Ultrasonic solvent cleaning processes can effectively decontaminate sensitive equipment. The disclosed decontamination liquids meet the following criteria: a. It is compatible with a wide range of sensitive equipment--the performance of electronic and optical equipment is not affected by immersion in decontamination liquid. b. The principal chemical warfare agents of concern are sufficiently soluble in decontamination liquid for it to be an effective decontamination medium. c. The principal chemical warfare agents of concern are quantitatively removed from solution in decontamination liquid by activated carbon. When agent contaminated decontamination liquid is passed through a bed of activated carbon, the agent adsorbs onto the activated carbon, resulting in agent free decontamination liquid that can be recycled and reused. d. It is nonflammable, nontoxic, and environmentally acceptable. Ultrasonic agitation provides effective mass and physical transfer of contaminants from the surfaces of the objects being decontaminated to the bulk of the decontamination liquid.Contaminant removal occurs in three steps: removal of the contaminant from the surface of the part being processed, transfer of the dissolved or suspended contaminant into the bulk of the decontamination liquid in the immersion sump, and then removal of the dissolved contaminant by activated carbon adsorption, or suspended contaminant by filtration.Biological contaminants are also effectively removed or inactivated by immersion and sonication in decontamination fluid or solutions of a soluble surfactant in decontamination fluid.Activated carbon beds and filters that come into contact with contaminated liquid can be contained in commercially available housings that shield the system operator from any contained toxic contents. These sealable containers, and their contents, can be destroyed by standard methods, such as incineration.Spectrographic fluorimetry can detect extremely low levels (of the order of 10 ppt) of fluorescent dyes dissolved in decontamination fluid.Decontamination of sensitive equipment in decontamination fluid can be performed in commercially available ultrasonic vapor degreasers.
An apparatus for detecting a chemical agent, capable of increasing a detection speed of a chemical agent, decreasing a false alarm rate, pinning down the kind of a chemical agent, and meeting specifications for unattended continuous monitoring equipment suitable for detecting sarin or soman. This detection apparatus comprises a sample introduction unit for introducing a sample, an ionizing unit for positively ionizing the sample from the sample introduction unit, a mass spectrometer unit for analyzing ions of the sample, and a computer for analyzing data, and is best suited for identifying a dangerous substance by detecting signals peculiar to chemical agents, such as sarin or soman.
The present invention describes compositions and methods for sorbing and/or destroying dangerous substances such as chemical and biological warfare agents. The present invention relates to dendritic polymers, specifically, to quaternary ammonium functionalized dendritic polymers and N-Halamine functionalized dendritic polymers. Such dendrimers are useful for the capture and neutralization of biological and chemical warfare agents.
An improved continuous process for converting methane, natural gas, or other hydrocarbon feedstocks into one or more higher hydrocarbons or olefins by continuously cycling through the steps of alkane halogenation, product formation (carbon-carbon coupling), product separation, and regeneration of halogen is provided. Preferably, the halogen is continually recovered by reacting hydrobromic acid with air or oxygen. The invention provides an efficient route to aromatic compounds, aliphatic compounds, mixtures of aliphatic and aromatic compounds, olefins, gasoline grade materials, and other useful products.
A process for converting gaseous alkanes to liquid hydrocarbons wherein a gaseous feed containing alkanes is reacted with a dry bromine vapor to form alkyl bromides and hydrobromic acid vapor. The mixture of alkyl bromides and hydrobromic acid are then reacted over a synthetic crystalline alumino-silicate catalyst, such as a ZSM-5 zeolite, at a temperature of from about 150.degree. C. to about 450.degree. C. so as to form higher molecular weight hydrocarbons and hydrobromic acid vapor. Propane and butane which comprise a portion of the products may be recovered or recycled back through the process to form additional C.sub.5+ hydrocarbons. Various methods are disclosed to remove the hydrobromic acid vapor from the higher molecular weight hydrocarbons and to generate bromine from the hydrobromic acid for use in the process.
