
Polymer-based second harmonic generation materials are disclosed, including electric field poled, chromophore-functionalized polyphenylene ethers with second harmonic coefficients (d.sub.33) as high as 65.times.10.sup.-9 esu, Tg.apprxeq.173.degree. C., and with superior temporal stability of the poling-induced chromophore orientation. Procedures for simultaneously poling and diepoxide cross-linking chromophore-functionalized poly(.rho.-hydroxystyrene) are set forth, resulting in a significant im...











