
Disclosed is a method for increasing the molar ratio of aluminum to chlorine in a polyaluminum chloride solution by the electrochemical dissolving of aluminum, including contacting a polyaluminum chloride solution having a molar ratio of aluminum to chlorine of equal to or greater than 0.5 with a galvanic element. The galvanic element includes metallic aluminum and an electrochemically more noble metal. Contact is maintained until the aluminum to chlorine ratio is increased to the desired level.











