The present invention relates to a hair cuticle caring method or volume enhancing method, which comprises treating hair with a composition containing (A) a cationic surfactant and (B) an organic acid or salt thereof in a combination to give, when an aqueous solution containing 1 mM of each of the components is formed, 40 mN/m or less as the surface tension of the aqueous solution at 27.+-.0.5.degree. C. By the application of the above-described composition, the lift-up of the hair cuticle can be suppressed, the volume can be enhanced softly, moisturized but stickiness-free feeling is imparted and styling ease is improved.