This invention is a method for forming hypohalous acid in a mass transfer device. The method comprises: (1) feeding into the device a stream of caustic solution comprising at least one alkali or alkaline earth metal of a hydroxide, oxide, hypohalite, bicarbonate, or carbonate; (2) feeding a stream comprising halogen gas into the device; (3) reacting at least some of the halogen gas with the caustic solution to form a solution containing hypohalous acid; (4) desorbing the hypohalous acid from the solution and into the stream of halogen gas; and (5) removing the stream of halogen gas from the device. In this method, the mass transfer device comprises a porous rotor which is permeable to the streams, and is rotated about an axis such that the streams flow through the rotor and the stream of caustic solution flows radially outward from the axis.
A high viscosity liquid is fed into a rotation pack bed at a position with a distance far enough from a rotation axis, creating a centrifugal force exerted on the high viscosity liquid overwhelming a drag thereof, so that it can flow radially through the rotation pack bed. A high pressure gas is introduced into the rotation pack bed peripherally and/or a suction force source is connected to a position near the rotation axis, so that a volatile component contained in the high viscosity fluid is entrained in the gas counter currently flowing through the rotation pack bed and withdrawn from the position near the rotation axis, or the volatile component exits from the position near the rotation axis in gas phase, and thus the volatile component is removed from the high viscosity liquid. A second fluid can also be fed into the rotation pack bed to react with the high viscosity liquid, so that a reaction product is formed, and a volatile side product is removed at the same time.
A spinning impingement multiphase contacting device and method for heat or mass transfer are disclosed. A first fluid, from which the transfer is to occur, is caused to impinge and be entrained in a spinning permeable element, creating a highly dispersed phase. The highly dispersed phase contacts the second fluid to cause the desired heat or mass transfer.
A spinning impingement multiphase contacting device and method for heat or mass transfer are disclosed. A first fluid, from which the transfer is to occur, is caused to impinge and be entrained in a spinning permeable element, creating a highly dispersed phase. The highly dispersed phase contacts the second fluid to cause the desired heat or mass transfer.
Degassing is accomplished by driving a gas-containing solution to a subatmospheric pressure approximately equal to the solution vapor pressure, and maintaining the subatmospheric pressure notwithstanding evolution of gas from the solution. This may be accomplished using a vacuum tower arrangment whereby a column of the gas-containing liquid is drawn to the maximum physically attainable height. So long as the vacuum is coupled to the liquid column above this height (generally on the order of 34 feet, depending on the ambient temperature and the composition of the liquid), the liquid will not be drawn into the vacuum, which creates a non-equilibrium region of extremely low pressure above the liquid that liberates dissolved gases. Moreover, liquid introduced into the low-pressure region above the column will fall onto the column without entering the vacuum system. As a result, the region above the column represents an interaction region within which gas will be stripped from an incoming liquid as it falls toward the column.
