A polyaniline is highly conductive and less corrosive when it contains up to 7 mol % of benzenoid-ammonium salt state and up to 25 mol % of quinoid-diimine state, based on the total molar amount of the polyaniline.

Processable electrically conductive latex polymer compositions including colloidal particles of an oxidized, polymerized amino-substituted aromatic monomer, a stabilizing effective amount of a random copolymer containing amino-benzene type moieties as side chain constituents, and dopant anions, and a method of preparing such polymer compositions are provided.

Electrochemical cells including secondary batteries and fuel cells are provided employing polyanilines having improved reversibility, stability and electrochemical properties. In accordance with a preferred embodiment polyaniline is employed as a cathode active polymer in a secondary battery at a pH between about 1 and 11. In accordance with other embodiment, fuel cells employing polyaniline are provided as are batteries wherein polyanilines are used as anodes.

The present invention provides a process for preparing electrically conductive polyaniline salts in various organic solvents using cost-effective protonic acids and where the solution is optically transparent.

The present invention provides a process for the preparation of a polyaniline salt by polymerizing an aromatic amine in the presence of a protonic acid and a mixture of aqueous and hydrocarbon solvents to obtain polyaniline salt dissolved in organic phase or in powder form.

This invention relates to a process for the enzymatic synthesis of electrically conductive substituted and unsubstituted polyanilines. Aniline monomer(s), an oxidizing agent, which comprises an enzyme and an electron acceptor, and an acidifying agent are reacted together to form polyanilines.

Stable, concentrated solutions of high molecular weight polyaniline. In order to process high quality fibers and other articles possessing good mechanical properties, it is known that solution concentrations of the chosen polymer should be in the range from 15-30% (w/w). Moreover, it is desirable to use the highest molecular weight consistent with the solubility properties of the polymer. However, such solutions are inherently unstable, forming gels before processing can be achieved. The present...

The present invention relates to a new process for preparation of conducting polyaniline. More particularly the present invention relates to a simple process for preparation of conducting polyaniline in non acidic medium.

Electrochemical electrodes are provided having improved capacity and efficiency. In accordance with preferred embodiments polyaniline species wherein oxidation and hydrogenation levels are carefully controlled are formulated into such electrodes and into batteries and fuel cells.

A method for producing a conductive polyaniline comprising oxidative polymerizing aniline or its derivative in the presence of at least one member of a sulfonic acid compound and a water-insoluble organic polymer compound having protonic acid group in a mixed layer composed of an aqueous layer and organic layer, during which it establishes the presence of a molecular weight adjusting agent and, optionally, a phase transfer catalyst so as to stably disperse them in an organic solvent, and an orga...