A gas diffusion electrode is constituted by forming a porous layer comprising a super-fine particle catalyst of silver or gold and a fluorine-containing material on a substrate and connecting a gas-liquid permeable collector to the substrate. The gas diffusion electrode can be used stably as an oxygen cathode for a sodium chloride electrolysis, etc., for a long period of time without causing decreased water repellency of the fluorine-containing material in the gas diffusion electrode and without lowering the activity of the electrode substance.
A polymer electrolyte fuel cell comprising a polymer electrolyte made of an ion exchange membrane, catalyst layers disposed on both sides thereof and current collectors disposed on the outer sides thereof, wherein a solvent-soluble fluorine-containing polymer (preferably a polymer having a fluorine-containing aliphatic ring structure) having substantially no ion exchange groups, is incorporated in the current collectors. By the above construction, the current collectors can have a high water repellency for a long period of time, and the polymer electrolyte fuel cell can operate at a high output density constantly over a long period of time.
Gas-diffusion electrodes containing modified carbon products are described wherein the modified carbon product is a carbon product having attached at least one organic group. The modified carbon product can be used for at least one component of the electrodes such as the active layer and/or the blocking layer. Methods to extend the service life of electrodes as well as methods to reduce the amount of fluorine containing compounds are also described.
Gas-diffusion electrodes containing modified carbon products are described wherein the modified carbon product is a carbon product having attached at least one organic group. The modified carbon product can be used for at least one component of the electrodes such as the active layer and/or the blocking layer. Methods to extend the service life of electrodes as well as methods to reduce the amount of fluorine containing compounds are also described.
Gas-diffusion electrodes containing modified carbon products are described wherein the modified carbon product is a carbon product having attached at least one organic group. The modified carbon product can be used for at least one component of the electrodes such as the active layer and/or the blocking layer. Methods to extend the service life of electrodes as well as methods to reduce the amount of fluorine containing compounds are also described.
Gas-diffusion electrodes containing modified carbon products are described wherein the modified carbon product is a carbon product having attached at least one organic group. The modified carbon product can be used for at least one component of the electrodes such as the active layer and/or the blocking layer. Methods to extend the service life of electrodes as well as methods to reduce the amount of fluorine containing compounds are also described.