Polyurethane-based pressure-sensitive adhesive which attaches strongly to polar plastic surfaces, smooth metal surfaces and glass, but which has weak, if any, adhesion to paper, paperboard or skin and is easily detachable without damaging surfaces during its removal, and is reusable. The adhesive comprises a polyurethane formed by reacting an aliphatic or alicyclic polyisocyanate having a functionality of equal to or less than three with a combination of diol and triol.
Polyurethane-based pressure-sensitive adhesive, characterized in that the polyurethane is composed of the following starting materials which are reacted catalytically with one another in the stated proportions: a) at least one aliphatic or alicyclic polyisocyanate having a functionality of in each case less than or equal to three, b) a combination of at least one triol A based on polypropylene glycol and having an average number-averaged molecular weight M.sub.n of less than or equal to 1000 and a triol B based on polypropylene glycol and having an average number-averaged molecular weight M.sub.n of greater than or equal to 1000, preferably greater than or equal to 3000, the ratio of the number of hydroxyl groups of the triol component A to the number of hydroxyl groups of the triol component B being between greater than 0 and 12, the ratio of the number of isocyanate groups to the total number of hydroxyl groups being between 0.8 and 1.15, preferably between 0.95 and 1.05, the catalyst for the reaction to the polyurethane consisting of or comprising a compound comprising bismuth and carbon, preferably a bismuth carboxylate or a bismuth carboxylate derivative.
A method and associated apparatus for forming a composite structural member from a charge are provided. The charge can be disposed on a first die of the apparatus and formed to a desired configuration defined by a recess of the die by inserting a second die or a tool into the recess. In some cases, the first die can include two portions that are adjustable in a transverse direction so that the recess can be opened by the insertion of the second die or tool. The second die or tool can be a substantially rigid member or an inflatable bladder. In either case, the charge can be disposed on the first die, formed, and then further processed on the first die, thereby facilitating indexing of the charge for each operation.