The present invention provides novel biopesticides which can replace commercial pesticides and biopesticides which have been banned, restricted, or are being phased out, including, but not limited to chloropicrin, dichlorvos and methyl bromide. Many of the biopesticides of the present invention are excellent fumigants, possessing quick action and volatility, while posing less risk than currently used pesticides to humans and the environment. The biopesticides of the present invention are natural and closely-related synthetic derivatives or analogs related to two classes of natural compounds, namely glucosinolates and monoterpenoids.
A treatment for eliminating unwanted organisms in agriculture, the treatment comprising a first component comprising allyl isothiocyanate emulsified in water, and a second component comprising a solution of phosphorus and water.
Objectionable odors from agrichemicals can be masked by adding one or more terpene or their oxygenated derivatives to the formulation before, during, or after application. A particularly preferred formulation is a granulated insecticide that includes an insecticidal amount of a phosphoroamido(di)thioate in solid form, a polymeric binder, a small amount of an anticking aid, and a masking agent containing an essential oil that is either mixed throughout the granule or sprayed onto its surface. The essential oil masks objectionable odors from the active ingredient without adversely affecting the storage stability or efficacy of the active ingredient.