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Process for the preparation of carboxylic acid esters
   
Document Number
US Patent 7399873
Issued Date
July 15, 2008
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Abstract
There is provided a process for preparing a carboxylic acid ester of formula (3): R.sup.2COOR.sup.1 (3) wherein R.sup.1 is an alkyl group which may be substituted, an alkenyl group which may be substituted, an alkynyl group which may be substituted, an aralkyl group which may be substituted, or a heteroarylalkyl group which may be substituted, and R.sup.2 is an alkyl group which may be substituted, an alkenyl group which may be substituted, an alkynyl group which may be substituted, an aryl group which may be substituted, a heteroaryl which may be substituted, an aralkyl group which may be substituted, or a heteroarylalkyl group which may be substituted, which process is characterized by the steps of reacting a monohydroxy compound of formula (1): R.sup.1OH (1) wherein R.sup.1 is as defined above, with a zirconium compound of formula (6): Zr(OR.sup.8).sub.4 (6) wherein R.sup.8 is an alkyl group or an aryl group which may be substituted and is not the same as R.sup.1, to prepare a zirconium catalyst, and reacting a carboxylic acid of formula (2): R.sup.2COOH (2) wherein R.sup.2 is as defined above, with the monohydroxy compound of formula (1) in the presence of the zirconium catalyst.
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Number of Claims:
9
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Published
July 15, 2008
Application Number
11/837,404
Filed
August 10, 2007
US Classification
556/54   556/56
Int'l Classification
C07F   7/00   (20060101)  
Parent Case
This application is a Divisional of application Ser. No. 10/994,228, filed on Nov. 23, 2004 now abandoned, the entire contents of which are hereby incorporated by reference and for which priority is claimed under 35 U.S.C. .sctn. 120.
Priority Data
Nov 26, 2003 [JP] 2003-395147
USPTO Field of Search
556/54   556/56  
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