The compositions of this invention comprise uncrosslinked reaction mixtures comprising (1) at least one organic monomer, oligomer or polymer comprising a multiplicity of organic, electrophilic substituents, and (2) at least one metal-containing polymer comprising a metal-nitrogen polymer. Preferred compositions of this invention comprise reaction mixtures comprising (1) at least one organic monomer, oligomer or polymer comprising a multiplicity of organic, electrophilic substituents, and (2) at least one of: silicon-nitrogen polymers, aluminum-nitrogen polymers and boron-nitrogen and polymer combinations thereof comprising a multiplicity of sequentially bonded repeat units the compositions comprising the reaction products of the reaction mixtures, and the compositions obtained by crosslinking the reaction products of the reaction mixtures. The crosslinking may be effected through at least one of thermal-based, radiation-based free radical-based or ionic-based crosslinking mechanisms. Furthermore, the reaction mixtures, the composition comprising the reaction products and the crosslinked composition may further comprise at least one filler or reinforcement. The composition may be molded or shaped by various techniques into numerous useful articles. Furthermore, the compositions may be applied as coatings by various techniques onto numerous articles to enhance the articles usefulness.
CROSS REFERENCE TO RELATED APPLICATION
The present application is a continuation-in-part of U.S. patent application Ser. No. 08/148,044, filed Nov. 5, 1993, abandoned.
Disclosed are a composition for forming a ceramic material useful for smoothly forming a ceramic film at a low temperature on surfaces of solid products such as substrates used in electronic products, plastic films or the like and a process for producing such a ceramic material. The afore-mentioned composition comprises a silazane-based polymer, and at least one ceramic-transformation promoting agent selected from the group consisting of an amine compound, an acid compound and peroxide. Further, the afore-mentioned ceramic material can be produced by bringing a mixture of the silazane-based polymer and the ceramic-transformation promoting agent into contact with steam.
Novel polysilazane-modified polyamine hardeners for epoxy resins, such classes as glycidyl ether epoxy resins and novolac epoxy resins, including reaction mixtures, compositions and reaction products comprising such hardeners, impart enhanced high temperature properties, higher char yields and better adhesion properties to the cured epoxy resins relative to the same epoxy resins cured using unmodified polyamine hardeners.
Disclosed herein are a highly porous ceramic having a high porosity of not less than 60% and a pore density of not less than 10.sup.8 pores/cm.sup.3 fabricated from expandable microspheres and a preceramic polymer, and a method for fabricating highly porous ceramic. The method for fabricating highly porous ceramic from expandable microspheres and a preceramic polymer comprises the steps of: homogeneously mixing a preceramic polymer powder and expandable hollow microspheres, if necessary, a ceramic powder, and molding the mixture to form a molded body; heating the molded body to expand it; curing the expanded molded body; and pyrolyzing the cured molded body.Since the highly porous ceramic has a higher porosity and pore density than conventional porous ceramics, it can be suitably used for various high temperature structure materials, kiln furniture, bulletproof materials, shock-absorbing materials, insulating materials, refractory materials, lightweight structure materials, etc.
An ecological fire retardant blend of thermoplastics is provided. That is, to one or more organic polymers is added one or more preceramic oligomers or preceramic polymers to provide a blend of polymers of reduced flammability which do not significantly increase the levels of smoke, carbon monoxide or other toxics during combustion. In one example a preceramic polymer, eg. a polysilane resin is added to a polyolefin to provide an ecological fire retardant blend per the invention.
The present invention relates to coated optical devices, such as optical fibers and optical wave guides, and methods for forming coated optical devices. Methods for forming coated optical devices comprise providing at least one optical device and contacting at least a portion of at least one optical device with at least one coating composition comprising at least one metal-nitrogen polymer. The at least one coating composition may further comprise at least one multifunctional organic electrophile comprising at least one monomer, oligomer, or polymer comprising a plurality of organic electrophilic substituents. The coating composition contacting at least a portion of an optical device is at least partially crosslinked, thereby forming coated optical devices which exhibit enhanced resistance to, for example, deterioration resulting from, among other things, exposure to chemicals and environmental factors.
