A method of treating inorganic solid waste in a bath of molten metal contained in a vessel (3) which has a space above the bath and a waste gas outlet (11) is disclosed. The method comprises injecting waste into the bath to form a primary reaction zone (13) in which there are reactions between the waste and the bath or in which the waste undergoes a change of phase to convert the waste into more readily recoverable or disposable products. The method further comprises injecting oxygen-containing gas towards the surface of the bath to form a secondary reaction zone (17) in a section above the bath through which oxidisable products released from the primary reaction zone (13) flow to reach the waste gas outlet (11) in the vessel (3) and in which the oxidisable products are oxidised and the heat released by such oxidation is transferred into the bath.
Solid material, e.g., coal, is upgraded, e.g., the water content reduced and the BTU value increased, by a method comprising the steps of: (a) supplying the solid material to a reactor; (b) heating the solid material in the reactor under water saturation pressure conditions and removing water from the solid material; and (c) cooling the solid material by depressurising the solid material under water saturation conditions.
A molten bath-based direct smelting process for producing metals from metal oxides (including partially reduced metal oxides) is disclosed. The process includes causing upward movement of splashes, droplets, and streams of molten material from a metal layer (15) of the molten bath which: (i) promotes strong mixing of metal in a slag layer (16) of the molten bath so that the slag layer (16) is maintained in a strongly reducing condition leading to FeO levels below 8 wt % based on the total weight of the slag in the slag layer (16); and (ii) extends into a space above a nominal quiescent surface of the molten bath to form a transition zone (23).
A procedure for starting up a direct smelting process for producing iron from a metalliferous feed material in a metallurgical vessel is disclosed. The vessel is of the type which includes a plurality of feed material injection lances/tuyeres (11, 13). The start-up procedure includes the steps of: (a) preheating the vessel; (b) supplying a charge of molten iron to the vessel and forming a molten bath in the vessel, (c) supplying carbonaceous material and flux to the molten bath and injecting oxygen-containing gas through one or more than one feed material injection lance/tuyere and combusting carbon and bath derived gas (if present) and thereby heating the molten bath and generating slag; and (d) suppling metalliferous feed material to the vessel while continuing supply of carbonaceous material and flux and injection of oxygen-containing gas and smelting metalliferous feed material and producing molten iron and thereby completing the start-up procedure.
A direct smelting vessel which is adapted to contain a molten bath of metal and slag is disclosed. The vessel includes an off-gas duct that has: (a) a first section which has a relatively slight upward inclination to the horizontal from an inlet end of the first section; and (b) a second section which extends upwardly from an upper end of the first section at a relatively steep inclination to the horizontal.
A direct smelting process and a fixed, ie non-rotatable, metallurgical vessel for producing metal from a metalliferous feed material is disclosed. The process is a molten bath-based process which includes injecting solid feed materials with a carrier gas into the molten bath via one or more downwardly extending lance/tuyere (11) and causing gas flow from the molten bath at a flow rate of at least 0.30 Nm.sup.3 /s/m.sup.2 at the interface between the metal layer (15) and the slag layer (16) of the molten bath (under quiescent conditions).
