A polyalkylene terephthalate-series resin (e.g., polyethylene terephthalate-series resin, polybutylene terephthalate-series resin) is improved in flame retardancy by using a flame retardant containing a phosphazene compound and a phenolic resin. The phosphazene compound is a compound shown by the following formulae (1) and/ or (2), and/or a compound being the above compound crosslinked with a phenylene group or a crosslinking group shown by the following formula (3a). The proportion of the phosphazene compound to the phenolic resin is the former/the latter=5/95 to 95/5 (weight ratio). By means of the above flame retardant, a polyalkylene terephthalate-series resin can be highly improved in flame retardancy without deteriorating the properties. Further, by adding the other flame retardant (e.g., a nitrogen-containing flame retardant, a phosphate-series flame retardant), and a carbonizable resin, the flame retardancy can be enhanced. Mechanical Property In accordance with ASTM D-638 and ASTM D-790, the mechanical strength was determined with use of a test piece obtained by injection molding.
A flame retardant comprising a phosphazene compound, a polyphenylene oxide-series resin, and if necessary a styrenic resin and/or a nitrogen-containing compound imparts flame retardancy to a polyalkylene arylate-series resin. The phosphazene compound comprises at least a crosslinked phenoxyphosphazene compound. The obtained polyalkylene arylate-series resin composition shows high flame-retardancy.
A flame-retardant resin composition comprises a thermoplastic resin; a flame retardant comprising a phosphorus-containing compound (A), a aromatic resin (B), and at least one flame-retardant auxiliary (C) selected from a nitrogen-containing compound and a metal salt of an inorganic acid; and at least one stabilizer auxiliary (D) selected from a compound having a functional group reactive to an active hydrogen atom and a water-repellent compound. The phosphorus-containing compound may be a phosphoric ester. The aromatic resin may be a polyphenylene sulfide-series resin or a polyphenylene oxide-series resin. The nitrogen-containing compound is a salt of an amino group-containing triazine compound with an oxygen acid, a salt of an amino group-containing triazine compound with a hydroxyl group-containing triazine compound, a polyphosphoric acid amide, a cyclic urea compound, or others. The present invention provides a flame-retardant resin composition which has been flame-retarded without using a halogen-containing flame retardant.
A flame retardant polytrimethylene terephthalate resin composition, comprising: 30 to 99 parts by weight of (A) a polytrimethylene terephthalate resin, and 1 to 70 parts by weight of at least one flame retardant selected from the group consisting of (B-1) phosphorus-containing flame retardant and (B-2) nitrogen-containing flame retardant, is disclosed. The composition has superior mechanical characteristics, chemical resistance, electrical characteristics, weatherability, heat aging resistance and hydrolysis resistance, and has superior moldability, good appearance with less warpage deformation when molded, and furthermore has superior flame retardance and does not generate highly corrosive hydrogen halide gas upon combustion.
Organic polymeric substrates, for example polyolefins such as polypropylene, can be made flame retardant by the incorporation of a synergistic mixture of (i) at least one compound selected from the group consisting of the (a) sterically hindered nitroxyl stabilizers, (b) sterically hindered hydroxylamine stabilizers and (c) sterically hindered alkoxyamine stabilizers and (ii) at least one phosphazene flame retardant. Advantageously, a further flame retardant may be added, without the need of adding an antimony synergist. The compositions of the invention combine good flame retardant properties with light stability and good mechanical properties.
