A method for selecting alloying elements for complex, multi-component amorphous metal alloys is provided in which the solvent element is the largest atom with a concentration of 40-80 at %, the second most concentrated element has a radius of 65-83 % the radius of the solvent atom and a concentration of 10-40 at % in the alloy, with other elements selected at lower concentrations. For ternary alloys specified by this invention, the third element must have an atomic radius within 70-92 % of the solvent atom radius. In the preferred embodiment, alloys with four or more elements are specified, where the third elements must have an atomic radius within 70-80 %, the fourth element must have an atomic radius within 80-92 % of the solvent atom radius, and all other solute elements must have atomic radii within 70-92 % of the solvent atom radius. The concentrations of elements that have radii that differ by less than 1 % from one another are added together and treated as a single alloy addition for the purpose of this invention.
CROSS-REFERENCE TO RELATED APPLICATION
This application claims priority of the filing date of Provisional Application Ser. No. 60/308,800 filed Jul. 30, 2001, the entire contents of which are incorporated by reference herein.
A nanometer-sized porous metallic glass and a method for manufacturing the same are provided. The porous metallic glass includes Ti (titanium) at 50.0 at % to 70.0 at %, Y (yttrium) at 0.5 at % to 10.0 at %, Al (aluminum) at 10.0 at % to 30.0 at %, Co (cobalt) at 10.0 at % to 30.0 at %, and impurities. Ti+Y+Al+Co+the impurities=100.0 at %.
Metallic glass alloys of palladium, copper, cobalt, and phosphorus, that are bulk-solidifying having an amorphous structure. Other embodiments are described and claimed.
A bulk amorphous alloy has the approximate composition: Fe.sub.(100-a-b-c-d-e)Y.sub.aMn.sub.bT.sub.cM.sub.dX.sub.e wherein: T includes at least one of the group consisting of: Ni, Cu, Cr and Co; M includes at least one of the group consisting of W, Mo, Nb, Ta, Al and Ti; X includes at least one of the group consisting of Co, Ni and Cr; a is an atomic percentage, and a<5; b is an atomic percentage, and b.ltoreq.25; c is an atomic percentage, and c.ltoreq.25; d is an atomic percentage, and d.ltoreq.25; and e is an atomic percentage, and 5.ltoreq.e.ltoreq.30.
Zirconium-rich bulk metallic glass alloys include quinary alloys containing zirconium, aluminum, titanium, copper and nickel. The bulk metallic glass alloys may be provided as completely amorphous pieces having cross-sectional diameters of at least about 5 mm or even greater.
