A process uses a water repellant material in order to enhance the water resistance of composite. The process begins with a saturated vegetable or animal fat triglyceride having a low iodine value. The triglyceride is melted to form a sprayable liquid. The sprayable triglyceride and a bonding agent are applied to the fibrous materials, preparatory to a press binding. Then, the sprayed fibrous material is subjected to a hot press cycle in order to form a bonded fibrous composition. The low Iodine Value triglyceride may be selected from a group including hydrogenated vegetable oil, palm oil, stearine, winterized low IV fractions, soy stearine, animal fat, hydrogenated animal fat, and fractionated fats or blends of these materials.
The specification describes preserved solid wood or wood composites including a copper ammonium acetate complex wood preservative and a drying oil. The wood preservative is present in the wood in an amount effective to improve the resistance of the treated wood to at least one type of decomposition, such as decay or insect attack. The drying oil is present in the wood in an effective amount to accomplish at least one useful end, such as reducing the water absorption or thickness swell of the treated wood or increasing its mechanical strength, even in a wood composite made using less binding resin than usual. Yet another aspect of the invention is a method of making the treated wood from green wood in solid or flaked form. A copper ammonium acetate complex wood preservative and optionally a drying oil are added to the green wood.
A method of tempering composite fiber panels eliminates a need for a bake oven during the tempering step. Both the front and back surfaces of the panels are sprayed with a tempering oil including a mixture of a drying oil and a dryer or catalyst. The drying oil may include a linseed oil refined to minimize low molecular weight and a conjugated oil. Sometimes the drying oil is further mixed with either a conjugated oil, a catalyst, a low molecular weight isocyanate resin (Imw-MDI) or another additive. The sprayed panels are stacked preferably in face-to-face contact inside a curing chamber heated only by the residual heat in the hot panels. A number of additives to the tempering oil are considered. A number of different forms of commercial panels are considered, such as: hardboard, oriented strandboard, fiber board siding, wafer board, medium density fiber board, particle board, and other similar boards.
Waxes prepared from hydrogenated plant oils, such as castor, palm, and soybean, are used to prepare water based emulsions. The inventive waxes, obtained from naturally derived, renewable resources, were emulsified under anionic, cationic and nonionic conditions, producing emulsions having a solids content up to about 45% solids. When used to coat fibrous cellulosic articles, such as paperboard, the emulsions' performance was similar to emulsions containing petroleum-derived waxes. The inventive waxes have a low iodine value (between 2-5), and melting points between approximately 120-200 degrees F. (Mettler Drop Point). These waxes comprise a triglyceride whose fatty acids are predominantly stearic acid or ricinoleic acid. The inventive waxes are used as an alternative to petroleum-derived, or expensive naturally-occurring waxes in the manufacture of emulsions used in coatings, polishes, adhesives, paper products, paperboard, in the removal of ink from fibrous cellulosic products and other manufacturing operations.
Glycerides of acids having conjugated groups of aliphatic carbon-carbon double bonds, such as tung oil, are functionalized by reaction with certain polyol compounds at mild conditions. The functionalized oils are useful in a variety of coating and adhesive applications. They can be cured with melamine-formaldehyde, urea-formaldehyde, benzoguanimine-formaldehyde and/or glycoluril-formaldehyde resins. They can be reacted with polyisocyanates to form polyurethanes, and urethane-group containing prepolymers. Of particular interest are water-dispersible prepolymers, which can be used to make anionic, cationic or nonionic polyurethane dispersions for coating, adhesive and sealant as well as composites applications.
A triacylglycerol-based wax, which can be used in candle making, is provided. The triacylglycerol-based material is predominantly includes a triacylglycerol stock which has a fatty acid profile has no more than about 25 wt. % fatty acids having less than 18 carbon atoms. In addition, the fatty acid profile of the triacylglycerol typically includes at least about 50 wt. % 18:1 fatty acid and no more than about 25 wt. % 18:0 fatty acid. In another embodiment, the triacylglycerol-based material is characterized in part by an Iodine Value of about 60 to 75. For applications such as candles, the wax commonly includes a hydrogenated vegetable oil and palmitic acid. Candles formed from triacylglycerol-based material and methods of producing the candles are also provided.
