Organic semiconductors are described having an electron donating cation which is a Group VIa element derivative of a polycyclic aromatic hydrocarbon and an inorganic or organic electron-accepting anion. These materials are generally soluble in ordinary solvents and have resistivities between 10.sup.-.sup.3 and 10.sup.9 ohm-cm. They are useful in conducting coatings, fibers, etc.











