') Formation of a catalyst element-containing material on or in contact with a semiconductor (silicon) film in the TFT region

(2) Formation of an insulation film (gate insulation film)

(3) Formation of a TFT gate electrode and a mask material for a TFD

(4) Introduction of doping impurity (for example, by ion implantation or ion doping method)

(5) Activation of doped impurity (possible at a temperature lower than 600.degree. C. and within 8 hours)

(8) Formation of an interlayer insulator

(7) Formation of source and drain electrodes of TFT or, alternatively,

(1) Formation of an amorphous semiconductor (silicon) film

(1') Introduction of a catalyst element into the semiconductor (silicon) film in the TFT region (for example, by ion implantation or ion doping method)

(2) Formation of an insulation film (gate insulation film)

(3) Formation of a TFT gate electrode and a mask material for a TFD

(4) Introduction of doping impurity (for example, by ion implantation or ion doping method)

(5) Activation of doped impurity (possible at a temperature lower than 600.degree. C. and within 8 hours)

(6) Formation of an interlayer insulator

(7) Formation of source and drain electrodes of TFT.

In the fourth feature of the present invention, the present inventor has found a method capable of simplifying the process, that is, saving the number of film-forming steps as the object described above by crystallizing and activating the impurity regions and the active region of TFT and the intrinsic region of TFD at a temperature lower than that in the prior art. The outline is shown below.

(1) Formation of an amorphous semiconductor (silicon) film

(1') Introduction of a catalyst element (for example, by ion implantation or ion doping method) (catalyst element-containing material in the form of a film may be provided on a silicon film)

(2) Formation of an insulation film (gate insulation film)

(3) Formation of a TFT gate electrode and a mask material for a TFD

(4) Introduction of doping impurity (for example, by ion implantation or ion doping method)

(5) Activation of doped impurity (possible at a temperature lower than 600.degree. C. and within 8 hours)

(6) Formation of an interlayer insulator

(7) Formation of source and drain electrodes of TFT or, alternatively,

(1) Formation of an amorphous semiconductor (silicon) film

(2) Formation of an insulation film (gate insulation film)

(3) Formation of a TFT gate electrode and a TFD mask material

(4) Introduction of doping impurity (for example, by ion implantation or ion doping method)

(4') Introduction of a catalyst element (for example, by ion implantation or ion doping method) (catalyst element-containing material in the form of a film may be provided on a silicon film)

(5) Activation of doped impurity (possible at a temperature lower than 600.degree. C. and within 8 hours)

(8) Formation of an interlayer insulator

(7) Formation of source and drain electrodes of TFT.

In the steps described above, the sequence for the steps of introducing the doping impurity and the catalyst element conducted one after the other (steps (4) and (4') in the first and the second features and the steps (4) and (4') in the latter alternative steps in the fourth feature) can be reversed. For strictly controlling the concentration of the catalyst element, the ion implantation or like other means is desirable for the step of introducing the catalyst element. Since the catalyst element is present, the annealing temperature lower than 600.degree. C., typically, lower than 550.degree. C. is sufficient for crystallization and activation, as well as the annealing time within 8 hours, typically, within 4 hours is sufficient. In particular, in a case where the catalyst element is distributed homogeneously by the ion implantation or ion doping method, crystallization proceeded extremely readily.

In the present invention, if a gate electrode is present on an active region or a mask material is present on an intrinsic region, the catalyst element is not brought into intimate contact with or implanted into the active region directly in the step for introducing the catalyst element (such as step (4') in the first and the second features of the invention). Accordingly, characteristics of the active region and the intrinsic region are not deteriorated.

Further, if annealing is applied under appropriate conditions for temperature and time, crystallization proceeds from the source, drain regions and the active region also becomes crystalline silicon. As a result, TFT of extremely high mobility can be obtained.

Referring briefly to the structure of TFD in the present invention, the TFD in the prior art has a laminate structure, whereas the present invention has a feature of a planar structure. In the present invention, the active region of TFT and the intrinsic region of TFD start from an identical amorphous silicon film. However, since the catalyst element is not introduced in the TFD region, the region is not crystallized by the subsequent annealing step. This is attained since the annealing temperature in the present invention can be lowered by more than 50.degree. C. than that in the prior art. Therefore, although two layers of silicon films have to be formed in the prior art, it is suffice to form a single silicon film layer in the present invention. Then, the n-type layer and the p-type layer necessary so far can be obtained by forming them simultaneously in a planar structure upon doping impurities in TFT. That is, the n-type region of TFD is formed upon implantation of n-type impurities to TFT, while the p-type region of TFD is formed upon implantation of p-type impurities to TFT. As a result, the interlayer insulator can also be a single layer.

Such a planar TFD has a novel feature not obtainable in the prior art. In a case of using a conventional TFD (having a shape as shown in FIG. 1), for example, as a light sensor, the direction of an electric field generated at the inside of the semiconductor is vertical to a light irradiation plane, so that the light irradiation intensity is not uniform in the direction of the electric field and it has been impossible to efficiently generate electrons and holes and take out them externally. In addition, short-circuit may be caused sometimes to TFD due to pinholes through the layers. In the present invention, since the direction of the electric field generated in TFD is in parallel with the light irradiation plane, the light intensity is constant in the direction of the electric field to improve photoelectric conversion efficiency and, in addition, suppress occurrence of short-circuit.

In the present invention, a thin amorphous silicon film with a thickness of less than 1,000 .ANG., which is not crystallized by usual heat annealing, is also crystallized due to the effect of the catalyst element. It has been required that the thickness of the crystalline silicon film is less than 1,000 .ANG., preferably, less than 500 .ANG. with a view point of avoiding pinholes or insulation failure in the gate insulation film and disconnection of the gate electrode at stepped portions of TFT. This can not be attained so far by the method other than laser crystallization but this can be attained in accordance with the present invention by heat annealing even at a low temperature. This is naturally attributable to further improvement of the yield. In addition, in a case of utilizing TFD as a light sensor, S/N ratio and photoelectric conversion efficiency can be improved by using a thin semiconductor film.

According to the present invention, it is possible to save the number of processing steps for fabricating a semiconductor device/circuit having, for example, crystalline silicon TFT and amorphous silicon TFD and improving the productivity. Further, in the present invention, throughput can be improved also by crystallizing silicon, for example, at a temperature as low as 500.degree. C. and at a processing time as short as four hours. In addition, in a case of adopting a process at a temperature higher than 600.degree. C. in the prior art, there has been a problem of causing shrinkage or warp in a glass substrate which leads to the reduction of the yield, whereas such problems can be overcome altogether by utilizing the present invention.

This means that a substrate of a large area can be processed at a time. That is, unit cost can be reduced remarkably by cutting out a number of integrated circuits, etc. from a single substrate by processing a substrate of a large area. Thus, the present invention is of an industrial advantage.

These and other novel features and advantages of the present invention are described in or will become apparent from the following detailed description of preferred embodiments.

BRIEF DESCRIPTION OF THE DRAWINGS

The preferred embodiments will be described with reference to the drawings, wherein like elements have been denoted throughout the figures with like reference numerals, and wherein:

FIGS. 1A-1E are cross sectional views illustrating an example of fabrication steps in the prior art;

FIGS. 2A-2F are cross sectional views illustrating fabrication steps in Example 1 of the first feature of the present invention;

FIGS. 3A-2F are cross sectional views illustrating fabrication steps in Example 2 of the first feature of the present invention;

FIGS. 4A-2E are cross sectional views illustrating fabrication steps in Example 3 of the second feature of the present invention;

FIGS. 5A-5F are cross sectional views illustrating fabrication steps in Example 4 of the second feature of the present invention;

FIGS. 6A-6E are cross sectional views illustrating fabrication steps in Example 5 of the third feature of the present invention;

FIGS. 7A-7F are cross sectional views illustrating fabrication steps in Example 6 of the third feature of the present invention;

FIGS. 8A-8F are cross sectional views illustrating fabrication steps in Example 7 of the fourth feature of the present invention;

FIG. 9A is a cross sectional view of a TFD obtained in the previous example;

FIG. 9B is a band diagram of the TFD;

FIG. 9C is a cross sectional view illustrating a modified embodiment of the TFD; and

FIGS. 10A-10F are cross sectional views illustrating fabrication steps in Example 8 of the fourth feature of the present invention.

DETAILED DESCRIPTION OF PREFERRED EMBODIMENTS

Description will be made more specifically to the present invention by way of examples.

Example 1

FIGS. 2A-F illustrate cross sectional views for fabrication steps in Example 1 of the first feature according to the present invention. At first, an underlying film 11 made of silicon oxide was formed to a thickness of 2,000 .ANG. by a sputtering method on a substrate (Corning (Trademark) 7059) 10. Further, an intrinsic (I) amorphous silicon film was deposited to a thickness of 500 to 1,500 .ANG., for example, 1,500 .ANG. by a plasma CVD process. Then, the thus obtained amorphous silicon film was patterned by photolithography to form an island-like silicon regions 14a (for TFT) and 14b (for TFD). Further, a silicon oxide film 15 was deposited to a thickness of 1,000 .ANG. as a gate insulation film by a sputtering method. Sputtering was applied using silicon oxide as a target, at a substrate temperature of 200.degree. to 400.degree. C., for example, at 250.degree. C. in a sputtering atmosphere of oxygen and argon at an argon/oxygen ratio of 0 to 0.5, for example, less than 0.1. Successively, a silicon film (containing 0.1 to 2% phosphorus) was deposited to a thickness of 6,000 to 8,000 .ANG., for example, 6,000 .ANG. by a vacuum CVD process. The steps of forming the silicon oxide and the silicon film are desirably conducted continuously. Then, the silicon film was patterned to form gate electrodes 16a and 16b for TFT and a mask material 16c for