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A unique two-step process is disclosed for the surprisingly high rate of amidation of vinyl chloride (VCl) with carbon monoxide and certain amines catalyzed by an effective amount of monodentate tertiary phosphonium complexes of Pd(0). The rate is orders of magnitude faster than that of other monochloroalkenes. When compared with the three chloropropenes, the simplest alkyl-substituted derivatives of VCl, rates differ by a factor of about 40 to 70 with ammonia as the amine. The reaction product ...
A continuous process for making N,N-dimethylacrylamide (NNDMA) is disclosed which uses a commodity chemical, namely vinyl chloride (VCl), which is amidated with dimethylamine (DMA) and carbon monoxide in the presence of a supported palladium(O) triorganophosphine catalyst used under conditions where the ratio of P/Pd is critical. The continous process unexpectedly provides the catalyst with long life because the reaction can be carried out in a moving bed of catalyst in the presence of enough ac...
An input image is inputted into a pre-process circuit and a spatial filter. The pre-process circuit emphasizes a linear shadow or an edge to some extent, or reduces noises overall. Following pre-processing, the image signal is supplied to a direction detection circuit, a direction and its intensity of an area of interest are detected. These two results of the detections are correlated with peripheral areas of interest to some extent by a vector filter. An output of the vector filter is supplied ...
The disclosure is of a device used in a hair cutting procedure, comprising a pair of comb-like parts having alternately positioned teeth which may be moved into and out of engagement to alternately hold and release the hair.
An arrangement for aligning a drive shaft of a fluid-operated gear machine having a cover enclosing a housing of the machine is provided. The aligning arrangement includes a plate connected to the axial end face of the cover, which side is directed to a pair of meshing gears mounted within the housing of the machine. This plate is formed with an opening receiving the drive shaft without a play when the cover is placed in a position in which it sealingly closes the housing.
A gear machine, such as a gear pump or gear motor, has a housing in a chamber of which there are journalled two gears which mesh with one another. One of the gears is mounted on a drive shaft the end of which is extended outwardly from the housing. The housing is closed at one side thereof with a cover having a stepped bore for receiving the end portion of the drive shaft. The cover is formed with a circumferential projection concentric with the drive shaft and adapted for centering the cover re...
An improved rearranging composition and permanent waving process is disclosed. The improved waving process produces hair that is characterized as thicker, more full bodied with improved humectant properties and requiring significantly less maintenance than is typically required when conventional waving processes are used. The waving process is a step by step procedure involving the addition of a rearranger, a wrapping lotion, and a neutralizer, in combination with intermittent rinsing. The impro...
An improved wrapping lotion and permanent waving process is disclosed. The improved waving process produces hair styles characterized as bouncier, more full bodied with an open/looser pattern of curls. The waving process is a step-by-step procedure involving the addition of a rearranger, a wrapping lotion, and a neutralizer, with intermittent rinsing between. The improved quality and setability of the hair is believed attributable to the improved wrapping lotion composition that comprises a homo...
Cosmetic compositions for treating the hair, nails and skin are described which contain, in a solvent medium, at least one amphoteric polymer of betainised dialkylaminoalkyl (meth)acrylate or dialkylaminoalkyl(meth)acrylamide, containing at least units of the formula: ##STR1## in which R.sub.1 denotes a hydrogen atom or a methyl group, R.sub.2 denotes an alkylene group having 1 to 4 carbon atoms, Y denotes O or NH and R.sub.3 and R.sub.4 independently of one another denote hydrogen or alkyl havi...
A process for simultaneously cold waving and coloring hair in which the neutralization of the hair waving composition is accomplished in two stages, the second stage of which involves the use of a neutralizing composition containing a hair dye.
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