This invention relates to improved hydrocarbon gels finding use in the fracturing of formations which produce petroleum and other hydrocarbons. The gelling agents comprise combinations of ferric salts, selected orthophosphate esters, a low molecular weight amine such as triethonolamine or triethylamine, and a surfactant.
RELATED APPLICATIONS
This application is a continuation-in-part of our application Ser. No. 08/360,438 of the same title filed Dec. 21, 1994, now abandoned, which is a division of our application Ser. No. 08/209,266, also of the same title, filed Mar. 14, 1994, now U.S. Pat. No. 5,417,287.
Method and composition for gel formation in hydrocarbon recovery, in which an organic phosphate ester is gelled by a novel activator composition comprising iron sulfate, dibutylaminoethanol, and a phosphate surfactant.
Method and composition for gel formation in hydrocarbon recovery, in which an organic phosphate ester is gelled by a novel activator composition comprising iron sulfate, dibutylaminoethanol, and a phosphate surfactant.
A fracturing fluid is provided for use in fracturing subterranean formations. It comprises a hydrocarbon base. In the base, acidified alkyl phosphate esters are complexed with metallic cations, to form a gel.
A fracturing fluid is provided for use in fracturing subterranean formations. It comprises a hydrocarbon base. In the base, acidified alkyl phosphate esters are complexed with metallic cations, to form a gel.
A method of treating a subterranean formation comprising the steps of providing a servicing fluid comprising carbon dioxide and a hydrocarbon blend, wherein the hydrocarbon blend comprises at least about 65% hydrocarbons having from six carbons (C.sub.6) to eleven carbons (C.sub.11); and placing the servicing fluid into the subterranean formation. A subterranean servicing fluid comprising carbon dioxide and a hydrocarbon blend wherein the hydrocarbon blend comprises and at least about 65% hydrocarbons having from six carbons (C.sub.6) to eleven carbons (C.sub.11).
