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Method of preparing cyclic olefin copolymer having controlled gel contents
   
Document Number
US Patent 7468417
Issued Date
December 23, 2008
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Abstract
The present invention relates to a method of preparing a copolymer having controlled gel content by polymerizing cyclic olefin compound by ROMP (Ring Opening Metathesis Polymerization), and more precisely, a method of preparing cyclic olefin copolymer with high yield, in which a complex prepared by mixing a W salt compound and an organoaluminum halide compound is used as a catalyst in the presence or absence of a molecular weight regulator, and a method of controlling gel formation by regulating the composition of cyclic olefin monomer composing a copolymer as shown in the following Empirical Formula 1 without using a reaction speed regulator or gel formation inhibitor. (Empirical Formula 1) Norbornene=30.about.70 weight % Cyclic olefin compound=70.about.30 weight % At this time, the cyclic olefin compound presented in the above Empirical Formula 1 is one or more compounds selected from a group consisting of dicyclopentadiene and compounds represented by the following Formula 1. ##STR00001## Wherein, m is an integer of 0-1, R.sub.1 is C.sub.1-C.sub.5 alkyl and R.sub.2 is H or C.sub.1-C.sub.10 alkyl.
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Number of Claims:
12
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Published
December 23, 2008
Application Number
11/467,100
Filed
August 24, 2006
US Classification
526/169   526/161 526/281 526/283
Int'l Classification
C08G   61/08   (20060101)   C08F   2/38   (20060101)   C08F   4/78   (20060101)  
Examiner
Attorney/Law Firm
Priority Data
Aug 26, 2005 [KR] 10-2005-0078864
USPTO Field of Search
526/161   526/169   526/281   526/283  
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