A metallized film comprises an opaque, continuous layer of metal on an aliphatic polyurethane substrate. The polyurethane substrate displays a glass transition temperature of about 25.degree. to 110.degree. C. and a melting temperature greater than or equal to 200.degree. C. Decorative articles can be made with the metallized film.
A decorative emblem with an enhanced depth of vision is provided. The decorative emblem comprises a decorative substrate, at least one layer of transparent plastic material formed on the top surface of the decorative substrate, and image or design printed on the substantially flat surface of the layer of plastic material, and a transparent plastic overlay flow coated over the image or design, the transparent plastic overlay has radiused edges to give an enhanced depth of vision to the decorative emblem by creating a lens effect and providing a floating appearance to the image or design.
A primer layer and a thermoformable film that includes the primer layer are provided. The primer layer includes a cross-linked adhesive polymer having a semicrystalline region and a polar region. The cross-linked adhesive polymer has a tensile strength at maximum elongation that is less than that of an otherwise identical adhesive polymer that has not been cross-linked. The primer layer can be an outer layer of the thermoformable film, can be positioned between two additional layers of the thermoformable film, or a combination thereof. The primer layer can be positioned in contact with a mold surface during a thermoforming process.
Disclosed are multi-component waterborne coating compositions that include a first component and a second component which are mixed together prior to application of the composition to a substrate. The first component includes an aqueous dispersion of (i) a polycarbonate-polyurethane polymer, and (ii) an acrylic polyol having a number average molecular weight of no more than 5,000. The second component includes a material having functional groups reactive with the functional groups of the acrylic polyol and/or the polycarbonate-polyurethane polymer. Also disclosed are coatings formed from such compositions and substrates at least partially coated with such compositions.
A thermoforming method and objects prepared using the thermoforming method are described. Non-self-supporting, polymeric films are initially formed into a three-dimensional shaped film on a male mold and then transferred to a female mold while being supported by the male mold. The three-dimensional shaped film can be further thermoformed, reinforced, or a combination thereof on the female mold. The resulting object has a substantially uniform thickness across a major surface. The method can preserve the surface quality of the polymeric film used to prepare the three-dimensional objects.
A bright metallized laminate is disclosed that includes a polyvinylidene difluoride-acrylic film having microscopically smooth surfaces, a discontinuous layer of indium islands deposited on the polyvinylidene difluoride-acrylic film, an adhesive layer bonded to the surface of the discontinuous indium layer opposite the polyvinylidene difluoride-acrylic film, and a thermoplastic backing layer bonded to the adhesive layer opposite the discontinuous layer of indium islands. An associated method is disclosed for forming the bright metallized laminate that includes the steps of casting a polyvinylidene difluoride-acrylic film to a polymeric substrate, depositing a discontinuous layer of indium islands upon the polyvinylidene difluoride-acrylic film, placing a polymeric film onto the discontinuous layer of indium islands, and press polishing the polyvinylidene difluoride-acrylic film and the discontinuous indium layer. The polyvinylidene difluoride-acrylic film demonstrates a roughness average (RA) of about 0.75 micron or less, and a distinctness of image (DOI) of about 95 or more.