There is disclosed a heat resistant cloth for fire fighting. At least an inner surface of a fluororesin film is subjected to plasma discharge treatment to form a treated surface. A vacuum-deposition film made of a bright metal such as aluminum is formed on the treated surface of the fluororesin film without use of a primer. The vacuum-deposition film on the treated surface is bonded to an outer surface of a substrate fabric through use of a silicone rubber adhesive in order to form a heat-reflecting layer on the outer surface of the substrate fabric. Since no primer coating layer is used, the heat reflecting layer can prevent a decrease in brightness, which would otherwise occur due to cracks generated in the primer coating layer. Thus, a decrease in heat reflectivity at high temperature is prevented. Since no flammable synthetic resin layer is used at the surface of the heat reflecting layer, flame resistance can be improved.
A burn through resistant nonwoven mat and cover film composite for use in a thermal and/or acoustical insulation blanket system, are, preferably, made up of non-respirable and/or biosoluble base fibers and capable of retaining their integrity and dimensional stability during 4 minutes of exposure to a fluctuating high pressure flame front at a temperature of 1100.degree. C. examples of non-respirable base fibers which make up the nonwoven mat are quartz fibers; aluminosilicate, aluminoborosilicate or alumina ceramic oxide fibers; partially oxidized pitch based fibers; and partially oxidized polyacrylonitrile fibers having mean diameters greater than 6 microns. Examples of biosoluble fibers are biosoluble glass fibers. Preferably, the nonwoven mats also include a lubricant sizing with a water repellent additive.