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Method for non-oxidative production of formaldehyde from methanol
   
Document Number
US Patent 6232507
Issued Date
May 15, 2001
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Abstract
Process for the nonoxidative preparation of formaldehyde from methanol The invention relates to a process for preparing formaldehyde from methanol by dehydrogenation in a reactor at temperatures in the range from 300 to 1000.degree. C. in the presence of a catalyst which is introduced into the reactor with the aid of a carrier gas to give a product gas mixture, wherein the formaldehyde is separated from the product gas mixture and at least part of the remaining product gas mixture is recirculated to the reactor in a circulating gas stream and the carrier gas used is a carbon-free gas or gas mixture.
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Method for non-oxidative production of formaldehyde from methanol - US Patent 6232507 Drawing
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Number of Claims:
14
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Published
May 15, 2001
Application Number
09/623,660
Filed
September 26, 2000
US Classification
568/449  
Int'l Classification
C08G   65/00   (20060101)   C01B   3/00   (20060101)   C01B   3/22   (20060101)   C07C   45/00   (20060101)   C07D   323/06   (20060101)   C07D   323/00   (20060101)   C08G   2/08   (20060101)   C08G   2/00   (20060101)  
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Priority Data
Mar 10, 1998 [DE] 198 10 087
USPTO Field of Search
568/449  
Related Patents
7390932 - Method for preparing highly concentrated, gaseous formaldehydes - Owned by BASF Aktiengesellschaft (DE)

Process for preparing high-concentration gaseous formaldehyde having a molar CH.sub.2O:H.sub.2O ratio of .gtoreq.0.6 from an aqueous formaldehyde solution by evaporation of at least part of the solution, in which the aqueous formaldehyde solution is heated to a vaporization temperature T and the gas phase formed is taken off, wherein the evaporation temperature T obeys the relationship: T[.degree. C.].gtoreq.T'.sub.min[.degree. C.] where T'.sub.min(c)=A+B.times.(c/100)+C.times.(c/100).sup.2+D.times.(c/100).sup- .3 and A=+68.759, B=+124.77, C=-12.851, D=-10.095, where c is the instantaneous CH.sub.2O content of the aqueous formaldehyde solution during the evaporation in percent by weight and is from 20 to 99% by weight.

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