A multi-layer semiconductor device including copper interconnects with improved interlayer adhesion and a method for forming the same, the method including providing a semiconductor substrate comprising a dielectric insulating layer comprising copper containing interconnects the dielectric insulating layer and copper containing interconnects comprising an exposed surface; forming a first capping layer on the exposed surface; providing a treatment on the first capping layer to increase interface adhesion between the capping layer and the dielectric insulating layer; and, forming a second capping layer on the first capping layer.
A method for forming a metal interconnection of a semiconductor device avoids over-etching and under-etching through the use of the "self-stop" function of a nitridation layer, to prevent the occurrence of openings and voids in a copper interconnection and to obtain a constant trench depth. The method includes forming nitride films on a semiconductor substrate by primary annealing, the semiconductor substrate being provided with a first IMD film and a tungsten plug; depositing a second IMD film on the semiconductor substrate on which the nitride films are formed; depositing a photoresist on the second IMD film and patterning the photoresist; etching the second IMD film using the patterned photoresist to form a trench; removing the nitride films using a chemical; depositing a copper barrier metal film and a copper seed layer in the trench from which the nitride films are removed, and depositing copper; secondarily annealing the substrate on which the copper is deposited; and planarizing the secondarily annealed substrate by chemical-mechanical polishing.
A metal wiring for a semiconductor device and a method for forming the same are provided. The metal wiring includes a first insulating layer and a second insulating layer; an interlayer insulating film formed between the first and second insulating layers, wherein the interlayer insulating film is provided with holes having a designated shape; a barrier metal layer, a copper seed layer, and a copper layer sequentially formed in the holes of the interlayer insulating film; and a capping layer formed between the interlayer insulating film and the second insulating layer. The capping layer formed between the interlayer insulating film and the second insulating layer may be made of a negatively charged insulating material, thereby improving electro-migration characteristics at an interface between the capping layer and the copper layers.
