The present invention relates to a method of immobilizing aqueous waste, including low level nuclear waste, by converting the waste to a solid. Solidification is accomplished with the addition of a compound having the formula Me(II)O or Me(II)(OH).sub.2 in combination with compounds of the general formula Me(II)O.R.sub.2O.sub.3, R.sub.2O.sub.3, R(OH).sub.3 or ROOH, where Me is a cation selected from the group consisting of Ca, Ba, Sr, Mn, and Zn, and R is selected from the group consisting of Al...

A mediated electrochemical oxidation process and apparatus for the use of mediated electrochemical oxidation for the oxidation, conversion/recovery, and decontamination of inorganic solids, liquids, and gases where higher oxidation states exist. Inorganic materials are introduced into an apparatus for contacting the inorganic materials with an electrolyte containing the oxidized form of one or more reversible redox couples, at least one of which is produced electrochemically by anodic oxidation ...

Methods and apparatus for treating waste are provided. Waste is converted in an arc plasma-joule heated melter system utilizing one or more arc plasma electrodes and a plurality of joule heating electrodes. The arc plasma electrode(s) can be configured for operation utilizing AC or DC power, or for switching between AC and DC power. The arc plasma electrodes can also be configured for independent arc voltage and arc current control. The joule heating circuits are configured for simultaneous oper...

Improved methods for the treatment of commingled wastes and process systems for practicing those methods are provided. The methods are practiced by first treating the commingled waste material in a primary treatment unit in the presence of a carrier fluid to separate the organic waste from the inorganic waste. The carrier fluid and the gaseous products from the primary unit are then treated in a flameless oxidizer, which efficiently destroys any remaining organic compounds. In one embodiment, th...

A method of treating inorganic solid waste in a bath of molten metal contained in a vessel (3) which has a space above the bath and a waste gas outlet (11) is disclosed. The method comprises injecting waste into the bath to form a primary reaction zone (13) in which there are reactions between the waste and the bath or in which the waste undergoes a change of phase to convert the waste into more readily recoverable or disposable products. The method further comprises injecting oxygen-containing ...

A method and a system is disclosed for controlling chemical reaction of a feed. The feed is directed into a reactor containing a molten metal bath to at least partially chemically react the feed to form an intermediate component. A portion of the intermediate component is combined with an off-gas which is emitted from the molten metal bath. At least a portion of the intermediate is then separated from the off-gas and returned to the molten metal bath. The returned intermediate component is then ...

A melting furnace that incorporates the autoclave theory and is equipped with a high-frequency (horizontal wave) device for incinerating material and for thermal decomposition and recrystallization of organic and inorganic hazardous compounds contained in it and to detoxify hazardous substances that have been recrystallized or thermally decomposed by using specific solvents. A method to accomplish the above is provided and hazardous gas that is generated during the incineration process at high t...

A waste destruction method using a reactor vessel to combust and destroy organic and combustible waste, including the steps of introducing a supply of waste into the reactor vessel, introducing a supply of an oxidant into the reactor vessel to mix with the waste forming a waste and oxidant mixture, introducing a supply of water into the reactor vessel to mix with the waste and oxidant mixture forming a waste, water and oxidant mixture, reciprocatingly compressing the waste, water and oxidant mix...

The burning of material, including fuel and/or waste products, is performed ithin an incineration chamber heated above room-temperature while being supplied with high-power microwave radiation under conditions generating a plasma through which oxidation is enhanced to eliminate contaminants from the gaseous emission discharged from the incineration chamber.

Methods for determining the parameters critical in designing an electrokinetic soil remediation process including electrode well spacing, operating current/voltage, electroosmotic flow rate, electrode well wall design, and amount of buffering or neutralizing solution needed in the electrode wells at operating conditions are disclosed These methods are preferably performed prior to initiating a full scale electrokinetic remediation process in order to obtain efficient remediation of the contamina...