The present invention provides a coating composition and a process for producing a multicoat finish therefrom. The coating composition has a binder component obtained by polymerizing: (a) from 10 to 51% by weight of a mixture of hydroxy n-butyl (meth)acrylate(s) and hydroxy n-propyl (meth)acrylate(s), (b) from 0 to 20% by weight of at least one further hydroxyl group-containing monomer, (c) from 28 to 85% by weight of at least one (cyclo)aliphatic (meth)acrylic acid ester, (d) from 0 to 25% by weight of at least one aromatic vinyl compound, (e) from 0 to 5% by weight of at least one unsaturated carboxylic acid, and (f) from 0 to 20% by weight of further monomers, to give a polyacrylate resin having a hydroxyl number of from 60 to 200, an acid number of from 0 to 35, and an Mn of from 1000 to 5000. The coating composition also has a crosslinking component that is a mixture comprising a polyisocyanate having an average functionality of from 3 to 4 and having a uretdione group content of less than 5%, and optionally a polyisocyanate having an average functionality of from 2 to 3 and having a uretdione group content of from 20 to 40%, and optionally a further polyisocyanate.
A description is given of polyisocyanates of the formula I ##STR1## in which R and R' are identical or different and are alkyl groups having 1-4 carbon atoms and n is on average from 1.5 to 5 and also of a process for preparing these polyisocyanates in which a polyamine of the formula II ##STR2## in which R, R', and n are as defined above, is reacted with phosgene. The new polyisocyanates are suitable for producing crosslinked polyurethanes from reaction mixtures with low solvent content and for producing coating compositions or adhesives. Also described are the coating compositions and adhesives, and their use.
A two-stage cure coating composition of a binder and a crosslinking component; the binder comprises and acrylic polymer having a weight average molecular weight of 3,000 to 50,000 and hydroxyl moieties in the range of 7.0 to 40.0 weight; wherein at least 40.0 weight percent of the hydroxyl moieties are provided by hydroxy butyl acrylate; the crosslinking component comprises an organic polyisocyanate; and the first stage curing of a finish of the composition forms a water spot free finish within 90 minutes of application and the composition has a pot life of less than a 2 second rise in Zahn cup viscosity in 150 minutes; and the invention also is directed to a method of producing a finish on a substrate utilizing the coating composition.
Liquid compositions and homopolymers or copolymers of olefinically unsaturated compounds, preparable by (co)polymerizing olefinically unsaturated compounds and reactive diluents for thermally curable multisubstance mixtures as reaction medium, and their use to prepare coating compositions, adhesives and sealing compounds.
